Experimental and theoretically estimated excess molar enthalpies for tert-butyl methyl ether+ 1-pentanol+octane at 298.15 K

  • P. V. Verdes
  • Marta M. Mato
  • E. Jiménez
  • J. L. Legido
  • María Inmaculada Paz Andrade
Article

Abstract

Forming part of the scientific project entitled ‘Study on physical properties of mixtures hydrocarbon+alcohol+ether like alternative fuels’, the present article reports experimental data of excess molar enthalpies for the ternary mixture {x1tert-butyl methyl ether (MTBE)+x21-pentanol+(1−x1x2)octane} and the involved binary mixture {x1-pentanol+(1−x) octane} at the temperature of 298.15 K and atmospheric pressure. No experimental excess enthalpy values were found in the currently available literature for the ternary mixture under study. The group contribution model of the UNIFAC (in the versions of Larsen, and Gmehling) were used to estimate excess enthalpy values. Several empirical expressions for estimating ternary properties from binary results were also tested.

Keywords

excess molar enthalpies group contribution model octane 1-pentanol ternary mixture tert-butyl methyl ether (MTBE) 

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References

  1. 1.
    M. M. Mato, S. M. Cebreiro, J. L. Legido and M. I. Paz Andrade, J. Therm. Anal. Cal., 84 (2006) 279.CrossRefGoogle Scholar
  2. 2.
    M. M. Mato, M. Illobre, P. V. Verdes and M. I. Paz Andrade, J. Therm. Anal. Cal., 84 (2006) 291.CrossRefGoogle Scholar
  3. 3.
    M. M. Mato, S. M. Cebreiro, P. V. Verdes, J. L. Legido and M. I. Paz Andrade, J. Therm. Anal. Cal., 80 (2005) 245.CrossRefGoogle Scholar
  4. 4.
    M. M. Mato, S. M. Cebreiro, P. V. Verdes, J. L. Legido and M. I. Paz Andrade, J. Therm. Anal. Cal., 80 (2005) 303.CrossRefGoogle Scholar
  5. 5.
    M. M. Mato, S. M. Cebreiro, P. V. Verdes, A. V. Pallas, J. L. Legido and M. I. Paz Andrade, J. Therm. Anal. Cal., 80 (2005) 317.CrossRefGoogle Scholar
  6. 6.
    P. V. Verdes, M. M. Mato, J. Salgado, J. L. Legido and M. I. Paz Andrade, J. Therm. Anal. Cal., 80 (2005) 323.CrossRefGoogle Scholar
  7. 7.
    P. V. Verdes, M. M. Mato, J. Salgado, J. L. Legido and M. I. Paz Andrade, J. Therm. Anal. Cal., 80 (2005) 329.CrossRefGoogle Scholar
  8. 8.
    P. V. Verdes, M. M. Mato, J. Salgado, X. Villaverde, J. L. Legido and M. I. Paz Andrade, J. Therm. Anal. Cal., 80 (2005) 333.CrossRefGoogle Scholar
  9. 9.
    P. V. Verdes, M. M. Mato, X. Villaverde, J. L. Legido and M. I. Paz Andrade, J. Therm. Anal. Cal., 80 (2005) 339.Google Scholar
  10. 10.
    M. M. Mato, S. M. Cebreiro, P. V. Verdes, A. V. Pallas, J. L. Legido and M. I. Paz Andrade, J. Therm. Anal. Cal., 80 (2005) 345.CrossRefGoogle Scholar
  11. 11.
    P. V. Verdes, M. M. Mato, J. Salgado, J. L. Legido and M. I. Paz Andrade, Fluid Phase Equilib., 232 (2005) 16.CrossRefGoogle Scholar
  12. 12.
    P. V. Verdes, M. M. Mato, M. Illobre, S. M. Cebreiro, J. L. Legido and M. I. Paz Andrade, J. Chem. Eng. Data, 49 (2004) 1703.CrossRefGoogle Scholar
  13. 13.
    S. M. Cebreiro, M. Illobre, M. M. Mato, P. V. Verdes, J. L. Legido and M. I. Paz Andrade, J. Therm. Anal. Cal., 70 (2002) 251.CrossRefGoogle Scholar
  14. 14.
    D. B. Myers and R. L. Scott, Ind. Eng. Chem., 55 (1963) 43.CrossRefGoogle Scholar
  15. 15.
    B. L. Larsen, P. Rasmussen and A. Fredenslund, Ind. Eng. Chem. Res., 26 (1987) 2274.CrossRefGoogle Scholar
  16. 16.
    J. Gmehling, L. Jiding and M. Schiller, Ind. Eng. Chem. Res., 32 (1993) 178.CrossRefGoogle Scholar
  17. 17.
    F. Kohler, Monatsh. Chem., 91 (1960) 738.CrossRefGoogle Scholar
  18. 18.
    K. T. Jacob and K. Fitzner, Thermochim. Acta, 18 (1977) 197.CrossRefGoogle Scholar
  19. 19.
    C. Colinet, Ph.D. Thesis University of Grenoble, France 1967.Google Scholar
  20. 20.
    J. B. Knobeloch and C. E. Schwartz, J. Chem. Eng. Data, 7 (1962) 386.CrossRefGoogle Scholar
  21. 21.
    C. C. Tsao and J. M. Smith, Chem. Eng. Prog. Symp. Series, 49 (1953) 107.Google Scholar
  22. 22.
    W. G. Toop, Trans. TMS-AIME., 223 (1965) 850.Google Scholar
  23. 23.
    G. Scatchard, L.B. Ticknor, J. R. Goates and E. R. McCartney, J. Am. Chem. Soc., 74 (1952) 3721.CrossRefGoogle Scholar
  24. 24.
    M. Hillert, Calphad, 4 (1980) 1.CrossRefGoogle Scholar
  25. 25.
    A. R. Mathieson and J. C. Thynne, J. Chem. Soc., (1957) 3713.Google Scholar
  26. 26.
    CRC. Handbook of Chemistry and Physics, 77th Ed.; CRC Press: Boca Raton, FL, 1996–1997; Vol. 16, pp. 1–11.Google Scholar
  27. 27.
    IUPAC, Pure and Appl. Chem., 58 (1986) 1677.Google Scholar
  28. 28.
    M. I. Paz Andrade, Les Dévelopements Récents de la Microcalorimétrie et de la Thermogenèse, 1st Ed.; CRNS, Paris 1967.Google Scholar
  29. 29.
    M. I. Paz Andrade, S. Castromil and M. C. Baluja, J. Chem. Thermodyn., 2 (1970) 775.CrossRefGoogle Scholar
  30. 30.
    K. N. Marsh, Int. DATA Ser. Sel. Data Mixtures, Ser. A, 1 (1973) 22.Google Scholar
  31. 31.
    J. Gmehling, Excess Enthalpy. Cyclohexane+hexane system. Int. DATA Ser. Sel. Data Mixtures, Ser. A, 3 (1992) 144.Google Scholar
  32. 32.
    V. Ragaini, R. Santi and S. Carra, Lincei-Rend. Sci. Fis. Mat. Nat., 45 (1968) 540.Google Scholar
  33. 33.
    D. W. Marquardt, J. Soc. Ind. Appl. Math., 2 (1963) 431.CrossRefGoogle Scholar
  34. 34.
    P. Bevington, Data Reduction and Error Analysis for the Physical Sciences; McGraw-Hill, New York 1969.Google Scholar
  35. 35.
    A. Fredenslund, J. Gmehling and P. Rasmussen, Vapor-Liquid Equilibria using UNIFAC, Elsevier, New York 1977.Google Scholar
  36. 36.
    D. S. Abrams and J. M. Prausnitz, AICHE J., 21 (1975) 116.CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media LLC 2007

Authors and Affiliations

  • P. V. Verdes
    • 1
  • Marta M. Mato
    • 2
  • E. Jiménez
    • 3
  • J. L. Legido
    • 2
  • María Inmaculada Paz Andrade
    • 1
  1. 1.Departamento de Física AplicadaUniversidade de SantiagoSantiago de CompostelaSpain
  2. 2.Departamento de Física Aplicada, Facultade de CienciasUniversidade de VigoVigoSpain
  3. 3.Departamento de Física, Facultade de Ciencias, Campus A ZapateiraUniversidade de A CoruñaA CoruñaSpain

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