Journal of Thermal Analysis and Calorimetry

, Volume 88, Issue 3, pp 693–698 | Cite as

The damage in the patrimonial books from Romanian libraries

Thermal analysis methods and scanning electron microscopy


The thermal analysis methods (TG, DTG, DSC, methods for shrinkage temperature evaluation) and scanning electron microscopy (SEM) were used for investigation of the thermal behaviour and surface morphology of some recent manufactured parchments and vegetable tanned leathers, patrimonial parchments and leathers proceeded from Romanian libraries. At the progressive heating in static air atmosphere and in the temperature range of 20–600°C, all investigated materials exhibit three main successive processes, associated with the dehydration and thermo-oxidative degradations.

The rate of the first thermooxidative process, temperatures corresponding to the maximum rate of the second thermooxidative process and shrinkage temperature were associated with the damage of the investigated materials due to environmental impact. Parchments and leathers surfaces were characterized by SEM, and specific morphological criteria were suggested for damage assessments. These criteria were correlated with the results obtained by thermal analysis methods.


DSC DTG leathers parchments patrimonial books from Romanian libraries SEM shrinkage temperature TG 


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  1. 1.
    C. Chahine and C. Rottier, Europen-Environmental, Leather Project, Research Report, Copenhagen 1996.Google Scholar
  2. 2.
    R. Larsen, Thermochim. Acta, 365 (2000) 85.CrossRefGoogle Scholar
  3. 3.
    C. Chahine, Thermochim. Acta, 365 (2000) 101.CrossRefGoogle Scholar
  4. 4.
    N. S. Cohen, M. Odlyha and G. Foster, Thermochim. Acta, 365 (2000) 111.CrossRefGoogle Scholar
  5. 5.
    T. J. Wess and J. P. Orgel, Thermochim. Acta, 365 (2000) 119.CrossRefGoogle Scholar
  6. 6.
    P. Budrugeac, L. Miu, V. Bocu, F. J. Wortmann and C. Popescu, J. Therm. Anal. Cal., 72 (2003) 1057.CrossRefGoogle Scholar
  7. 7.
    M. Odlyha, N. S. Cohen, G. M. Foster, A. Aliev, E. Verdonck and D. Grady, J. Therm. Anal. Cal., 71 (2003) 939.CrossRefGoogle Scholar
  8. 8.
    P. Budrugeac, L. Miu, C. Popescu and F. J. Wortmann, J. Therm. Anal. Cal., 79 (2004) 975.CrossRefGoogle Scholar
  9. 9.
    C. Popescu, P. Budrugeac, L. Miu, C. Idiţoiu and F. J. Wortmann, 30th Aachen Textile Conference, Aachen-Germany 2003.Google Scholar
  10. 10.
    G. Della Gatta, E. Badea, R. Ceccarelli, T. Usacheva, A. Masic and S. Collucia, J. Therm. Anal. Cal., 82 (2005) 637.CrossRefGoogle Scholar
  11. 11.
    B. Roduit and M. Odlyha, J. Therm. Anal. Cal., 85 (2006) 157.CrossRefGoogle Scholar
  12. 12.
    C. Marcolli and H. G. Wiedemann, J. Therm. Anal. Cal., 64 (2001) 987.CrossRefGoogle Scholar
  13. 13.
    M. Odlyha, N. S. Cohen, R. Campara and G. M. Foster, J. Therm. Anal. Cal., 56 (1999) 1219.CrossRefGoogle Scholar
  14. 14.
    S. Prati, G. Chiavari and D. Cam, J. Therm. Anal. Cal., 76 (2001) 1315.Google Scholar
  15. 15.
    S. Knappe, H. Mohler, J. Opfermann and H. Walter, ’Thermal Analysis for Paints’, Netzsch-Geratebau GmbH, Germany 2001.Google Scholar
  16. 16.
    H. G. Wiedemann, E. Arpagaus, D. Muller, C. Marcolli, S. Weigel and A. Reller, Thermochim. Acta, 382 (2002) 329.CrossRefGoogle Scholar
  17. 17.
    C. Genestar and J. Cifre, Thermochim. Acta, 385 (2002) 117.CrossRefGoogle Scholar
  18. 18.
    G. M. Foster, S. Ritchie and C. Lowe, J. Therm. Anal. Cal., 73 (2003) 119.CrossRefGoogle Scholar
  19. 19.
    R. E. White, P. S. Thomas, M. R. Phillips and R. Wuhrer, J. Therm. Anal. Cal., 80 (2005) 237.CrossRefGoogle Scholar
  20. 20.
    K. Heide, E. Hartmann, K. Gent and H. G. Wiedemann, Thermochim. Acta, 365 (2000) 147.CrossRefGoogle Scholar
  21. 21.
    L. Campanella, G. Favero, P. Flamini and M. Tomassetti, J. Therm. Anal. Cal., 73 (2003) 127.CrossRefGoogle Scholar
  22. 22.
    V. A. Drebuschchak, L. N. Mylnikova, T. S. Drebushchak and V. V. Boldyrev, J. Therm. Anal. Cal., 82 (2005) 617.CrossRefGoogle Scholar
  23. 23.
    S. Shoval and P. Beck, J. Therm. Anal. Cal., 80 (2005) 609.CrossRefGoogle Scholar
  24. 24.
    Q. Wang, M. Odlyha and N. S. Cohen, Thermochim. Acta, 365 (2000) 189.CrossRefGoogle Scholar
  25. 25.
    I. C. A. Sandu, M. Brebu, C. Luca, I. Sandu and C. Vasile, Polym. Degrad. Stab., 80 (2003) 83.CrossRefGoogle Scholar
  26. 26.
    H. Anastasiou, Th. Hasapis, T. Zorba, E. Pavlidou, K. Chrissafis and K. M. Paraskevopoulos, J. Therm. Anal. Cal., 84 (2006) 27.CrossRefGoogle Scholar
  27. 27.
    D. A. Silva, H. R. Wenk and P. J. M. Monteiro, Thermochim. Acta, 438 (2005) 35.CrossRefGoogle Scholar
  28. 28.
    M. Odlyha, Q. Wang, G. M. Foster, J. de Groot, M. Horton and L. Bozek, J. Therm. Anal. Cal., 82 (2005) 627.CrossRefGoogle Scholar
  29. 29.
    K. H. Friolo, A. S. Ray, B. H. Stuart and P. S. Thomas, J. Therm. Anal. Cal., 80 (2005) 559.CrossRefGoogle Scholar
  30. 30.
    W. K. Loke and E. Khor, Biomaterials, 16 (1995) 251.CrossRefGoogle Scholar
  31. 31.
    G. de Simone, B. Naviglio, M. Tomaselli, L. Bianchi, D. Sannino and P. Ciambelli, XXIII IULTCS Congress, Friedrichshafen, 1995, Part 1, Paper 21.Google Scholar
  32. 32.
    J. J. Lim and M. H. Shannon, Biopolymers, 13 (1974) 1791.CrossRefGoogle Scholar
  33. 33.
    A. Kaminska and A. Siokowska, Polym. Degrad. Stab., 51 (1996) 15.CrossRefGoogle Scholar
  34. 34.
    L. F. Lozano, M. A. Pena-Rico, A. Hereira, J. Ocotlan-Flores, A. Gomez-Cortes, R. Velazquez, I. A. Belio and L. Bucio, J. Mater. Sci., 38 (2003) 4777.CrossRefGoogle Scholar
  35. 35.
    L. Slusarski, J. Thermal Anal., 29 (1984) 905.CrossRefGoogle Scholar
  36. 36.
    C. Vasile, Handbook of Polyolefins, C. Vasile and R. Seymour, Eds., Marcel Decker, New York 2000, Ch. 2.Google Scholar
  37. 37.
    R. Reed, Ancient Skins, Parchments and Leathers, Seminar Press, London-New York 1972, p. 315.Google Scholar

Copyright information

© Springer Science+Business Media, LLC. 2007

Authors and Affiliations

  1. 1.INCDIE-ICPE-CA -National Institute for Research and Development in Electrical EngineeringBucharestRomania
  2. 2.R&D Textile and Leather National Institute — Division Leather and Footwear Research InstituteBucharestRomania
  3. 3.Czech National LibraryPrahaCzech Republic

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