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Journal of Thermal Analysis and Calorimetry

, Volume 87, Issue 1, pp 297–300 | Cite as

Development of a universal constant rate thermal analysis system for being used with any thermoanalytical instrument

  • J. M. Criado
  • L. A. Pérez-Maqueda
  • M. J. Diánez
  • P. E. Sánchez-Jiménez
regular

Abstract

The SCTA method implies to control the temperature in such a way that the reaction rate changes with the time according to a function previously defined by the user. Constant Rate Thermal Analysis (CRTA) is one of the most commonly used SCTA methods and implies achieving a temperature profile at which the reaction rate remains constant all over the process at a value previously selected by the user. This method permits to minimize the influence of heat and mass transfer phenomena on the forward reaction. The scope of this work is to develop a universal CRTA temperature controller that could be adapted to any thermoanalytical device. The thermoanalytical signal is programmed to follow a preset linear trend by means of a conventional controller that at the time controls a second conventional temperature programmer that forces the temperature to change for achieving the trend programmed for the thermoanalytical signal. Examples of the performance of this control system with a Thermobalance and a Thermomechanical Analyser (TMA) are given.

Keywords

BaTiO3 CRTA PVC SCTA TG TMA 

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Copyright information

© Springer-Verlag 2007

Authors and Affiliations

  • J. M. Criado
    • 1
  • L. A. Pérez-Maqueda
    • 1
  • M. J. Diánez
    • 1
  • P. E. Sánchez-Jiménez
    • 1
  1. 1.Instituto de Ciencia de Materiales de SevillaCentro Mixto Universidad de Sevilla-C.S.I.C.SevillaSpain

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