Journal of Thermal Analysis and Calorimetry

, Volume 90, Issue 2, pp 399–405 | Cite as

The relationship between properties of fluorinated graphite intercalates and matrix composition

Part II. Intercalates with chloroform
  • D. V. Pinakov
  • V. A. Logvinenko
  • Yu. V. Shubin
  • G. N. Chekhova
Regular papers Material Science/Geosciences


Inclusion compounds (intercalates) of fluorinated graphite matrix with chloroform (C2FxBrz·yCHCl3, x=0.49, 0.69, 0.87, 0.92, z=0.01) were synthesized by guest substitution from acetonitrile to chloroform. The kinetics of the thermal decomposition (the 1st stage of filling → the 2nd stage of filling) was studied under isothermal conditions at 286–311 K. The relationship between the structure of matrices intercalates with thermal properties and kinetic parameters of inclusion compounds is discussed.


fluorinated graphite inclusion compounds intercalates isothermal kinetics thermal stability 


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Copyright information

© Springer Science+Business Media, LLC. 2007

Authors and Affiliations

  • D. V. Pinakov
    • 1
  • V. A. Logvinenko
    • 1
  • Yu. V. Shubin
    • 1
  • G. N. Chekhova
    • 1
  1. 1.Nikolaev Institute of Inorganic ChemistrySiberian Branch of Russian Academy of SciencesNovosibirsk-90Russia

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