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Journal of Thermal Analysis and Calorimetry

, Volume 90, Issue 2, pp 399–405 | Cite as

The relationship between properties of fluorinated graphite intercalates and matrix composition

Part II. Intercalates with chloroform
  • D. V. Pinakov
  • V. A. Logvinenko
  • Yu. V. Shubin
  • G. N. Chekhova
Regular papers Material Science/Geosciences

Abstract

Inclusion compounds (intercalates) of fluorinated graphite matrix with chloroform (C2FxBrz·yCHCl3, x=0.49, 0.69, 0.87, 0.92, z=0.01) were synthesized by guest substitution from acetonitrile to chloroform. The kinetics of the thermal decomposition (the 1st stage of filling → the 2nd stage of filling) was studied under isothermal conditions at 286–311 K. The relationship between the structure of matrices intercalates with thermal properties and kinetic parameters of inclusion compounds is discussed.

Keywords

fluorinated graphite inclusion compounds intercalates isothermal kinetics thermal stability 

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References

  1. 1.
    D. V. Pinakov and V. A. Logvinenko, J. Therm. Anal. Cal., 86 (2006) 173.CrossRefGoogle Scholar
  2. 2.
    L. Mandelcorn, Ed., Non-Stoichiometric Compounds, Academic Press, New York and London 1964, p. 608.Google Scholar
  3. 3.
    O. A. Osipov, V. I. Minkin and Yu. B. Kletenik, Dipole Moments Reference Book, Rostov 1964, p. 242 (in Russian).Google Scholar
  4. 4.
    N. F. Yudanov and I. I. Yakovlev, Izv. Sib. Branch of USSR Acad. of Sciences, Ser. Chem. Sciences, Part 1 (1988), pp. 66–68.Google Scholar
  5. 5.
    V. M. Paasonen and A. S. Nazarov, Inorg. Mater., 37 (2001) 544 (in Russian).CrossRefGoogle Scholar
  6. 6.
    G. N. Chekhova, E. A. Ukraintseva, I. M. Ivanov, N. F. Yudanov, Yu. V. Shubin, V. A. Logvinenko, D. V. Pinakov, V. P. Fadeeva and N. I. Alferova., J. Inorg. Chem. 50 (2005) 1143 (in Russian).Google Scholar
  7. 7.
    N. F. Yudanov and L. I. Chernyavsky, J. Struct. Chem., 28 (1987) 86.Google Scholar
  8. 8.
    A. J. Gordon and R. A. Ford, The Chemist’s Companion, New York-London-Sydney-Tokyo 1972.Google Scholar
  9. 9.
    Chemical Reference Book, Volume 1, Moscow-Leningrad, 1962, Vol. 1, p. 694.Google Scholar
  10. 10.
    A. I. Kitaigrordsky, Molecular Crystals and Molecules, Academic Press, New York 1973.Google Scholar
  11. 11.
    J.-M. Lehn, Supramolecular Chemistry. Concepts and Perspectives. Weinheim-New York-Basel-Cambridge-Tokyo 1995.Google Scholar
  12. 12.
    K. I. Patrilyak, Inclusion compounds and certain problems of heterogeneous equilibria, Kiev, Naukova Dumka 1987 (in Russian).Google Scholar
  13. 13.
    V. A. Logvinenko, Thermal Analysis of Coordination Compounds and Clathrates, Novosibirsk, Nauk, Siberian Department, 1982 (in Russian).Google Scholar
  14. 14.
    Industrial Chloroorganic Products, L. A. Oshin, Ed., Moscow 1978, pp. 25–35 (in Russian).Google Scholar

Copyright information

© Springer Science+Business Media, LLC. 2007

Authors and Affiliations

  • D. V. Pinakov
    • 1
  • V. A. Logvinenko
    • 1
  • Yu. V. Shubin
    • 1
  • G. N. Chekhova
    • 1
  1. 1.Nikolaev Institute of Inorganic ChemistrySiberian Branch of Russian Academy of SciencesNovosibirsk-90Russia

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