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Journal of Thermal Analysis and Calorimetry

, Volume 86, Issue 3, pp 605–608 | Cite as

Synthesis, TG, DSC and infrared spectral study of NiMn2(C4H4O4)3·6N2H4

A precursor for NiMn2O4 nanoparticles
  • Reema A. Porob
  • Sitara Z. Khan
  • S. C. Mojumdar
  • V. M. S. Verenkar
Article

Abstract

Nickel manganese succinato-hydrazinate (NiMn2(C4H4O4)3·6N2H4), has been synthesized for the first time by a novel precursor technique and characterized by IR, AAS and XRD. Thermal decomposition of the compound was studied from room temperature (rT) to 800°C by differential scanning calorimetry (DSC) and thermogravimetric (TG) analysis besides isothermal mass loss studies. The compound was found to decompose autocatalytically, once ignited. TG-DSC shows two steps decomposition i.e. dehydrazination followed by decarboxylation. The infrared spectral studies show the N–N stretching frequency at 972 cm–1 suggesting a bidentate bridging structure of hydrazine molecule in (NiMn2(C4H4O4)3·6N2H4).

Keywords

DSC IR spectra NiMn2(C4H4O4)3·6N2H4 synthesis TG 

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Copyright information

© Springer-Verlag 2006

Authors and Affiliations

  • Reema A. Porob
    • 1
  • Sitara Z. Khan
    • 2
  • S. C. Mojumdar
    • 3
  • V. M. S. Verenkar
    • 4
  1. 1.Department of ChemistryGoa UniversityGoaIndia
  2. 2.Institut für Mechanische Verfahrenstechnik und MechanikUniversität Karlsruhe (TH)KarlsruheGermany
  3. 3.Institute for Research in ConstructionNational Research Council CanadaOttawaCanada
  4. 4.Institut für Technische Chemie und PolymerchemieUniversität Karlsruhe (TH)KarlsruheGermany

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