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Obtaining sols, gels and mesoporous nanopowders of hydrothermal nanosilica

  • Vadim Potapov
  • Roman FediukEmail author
  • Denis Gorev
Original Paper: Sol-gel, hybrids and solution chemistries
  • 33 Downloads

Abstract

Experiments were performed to obtain SiO2 sols, gels, and mesoporous nanopowders based on hydrothermal medium. To achieve this, polycondensation of orthosilicic acid (OSA) at certain pH and temperature, as well as ultrafiltration membrane concentration, sol–gel transition, and cryochemical vacuum sublimation were done. The dynamic light scattering, scanning and tunneling electron microscopy, low-temperature nitrogen adsorption, and others methods determined the physical and chemical characteristics of nanosized SiO2 samples. By choosing the pore size of the ultrafiltration membranes at the sol concentration stage, one can control the ratio of the SiO2 content to the total salt content and provide a zeta potential of nanoparticles sufficient for the stability of the sols. It was shown that by varying the temperature at the polycondensation stage from 20 to 90 °С at pH = 8.5–9.3, it is possible to control the final average diameter of SiO2 particles in the range from 5 to 100 nm, respectively. The specific surface area of particles are 50–500 m2/g, the average diameter of the mesoporous powders in the range of 2–15 nm; the fraction of the area (<4%) and volume (<0.25%) of micropores are low.

Highlights

  • Three forms of nanosilica produced from hydrothermal solution: liquid sols, gels, and solid powders.

  • Kinetic of orthosilicic acid regulated by temperature; diameters of silica particles are 5–100 nm.

  • By membrane pores, we separate silica nanoparticles from water molecules and ions of dissolved salts.

  • Specific surface areas of silica nanopowders can achieve 500 m2/g.

Keywords

Hydrothermal solution Kinetics of orthosilicic acid polycondensation Ultrafiltration membranes, Cryochemical vacuum sublimation SiO2 sols, Gels Nanopowders 

Notes

Compliance with ethical standards

Conflict of interest

The authors declare that they have no conflict of interest.

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Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2020

Authors and Affiliations

  1. 1.Research Geotechnological CenterFar Eastern Branch of Russian Academy of SciencesPetropavlovsk-KamchatskyRussian Federation
  2. 2.School of EngineeringFar Eastern Federal UniversityVladivostokRussian Federation

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