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  • Original Paper: Sol-gel and hybrid materials for catalytic, photoelectrochemical and sensor applications
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Fabrication and photocatalytic behavior of titanium oxide–gold nanoparticles composite ultrathin films prepared using surface sol–gel process

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Abstract

Ultrathin films consisting of titanium oxide and gold nanoparticles were prepared using a combination of the surface sol–gel process and liquid/liquid interfacial precipitation. The composite films had a titanium oxide/gold nanoparticle layer/titanium oxide film structure, comprising a gold nanoparticle thin-film layer sandwiched within titanium oxide films of nanometer-order thickness. Upon heating the titanium oxide–gold nanoparticle composite films to 450 °C, they underwent a phase change from the amorphous to the anatase phase, which was confirmed via Raman scattering analysis. It was observed that, even after heating, the plasmonic absorption band due to the presence of gold nanoparticles was maintained in the composite films. The photocatalytic degradation efficiencies of methylene blue dye were evaluated in films under 520 nm light irradiation. The results suggested that the sandwich-like structure of this titanium oxide/gold nanoparticle layer/titanium oxide is promising for the visible-light-induced degradation of methylene blue dye.

Highlights

  • A series of titanium oxide–gold nanoparticle composite thin films with nanometer thickness were prepared.

  • Formation of anatase titanium oxide ultrathin film was confirmed by Raman scattering analysis.

  • Sandwich-like structured titanium oxide/gold nanoparticle layer/titanium oxide composite ultrathin films is promising for the visible-light-driven photocatalyst.

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References

  1. 1.

    Fujishima A, Zhang X, Tryk DA (2008) Surf Sci Rep. 63:515–582

  2. 2.

    Oketani R, Miyake T, Jinnai S, Fukui T, Tsujimoto H, Matsumura M, Higashida S (2016) Chem Lett 45:801–803

  3. 3.

    Goto T, Ogawa M (2016) RSC Adv 6:23794–23797

  4. 4.

    Goto T, Ogawa M (2015) ACS Appl Mater Interfaces 7:12631–12634

  5. 5.

    Lang X, Chen X, Zhao J (2014) Chem Soc Rev 43:473–486

  6. 6.

    Mayer KM, Hafner JH (2011) Chem Rev 111:3828–3857

  7. 7.

    Atwater HA, Polman A (2010) Nat Mater 9:205

  8. 8.

    Kumaravel V, Mathew S, Bartlett J, Pillai SC (2019) Appl Catal B-Environ 244:1021–1064

  9. 9.

    Tatsuma T (2013) Bull Chem Soc Jpn 86:1–9

  10. 10.

    Tanaka A, Fuku K, Nishi T, Hashimoto K, Kominami H (2013) J Phys Chem C 117:16983–16989

  11. 11.

    Teranishi M, Hoshino R, Naya S, Tada H (2016) Angew Chem Int Ed Engl 55:12773–12777

  12. 12.

    Naya SI, Yamauchi J, Okubo T, Tada H (2017) Langmuir 33:10468–10472

  13. 13.

    Tian Y, Tatsuma T (2005) J Am Chem Soc 127:7632–7637

  14. 14.

    Du L, Furube A, Hara K, Katoh R, Tachiya M (2013) J Photochem Photobio C 15:21–30

  15. 15.

    Ichinose I, Senzu H, Kunitake T (1996) Chem Lett 25:831–832

  16. 16.

    Ichinose I, Kawakami T, Kunitake T (1998) Adv Mater 10:535–539

  17. 17.

    Arakawa T, Kawahara T, Akiyama T, Yamada S (2007) Jpn J Appl Phys 46:2490–2492

  18. 18.

    Akiyama T, Kawahara T, Arakawa T, Yamada S (2008) Jpn J Appl Phys 47:3063–3066

  19. 19.

    Matsumoto T, Akiyama T, Banya S, Izumoto D, Sakaguchi H, Oku T (2016) J Sol-Gel Sci Technol 78:692–697

  20. 20.

    Akiyama T, Hinoue M, Takishita T, Higashida S (2015) In The 13th meeting of the Japanese Sol-Gel Society. Hokkaido University, Japan, 84

  21. 21.

    Mitsukawa S, Akiyama T, Oku T (2017) In Annual meeting on photochemistry 2017. Tohoku University, Japan, 1P54

  22. 22.

    Akiyama T, Sakaguchi H (2017) In The 8th international symposium of advanced energy science. Kyoto University, Japan, ZE29A-22

  23. 23.

    Turkevich J, Stevenson PC, Hillier J (1951) Discuss Faraday Soc 11:55–75

  24. 24.

    Akiyama T (2012) e-J Surf Sci Nanotech 10:157–160

  25. 25.

    Suzuki M, Niidome Y, Kuwahara Y, Terasaki N, Inoue K, Yamada S (2004) J Phys Chem B 108:11660–11665

  26. 26.

    Akiyama T, Nakada M, Terasaki N, Yamada S (2006) Chem Commun 395–397

  27. 27.

    Ulman A (1991) An introduction to ultrathin organic films: from Langmuir-Blodgett to self-assembly. Academic Press, New York

  28. 28.

    Sugawa K, Tamura T, Tahara H, Yamaguchi D, Akiyama T, Otsuki J, Kusaka Y, Fukuda N, Ushijima H (2013) ACS Nano 7:9997–10010

  29. 29.

    Lubas M, Jasinski JJ, Sitarz M, Kurpaska L, Podsiad P, Jasinski J (2014) Spectrochim Acta A 133:867–871

  30. 30.

    Stagi L, Carbonaro CM, Corpino R, Chiriu D, Ricci PC (2015) Phys Status Solidi B 252:124–129

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Acknowledgements

This work is partially supported by the “Joint Usage/Research Program on Zero-Emission Energy Research,” Institute of Advanced Energy, Kyoto University (ZE29A-22, ZE30A-21, and ZE31A-26).

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Correspondence to Tsuyoshi Akiyama.

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Mitsukawa, S., Akiyama, T., Hinoue, M. et al. Fabrication and photocatalytic behavior of titanium oxide–gold nanoparticles composite ultrathin films prepared using surface sol–gel process. J Sol-Gel Sci Technol (2020) doi:10.1007/s10971-019-05214-w

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Keywords

  • Gold nanoparticle
  • Plasmon
  • Titanium oxide
  • Surface sol–gel process
  • Photocatalyst