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In situ sol–gel preparation of ZrO2 in nano-composite polymer electrolyte of PVDF-HFP/MG49 for lithium-ion polymer battery

  • Lee Tian KhoonEmail author
  • Mark-Lee Wun Fui
  • Nur Hasyareeda Hassan
  • Mohd Sukor Su’ait
  • Raman Vedarajan
  • Noriyoshi Matsumi
  • Mohammad Bin Kassim
  • Loh Kee Shyuan
  • Azizan AhmadEmail author
Original Paper: Sol-gel and hybrid materials for energy, environment and building applications
  • 37 Downloads

Abstract

Nano-composite polymer electrolyte (NCPE), poly(vinylidenefluoride-hexafluoropropylene)-poly(methylmethacrylate) grafted natural rubber with lithium tetrafluoroborate and zirconia (PVdF-HFP/MG49-LiBF4-ZrO2) was prepared by a facile one-pot in situ sol–gel method. The influence of zirconia nano-fillers on the electrochemical, chemical and structural properties of polymer electrolyte was investigated. The interaction of polymer electrolyte and zirconia was explored via density functional theory (DFT). Electrochemical impedance spectroscopy study showed that the optimum ionic conductivity is 2.39 × 10−3 S cm−1 (6 wt% zirconia). X-ray diffractogram results revealed a decreasing trend of crystalline phases and no lithium salt peaks were observed upon the addition of zirconia. As a result, the LiBF4 salt was well-solvated in the polymer matrix with a one-fold increase in lithium transference number. Remarkably, a good electrochemical stability was achieved at 6.9 V from a linear sweep voltammetry (LSV) analysis. Observations from the infrared spectra indicate that chemical interactions occurred at the carbonyl and fluoride functional groups and is further corroborated by DFT studies. Micrograph images showed that the zirconia nano-particles were successfully produced (7–15 nm). The nanocomposite polymer electrolyte possesses promising charge/discharge performance and has the potential to be applied in lithium-ion polymer battery.

The high electrochemical stability and flexible nanocomposite for lithium ion polymer battery application.

Highlights

  • The sizes of ZrO2 nano-particles are in the range of 7–15 nm.

  • High ionic conductivity (2.39 × 10−3 S cm−1) and electrochemical stability (6.9 V) was achieved for the nanocomposite polymer electrolyte sample.

  • Nano-particle zirconia improved the lithium transference number by a fold from 0.103 to 0.216.

  • The nanocomposite polymer electrolyte was able to maintain a good ionic conductivity (~10−5 S cm−1) at a high temperature of 200 °C.

Keywords

Nanocomposite polymer electrolyte Zirconia In situ sol–gel One pot preparation Lithium-ion polymer battery DFT 

Notes

Acknowledgements

The authors would like to acknowledge National University of Malaysia for the research facilities and sponsoring this project under Modal Insan UKM (MI-2018-002 and MI-2018-012) and INOVASI-2017-011. We would also like to thank UKM and Mr. Patrick Tan Sang Hup from KGC Resources Sdn. Bhd. for providing part of the financial support under INOVASI-2017-011. Special thanks to the Japan Student Services Organization (JASSO) for sponsoring the internship program in Japan. Many thanks to Prof. Hideaki Kasai, Prof. Wilson Agerico Diño and Osaka University, Japan for supporting us with the quantum computational facilities.

Compliance with ethical standards

Conflict of interest

The authors declare that they have no conflict of interest.

Supplementary material

10971_2019_4936_MOESM1_ESM.docx (4.2 mb)
Supplementary data.

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Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2019

Authors and Affiliations

  • Lee Tian Khoon
    • 1
    Email author
  • Mark-Lee Wun Fui
    • 2
  • Nur Hasyareeda Hassan
    • 2
  • Mohd Sukor Su’ait
    • 3
  • Raman Vedarajan
    • 4
  • Noriyoshi Matsumi
    • 5
  • Mohammad Bin Kassim
    • 2
  • Loh Kee Shyuan
    • 1
  • Azizan Ahmad
    • 2
    Email author
  1. 1.Fuel Cell Institute (FCI)Universiti Kebangsaan MalaysiaBangiMalaysia
  2. 2.School of Chemical Sciences and Food Technology, Faculty of Science and TechnologyUniversiti Kebangsaan MalaysiaBangiMalaysia
  3. 3.Solar Energy Research Institute (SERI)Universiti Kebangsaan MalaysiaBangiMalaysia
  4. 4.International Advanced Research Centre for Powder Metallurgy and New Materials (ARCI)HyderabadIndia
  5. 5.School of Materials ScienceJapan Advanced Institute of Science and TechnologyIshikawaJapan

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