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Novel and inexpensive Nb2O5/tannin-formaldehyde xerogel composites as substitutes for titanium dioxide in photocatalytic processes

  • Nicolas Perciani de Moraes
  • Leticia Araujo Bacetto
  • Livia Kent Paiva
  • Gabriela Spirandelli dos Santos
  • Maria Lucia Caetano Pinto da Silva
  • Liana Alvares RodriguesEmail author
Original Paper: Sol-gel and hybrid materials for catalytic, photoelectrochemical and sensor applications
  • 22 Downloads

Abstract

This project studied the preparation of new Nb2O5/tannin-formaldehyde xerogel composites (XTF-wNb) for photocatalytical applications. The choice of tannin biomass and niobium recycled scraps as precursors is aimed at reducing costs and environmental impacts. The composites were characterized by diffuse reflectance spectroscopy (DR), scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), infrared spectroscopy (IR), and X-ray diffraction (XRD). The photocatalytic properties of the composites were evaluated by methylene blue decomposition. The influence of the catalyst dosage and the initial concentration of dye in the adsorption and photocatalysis processes were studied. The X-ray profiles of the XTF-wNb show the presence of niobic acid in the structure of the materials, proving the presence of the inorganic oxide in the matrix of these composites. The tannin/Nb ratio had a significant influence on the morphology of the formed composites, causing changes in the shape and size of the particles composing each material. All materials have pHPZC < 5. The XTF-24Nb was the most effective photocatalyst, its photocatalytic efficiency superior to the one of titanium dioxide, evidencing the beneficial effect of the xerogel coupling on the photocatalytic properties of the material.

The graphical abstract portrays an illustration of the composites produced in this work, as well as a timeline view of the photocatalytic process employed

Highlights

  • Composites were made using low-cost materials, such as tannin and recycled niobium.

  • Composites showed photocatalytic activity at all wavelengths tested.

  • The XTF-24Nb composite presented virtually the same efficiency than that of titanium dioxide.

Keywords

Photocatalysis Niobium oxide Tannin Xerogel 

Notes

Acknowledgements

This study was financed in part by the Coordenação de Aperfeiçoamento de Pessoal de Nível Superior - Brasil (CAPES) - Finance Code 001 and by the São Paulo Research Foundation (FAPESP) (Grants No. 2015/08995-7, No. 2016/04244-0 and No. 2016/20920-5). The authors are grateful to TANAC SA Company, which supplied the black wattle tannin.

Compliance with ethical standards

Conflict of interest

The authors declare that they have no conflict of interest.

References

  1. 1.
    Bandara J, Kuruppu SS, Pradeep UW (2006) The promoting effect of MgO layer in sensitized photodegradation of colorants on TiO2/MgO composite oxide. Colloids Surf A Physicochem Eng Asp 276:197–202.  https://doi.org/10.1016/j.colsurfa.2005.10.059 CrossRefGoogle Scholar
  2. 2.
    Basturk E, Karatas M (2015) Decolorization of antraquinone dye Reactive Blue 181 solution by UV/H2O2 process. J Photochem Photobiol A Chem 299:67–72.  https://doi.org/10.1016/j.jphotochem.2014.11.003 CrossRefGoogle Scholar
  3. 3.
    Peng Z, Liu X, Lin G (2017) The synergistic degreasing treatment of background irradiated photocatalysis and microreactor. Catal Commun 90:79–82.  https://doi.org/10.1016/j.catcom.2016.11.008 CrossRefGoogle Scholar
  4. 4.
    Macedo LC, Pauli ED, Zaia DAM, de Santana H (2006) Remediação de águas residuais por Fotocatálise Heterogênea: Estudo dos parâmetros experimentais aplicados a fotocatálise eletroquímica. Semin Ciências Exatas E Tecnológicas 27:11–21. http://www.uel.br/revistas/uel/index.php/semexatas/article/view/1597 CrossRefGoogle Scholar
  5. 5.
    Kudo A, Miseki Y (2009) Heterogeneous photocatalyst materials for water splitting. Chem Soc Rev 38:253–278.  https://doi.org/10.1039/b800489g CrossRefGoogle Scholar
  6. 6.
    de Souza ML, Corio P (2013) Effect of silver nanoparticles on TiO2-mediated photodegradation of Alizarin Red S. Appl Catal B Environ 136–137:325–333.  https://doi.org/10.1016/j.apcatb.2013.02.012 CrossRefGoogle Scholar
  7. 7.
    Han F, Kambala VSR, Srinivasan M, Rajarathnam D, Naidu R (2009) Tailored titanium dioxide photocatalysts for the degradation of organic dyes in wastewater treatment: a review. Appl Catal A Gen 359:25–40.  https://doi.org/10.1016/j.apcata.2009.02.043 CrossRefGoogle Scholar
  8. 8.
    Li J, Xu X, Liu X, Qin W, Wang M, Pan L (2017) Metal-organic frameworks derived cake-like anatase/rutile mixed phase TiO2 for highly efficient photocatalysis. J Alloy Compd 690:640–646.  https://doi.org/10.1016/j.jallcom.2016.08.176 CrossRefGoogle Scholar
  9. 9.
    Long D, Zhang J, Yang J, Hu Z, Li T, Cheng G, Zhang R, Ling L (2008) Preparation and microstructure control of carbon aerogels produced using m-cresol mediated sol-gel polymerization of phenol and furfural. New Carbon Mater 23:165–170.  https://doi.org/10.1016/S1872-5805(08)60020-7 CrossRefGoogle Scholar
  10. 10.
    Tamon H, Ishizaka H, Yamamoto T, Suzuki T (2000) Influence of freeze-drying conditions on the mesoporosity of organic gels as carbon precursors. Carbon N Y 38:1099–1105.  https://doi.org/10.1016/S0008-6223(99)00235-3 CrossRefGoogle Scholar
  11. 11.
    Al-Muhtaseb SA, Ritter JA (2003) Preparation and properties of resorcinol-formaldehyde organic and carbon gels. Adv Mater 15:101–114.  https://doi.org/10.1002/adma.200390020 CrossRefGoogle Scholar
  12. 12.
    dos CRA, Queiroz A, de Morais SAL, do Nascimento EA (2002) Caracterizaçao dos taninos da aroeira-preta (Myracrodruon urundeuva), Rev. Árvore 26:485–492.  https://doi.org/10.1590/S0100-67622002000400011 CrossRefGoogle Scholar
  13. 13.
    Kraiwattanawong K, Mukai SR, Tamon H, Lothongkum AW (2008) Control of mesoporous properties of carbon cryogels prepared from wattle tannin and furfural. J Porous Mater 15:695–703.  https://doi.org/10.1007/s10934-007-9155-x CrossRefGoogle Scholar
  14. 14.
    Moraes N, Caetano L, Tiago S, Bastos M, Patrocínio G, Liana T, Rodrigues A (2018) Novel synthetic route for low-cost carbon-modified TiO2 with enhanced visible light photocatalytic activity: carbon content and calcination effects. J Sol-Gel Sci Technol (2018).  https://doi.org/10.1007/s10971-018-4700-4
  15. 15.
    Prado AGS, Bolzon LB, Pedroso CP, Moura AO, Costa LL (2008) Nb2O5 as efficient and recyclable photocatalyst for indigo carmine degradation. Appl Catal B Environ 82:219–224.  https://doi.org/10.1016/j.apcatb.2008.01.024 CrossRefGoogle Scholar
  16. 16.
    Hashemzadeh F, Rahimi R, Ghaffarinejad A (2014) Mesoporous nanostructures of Nb2O5 obtained by an EISA route for the treatment of malachite green dye-contaminated aqueous solution under UV and visible light irradiation. Ceram Int 40:9817–9829.  https://doi.org/10.1016/j.ceramint.2014.02.072 CrossRefGoogle Scholar
  17. 17.
    de Moraes NP, Bacani R, da Silva MLCP, Campos TMB, Thim GP, Rodrigues LA (2018) Effect of Nb/C ratio in the morphological, structural, optical and photocatalytic properties of novel and inexpensive Nb2O5/carbon xerogel composites. Ceram Int 44:6645–6652.  https://doi.org/10.1016/j.ceramint.2018.01.073 CrossRefGoogle Scholar
  18. 18.
    Wang L, Zhang J, Wang A (2008) Removal of methylene blue from aqueous solution using chitosan-g-poly(acrylic acid)/montmorillonite superadsorbent nanocomposite. Colloids Surf A Physicochem Eng Asp 322:47–53.  https://doi.org/10.1016/j.colsurfa.2008.02.019 CrossRefGoogle Scholar
  19. 19.
    Dong W, Lee CW, Lu X, Sun Y, Hua W, Zhuang G, Zhang S, Chen J, Hou H, Zhao D (2010) Synchronous role of coupled adsorption and photocatalytic oxidation on ordered mesoporous anatase TiO2-SiO2 nanocomposites generating excellent degradation activity of RhB dye. Appl Catal B Environ 95:197–207.  https://doi.org/10.1016/j.apcatb.2009.12.025 CrossRefGoogle Scholar
  20. 20.
    Houas A (2001) Photocatalytic degradation pathway of methylene blue in water. Appl Catal B Environ 31:145–157.  https://doi.org/10.1016/S0926-3373(00)00276-9 CrossRefGoogle Scholar
  21. 21.
    Yang X, Cao C, Erickson L, Hohn K, Maghirang R, Klabunde K (2009) Photo-catalytic degradation of Rhodamine B on C-, S-, N-, and Fe-doped TiO2 under visible-light irradiation. Appl Catal B Environ 91:657–662.  https://doi.org/10.1016/j.apcatb.2009.07.006 CrossRefGoogle Scholar
  22. 22.
    Dong W, Pan F, Wang Y, Xiao S, Wu K, Xu GQ, Chen W (2017) Surfactant-free synthesis of hierarchical niobic acid microflowers assembled from ultrathin nanosheets with efficient photoactivities. Appl Surf Sci 392:514–522.  https://doi.org/10.1016/j.apsusc.2016.09.085 CrossRefGoogle Scholar
  23. 23.
    de Moraes NP, Silva FN, da Silva MLCP, Campos TMB, Thim GP, Rodrigues LA (2018) Methylene blue photodegradation employing hexagonal prism-shaped niobium oxide as heterogeneous catalyst: effect of catalyst dosage, dye concentration, and radiation source. Mater Chem Phys 214:95–106.  https://doi.org/10.1016/j.matchemphys.2018.04.063 CrossRefGoogle Scholar
  24. 24.
    Chang T, Li Z, Yun G, Jia Y, Yang H (2013) Enhanced photocatalytic activity of ZnO/CuO nanocomposites synthesized by hydrothermal method. Nano-Micro Lett 5:163–168.  https://doi.org/10.1007/BF03353746 CrossRefGoogle Scholar
  25. 25.
    Zhao C, Tan G, Yang W, Xu C, Liu T, Su Y, Ren H, Xia A (2016) Fast interfacial charge transfer in α-Fe2O3-σCσ/FeVO4-x+σCx-σ; @C bulk heterojunctions with controllable phase content. Sci Rep 6:1–10.  https://doi.org/10.1038/srep38603 CrossRefGoogle Scholar
  26. 26.
    Zhao W, Zhao W, Zhu G, Lin T, Xu F, Huang F, Black (2016) Nb2O5 nanorods with improved solar absorption and enhanced photocatalytic activity. Dalt Trans 45:3888–3894.  https://doi.org/10.1039/C5DT04578A CrossRefGoogle Scholar
  27. 27.
    Ghobadi N (2013) Band gap determination using absorption spectrum fitting procedure, Int. Nano Lett 3:2.  https://doi.org/10.1186/2228-5326-3-2 CrossRefGoogle Scholar
  28. 28.
    Macedo ER, Oliveira PS, Oliveira HPDe (2015) Synthesis and characterization of branched polypyrrole/titanium dioxide photocatalysts J Photochem Photobiol A Chem 307–308:108–114.  https://doi.org/10.1016/j.jphotochem.2015.04.013 CrossRefGoogle Scholar
  29. 29.
    Aegerter MA (2001) Sol-gel niobium pentoxide: a promising material for electrochromic coatings, batteries, nanocrystalline solar cells and catalysis. Sol Energy Mater Sol Cells 68:401–422.  https://doi.org/10.1016/S0927-0248(00)00372-X CrossRefGoogle Scholar
  30. 30.
    Wu T, Huang K, Liu S, Zhuang S, Fang D, Li S, Lu D, Su A (2012) Hydrothermal ammoniated treatment of PAN-graphite felt for vanadium redox flow battery. J Solid State Electrochem 16:579–585.  https://doi.org/10.1007/s10008-011-1383-y CrossRefGoogle Scholar
  31. 31.
    Fang L, Cai P, Chen W, Liang W, Hong Z, Huang Q (2009) Impact of cell wall structure on the behavior of bacterial cells in the binding of copper and cadmium, Colloids. Surf A Physicochem Eng Asp 347:50–55.  https://doi.org/10.1016/j.colsurfa.2008.11.041 CrossRefGoogle Scholar
  32. 32.
    Puziy AM, Poddubnaya OI (2002) Synthetic carbons activated with phosphoric acid I. Surface chemistry and ion binding properties. Carbon N Y 40:1493–1505CrossRefGoogle Scholar
  33. 33.
    Achladas GE (1991) Analysis of biomass pyrolysis liquids: separation and characterization of phenols. J Chromatogr A 542:263–275.  https://doi.org/10.1016/S0021-9673(01)88766-5 CrossRefGoogle Scholar
  34. 34.
    Blázquez G, Hernáinz F, Calero M, Martín-Lara MA, Tenorio G (2009) The effect of pH on the biosorption of Cr (III) and Cr (VI) with olive stone. Chem Eng J 148:473–479.  https://doi.org/10.1016/j.cej.2008.09.026 CrossRefGoogle Scholar
  35. 35.
    Wang F, Wu HZ, Liu CL, Yang RZ, Dong WS (2013) Catalytic dehydration of fructose to 5-hydroxymethylfurfural over Nb2O5 catalyst in organic solvent. Carbohydr Res 368:78–83.  https://doi.org/10.1016/j.carres.2012.12.021 CrossRefGoogle Scholar
  36. 36.
    Ma X, Chen Y, Li H, Cui X, Lin Y (2015) Annealing-free synthesis of carbonaceous Nb2O5 microspheres by flame thermal method and enhanced photocatalytic activity for hydrogen evolution. Mater Res Bull 66:51–58.  https://doi.org/10.1016/j.materresbull.2015.02.005 CrossRefGoogle Scholar
  37. 37.
    Ristić M, Popović S, Musić S (2004) Sol-gel synthesis and characterization of Nb2O5 powders. Mater Lett 58:2658–2663.  https://doi.org/10.1016/j.matlet.2004.03.041 CrossRefGoogle Scholar
  38. 38.
    do Prado NT, Oliveira LCA (2017) Nanostructured niobium oxide synthetized by a new route using hydrothermal treatment: high efficiency in oxidation reactions. Appl Catal B Environ 205:481–488.  https://doi.org/10.1016/j.apcatb.2016.12.067 CrossRefGoogle Scholar
  39. 39.
    Lopes OF, Paris EC, Ribeiro C (2014) Synthesis of Nb2O5 nanoparticles through the oxidant peroxide method applied to organic pollutant photodegradation: a mechanistic study. Appl Catal B Environ 144:800–808.  https://doi.org/10.1016/j.apcatb.2013.08.031 CrossRefGoogle Scholar
  40. 40.
    Rodrigues LA, da Silva MLCP, Alvarez-Mendes MO, dos A, Coutinho R, Thim GP (2011) Phenol removal from aqueous solution by activated carbon produced from avocado kernel seeds. Chem Eng J 174:49–57.  https://doi.org/10.1016/j.cej.2011.08.027 CrossRefGoogle Scholar
  41. 41.
    Singh KP, Malik A, Sinha S, Ojha P (2008) Liquid-phase adsorption of phenols using activated carbons derived from agricultural waste material. J Hazard Mater 150:626–641.  https://doi.org/10.1016/j.jhazmat.2007.05.017 CrossRefGoogle Scholar
  42. 42.
    Kusiak-Nejman E, Janus M, Grzmil B, Morawski AW (2011) Methylene Blue decomposition under visible light irradiation in the presence of carbon-modified TiO2 photocatalysts. J Photochem Photobiol A Chem 226:68–72.  https://doi.org/10.1016/j.jphotochem.2011.10.018 CrossRefGoogle Scholar
  43. 43.
    de Moraes NP, Carvalho T, da Silva MLCP, Campos TMB, Thim GP, Rodrigues LA (2017) A novel synthesis route of titanium dioxide with (NH4)0.3TiO1.1F2.1 as by-product. Ceram Int 43:13677–13682.  https://doi.org/10.1016/j.ceramint.2017.07.078 CrossRefGoogle Scholar
  44. 44.
    Janani S, Sudha Rani KS, Ellappan P, Miranda LR (2016) Photodegradation of methylene blue using magnetically reduced graphene oxide bismuth oxybromide composite. J Environ Chem Eng 4:534–541.  https://doi.org/10.1016/j.jece.2015.10.043 CrossRefGoogle Scholar
  45. 45.
    Joseph CG, Taufiq-Yap YH, Li Puma G, Sanmugam K, Quek KS (2016) Photocatalytic degradation of cationic dye simulated wastewater using four radiation sources, UVA, UVB, UVC and solar lamp of identical power output. Desalin Water Treat 57:7976–7987.  https://doi.org/10.1080/19443994.2015.1063463 CrossRefGoogle Scholar
  46. 46.
    Shaban YA, El Sayed MA, El Maradny AA, Al Farawati RK, Al Zobidi MI, Khan SUM (2016) Photocatalytic removal of polychlorinated biphenyls (PCBs) using carbon-modified titanium oxide nanoparticles. Appl Surf Sci 365:108–113.  https://doi.org/10.1016/j.apsusc.2016.01.001 CrossRefGoogle Scholar
  47. 47.
    Zhang H, Tang Y, Cai D, Liu X, Wang X, Huang Q, Yu Z (2010) Hexavalent chromium removal from aqueous solution by algal bloom residue derived activated carbon: equilibrium and kinetic studies. J Hazard Mater 181:801–808.  https://doi.org/10.1016/j.jhazmat.2010.05.084 CrossRefGoogle Scholar
  48. 48.
    Liang Z, Cao Y, Qin H, Jia D (2016) Low-heating solid-state chemical synthesis of monoclinic scheelite BiVO4 with different morphologies and their enhanced photocatalytic property under visible light. Mater Res Bull 84:397–402.  https://doi.org/10.1016/j.materresbull.2016.08.038 CrossRefGoogle Scholar
  49. 49.
    Jones W, Martin DJ, Caravaca A, Beale AM, Bowker M, Maschmeyer T, Hartley G, Masters A (2016) A comparison of photocatalytic reforming reactions of methanol and triethanolamine with Pd supported on titania and graphitic carbon nitride. Appl Catal B Environ 1–7.  https://doi.org/10.1016/j.apcatb.2017.01.042
  50. 50.
    Chen X, Dai Y, Huang W (2015) Novel Ag3PO4/ZnFe2O4 composite photocatalyst with enhanced visible light photocatalytic activity. Mater Lett 145:125–128.  https://doi.org/10.1016/j.matlet.2015.01.097 CrossRefGoogle Scholar
  51. 51.
    Bancirova M (2011) Sodium azide as a specific quencher of singlet oxygen during chemiluminescent detection by luminol and Cypridina luciferin analogues. Luminescence 26:685–688.  https://doi.org/10.1002/bio.1296 CrossRefGoogle Scholar
  52. 52.
    Liu H, Gao N, Liao M, Fang X (2015) Hexagonal-like Nb2O5 nanoplates-based photodetectors and photocatalyst with high performances. Sci Rep 5:1–9.  https://doi.org/10.1038/srep07716 CrossRefGoogle Scholar
  53. 53.
    Nosaka Y, Nosaka AY (2017) Generation and detection of reactive oxygen species in photocatalysis. Chem Rev 117:11302–11336.  https://doi.org/10.1021/acs.chemrev.7b00161 CrossRefGoogle Scholar
  54. 54.
    Zhang L, Ni C, Jiu H, Xie C, Yan J, Qi G (2017) One-pot synthesis of Ag-TiO2/reduced graphene oxide nanocomposite for high performance of adsorption and photocatalysis. Ceram Int 43:5450–5456.  https://doi.org/10.1016/j.ceramint.2017.01.041 CrossRefGoogle Scholar
  55. 55.
    Li B, Yuan H, Yang P, Yi B, Zhang Y (2016) Fabrication of the composite nanofibers of NiO/γ-Al2O3 for potential application in photocatalysis. Ceram Int 42:17405–17409.  https://doi.org/10.1016/j.ceramint.2016.08.040 CrossRefGoogle Scholar
  56. 56.
    Hashemzadeh F, Rahimi R, Gaffarinejad A (2013) Photocatalytic degradation of Methylene blue and Rhodamine B dyes by niobium oxide nanoparticles synthesized via hydrothermal method. Int J Appl Chem Sci Res 1:95–102Google Scholar
  57. 57.
    Rauf MA, Meetani MA, Khaleel A, Ahmed A (2010) Photocatalytic degradation of Methylene Blue using a mixed catalyst and product analysis by LC/MS. Chem Eng J 157:373–378.  https://doi.org/10.1016/j.cej.2009.11.017 CrossRefGoogle Scholar
  58. 58.
    Gnaser H, Savina MR, Calaway WF, Tripa CE, Veryovkin IV, Pellin MJ (2005) Photocatalytic degradation of methylene blue on nanocrystalline TiO2: surface mass spectrometry of reaction intermediates. Int J Mass Spectrom 245:61–67.  https://doi.org/10.1016/j.ijms.2005.07.003 CrossRefGoogle Scholar

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© Springer Science+Business Media, LLC, part of Springer Nature 2018

Authors and Affiliations

  • Nicolas Perciani de Moraes
    • 1
  • Leticia Araujo Bacetto
    • 1
  • Livia Kent Paiva
    • 1
  • Gabriela Spirandelli dos Santos
    • 1
  • Maria Lucia Caetano Pinto da Silva
    • 1
  • Liana Alvares Rodrigues
    • 1
    Email author return OK on get
  1. 1.Chemical engineering departmentEngineering School of Lorena - EEL/USPSão PauloBrazil

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