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Journal of Sol-Gel Science and Technology

, Volume 84, Issue 1, pp 206–213 | Cite as

Structural, morphological and optical properties of SnO2 nanoparticles obtained by a proteic sol–gel method and their application in dye-sensitized solar cells

  • M. S. PereiraEmail author
  • F. A. S. Lima
  • C. B. Silva
  • P. T. C. Freire
  • I. F. Vasconcelos
Original Paper: Sol-gel and hybrid materials for optical, photonic and optoelectronic applications

Abstract

Tin dioxide nanoparticles were synthesized by the proteic sol–gel method. Tin chloride (SnCl4·5H2O) was used as source of Sn4+ and commercial gelatin as organic precursor. Several calcination temperatures were employed. Thermogravimetric analysis and differential scanning calorimetry were performed to investigate the thermal behavior of the precursor powders as well as to select the appropriate calcination temperatures for oxide formation. Structural, morphological, and optical properties of the synthesized materials were studied by X-ray diffraction, transmission electron microscopy, Fourier transformed infrared spectroscopy, and ultraviolet–visible spectroscopy. The results confirmed the formation of spherical nanoparticles of rutile SnO2 with an optical absorption band in the ultraviolet region near the visible light range. Thermally treated samples showed improved crystallinity and superior transparency to visible light. These SnO2 nanoparticles were successfully employed as photoanode material in dye-sensitized solar cells. The performance of the cells was evaluated by measuring J × V curves in a solar simulator and was found to be in line with results in the literature.

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Keywords

SnO2 nanoparticles Proteic sol–gel method Dye-sensitized solar cells Emerging technologies 

Notes

Acknowledgements

The authors are grateful to the Brazilian research agencies Fundação Cearense de Apoio ao Desenvolvimento Cientfico e Tecnológico (FUNCAP) and Conselho Nacional de Desenvolvimento Cientfico e Tecnológico (CNPq) for financial support. Dra. Monica Lira-Cantú and the Catalan Institute of Nanoscience and Nanotechnology (ICN2) for lending infrastructure used to develop this study. SEM measurements were performed at UFC’s Central Analtica.

Compliance with ethical standards

Conflict of interest

The authors declare that they have no competing interests.

References

  1. 1.
    Chang CH, Gong M, Dey S, Liu F, Castro RHC (2015) Thermodynamic stability of SnO2 nanoparticles: The role of interface energies and dopants. J Phys Chem C 119:6389–6397CrossRefGoogle Scholar
  2. 2.
    Priya SM, Geetha A, Ramamurthi K (2016) Structural, morphological and optical properties of tin oxide nanoparticles synthesized by sol–gel method adding hydrochloric acid. J Sol–Gel Sci Technol 78:365–372CrossRefGoogle Scholar
  3. 3.
    Rechberger F, Städler R, Tervoort E, Niederberger M (2016) Strategies to improve the electrical conductivity of nanoparticle-based antimony-doped tin oxide aerogels. J Sol–Gel Sci Technol 80:660–666CrossRefGoogle Scholar
  4. 4.
    Beltrán JJ, Sánchez LC, Osorio J, Tirado L, Baggio-Saitovitch EM, Barrero CA (2010) Crystallographic and magnetic properties of Fe-doped SnO2 nanopowders obtained by a sol–gel method. J Mater Sci 45:5002–5011CrossRefGoogle Scholar
  5. 5.
    Diéguez A, Romano-Rodrguez A, Vilà A, Morante JR (2001) The complete Raman spectrum of nanometric SnO2 particles. J Appl Phys 90:1557CrossRefGoogle Scholar
  6. 6.
    Pereira MS, Lima FAS, Ribeiro TS, da Silva MR, Almeida RQ, Barros EB, Vasconcelos IF (2017) Application of Fe-doped SnO2 nanoparticles in organic solar cells with enhanced stability. Opt Mater 64:548–556CrossRefGoogle Scholar
  7. 7.
    Trost S, Becker T, Polywka A, Görrn P, Oszajca MF, Luechinger NA, Rogalla D, Weidner M, Reckers P, Mayer T, Riedl T (2016) Avoiding photoinduced shunts in organic solar cells by the use of tin oxide (SnOx) as electron extraction material instead of ZnO. Adv Energy Mater 6:1600347CrossRefGoogle Scholar
  8. 8.
    Birkel A, Lee YG, Koll D, Van Meerbeek X, Frank S, Choi MJ, Kang YS, Char K, Tremel W (2012) Highly efficient and stable dye-sensitized solar cells based on SnO2 nanocrystals prepared by microwave-assisted synthesis. Energy Environ Sci 5:5392CrossRefGoogle Scholar
  9. 9.
    Pal M, Bera S, Jana S (2015) Sol–gel based simonkolleite nanopetals with SnO2 nanoparticles in graphite-like amorphous carbon as an efficient and reusable photocatalyst. RSC Adv 5:75062CrossRefGoogle Scholar
  10. 10.
    Sun J, Sun P, Zhang D, Xu J, Liang X, Liu F, Lu G (2014) Growth of SnO2 nanowire arrays by ultrasonic spray pyrolysis and their gas sensing performance. RSC Adv 4:43429CrossRefGoogle Scholar
  11. 11.
    Mei L, Chen Y, Ma J (2013) Gas sensing of SnO2 nanocrystals revisited: developing ultra-sensitive sensors for detecting the H2S leakage of biogas. Scientific Reports 4:6028CrossRefGoogle Scholar
  12. 12.
    Mueller F, Bresser D, Chakravadhanula VSK, Passerini S (2015) Fe-doped SnO2 nanoparticles as new high capacity anode material for secondary lithium-ion batteries. J Power Sources 299:398–402CrossRefGoogle Scholar
  13. 13.
    Ahmed SA (2010) Room-temperature ferromagnetism in pure and Mn doped SnO2 powders. Solid State Commun 150:2190CrossRefGoogle Scholar
  14. 14.
    Ferrari S, Pampillo LG, Saccone FD (2016) Magnetic properties and environment sites in Fe-doped SnO2 nanoparticles. Mater Chem Phys 177:206–212CrossRefGoogle Scholar
  15. 15.
    Shayesteh SF, Nosrati R (2015) The structural and magnetic properties of diluted magnetic semiconductor Zn1-xNixO nanoparticles. J Supercond Nov Magn 28:1821–1826CrossRefGoogle Scholar
  16. 16.
    Mehraj S, Ansari MS, Alimuddin (2015) Structural, electrical and magnetic properties of (Fe, Co) co-doped SnO2 diluted magnetic semiconductor nanostructures. Phys E 65:84–92CrossRefGoogle Scholar
  17. 17.
    Inpasalin MS, Choubey RK, Mukherjee S (2016) Evidence of bound magnetic polaron-mediated weak ferromagnetism in co-doped SnO2 nanocrystals: microstructural, optical, hyperfine, and magnetic investigations. J Electron Mater 45:3562–3569CrossRefGoogle Scholar
  18. 18.
    Meneses CT, Flores WH, Garcia F, Sasaki JM (2007) A simple route to the synthesis of high-quality NiO nanoparticles. J Nano Res 9:501–505CrossRefGoogle Scholar
  19. 19.
    Nogueira NAS, Utuni VHS, Silva YC, Kiyohara PK, Vasconcelos IF, Miranda MAR, Sasaki JM (2015) X-ray diffraction and Mossbauer studies on superparamagnetic nickel ferrite (NiFe2O4) obtained by the proteic sol–gel method. Mater Chem Phys 163:402–406CrossRefGoogle Scholar
  20. 20.
    Braga TP, Dias DF, de Sousa MF, Soares JM, Sasaki JM (2015) Synthesis of air stable FeCo alloy nanocrystallite by proteic sol–gel method using a rotary oven. J Alloy Compd 622:408–417CrossRefGoogle Scholar
  21. 21.
    Santos CM, Martins AFN, Costa BC, Ribeiro TS, Braga TP, Soares JM, Sasaki JM (2016) Synthesis of FeNi alloy nanomaterials by proteic sol–gel method: crystallographic, morphological, and magnetic properties. J Nanomater 2016:1–9CrossRefGoogle Scholar
  22. 22.
    Rietveld HM (1967) Line profiles of neutron powder-diffraction peaks for structure refinement. Acta Cryst 22:151CrossRefGoogle Scholar
  23. 23.
    Rietveld HM (1969) A profile refinement method for nuclear and magnetic structures. J Appl Cryst 2:65CrossRefGoogle Scholar
  24. 24.
    Toby BH (2001) EXPGUI, a graphical user interface for GSAS. J Appl Cryst 34:210CrossRefGoogle Scholar
  25. 25.
    Zhao B, Fan B, Xu Y, Shao G, Wang X, Zhao W, Zhang R (2015) Preparation of honeycomb SnO2 foams and configuration-dependent microwave absorption features. ACS Appl Mater Inter 7:26217–26225CrossRefGoogle Scholar
  26. 26.
    Liu J, Li X, Chen X, Niu H, Han X, Zhang T, Lin H, Qu F (2016) Synthesis of SnO2/In2O3 hetero-nanotubes by coaxial-electrospinning method for enhanced formaldehyde response. New J Chem 40:1756CrossRefGoogle Scholar
  27. 27.
    Ghodsi FE, Tepehan FZ, Tepehan GG (2011) Derivation of the optical constants of spin coated CeO2–TiO2–ZrO2 thin films prepared by sol–gel route. J Phys Chem Solid 72:761–767CrossRefGoogle Scholar
  28. 28.
    Williamson GK, Hall WH (1953) X-ray line broadening from filed aluminum and wolfram. Acta Metall 1:22CrossRefGoogle Scholar
  29. 29.
    Aragón FH, Coaquira JAH, Nagamine LCCM, Cohen R, da Silva SW, Morais PC (2015) Thermal-annealing effects on the structural and magnetic properties of 10% Fe-doped Sn2O nanoparticles synthetized by a polymer precursor method. J Magn Magn Mater 375:74–79CrossRefGoogle Scholar
  30. 30.
    Smith BC (2016) The infrared spectroscopy of Alkenes. Spectroscopy 31:28–34Google Scholar
  31. 31.
    Lim AH, Shim HW, Seo SD, Lee GH, Park KS, Kim DW (2012) Biomineralized Sn-based multiphasic nanostructures for li-ion battery electrodes. Nanoscale 4:4694CrossRefGoogle Scholar
  32. 32.
    Zhu H, Yang D, Yu G, Zhang H, Kuihong Yao K (2006) A simple hydrothermal route for synthesizing SnO2 quantum dots. Nanotechnology 17:2386–2389CrossRefGoogle Scholar
  33. 33.
    Zhang J, Gao L (2004) Synthesis and characterization of nanocrystalline tin oxide by sol–gel method. J Solid State Chem 177:1425–1430CrossRefGoogle Scholar
  34. 34.
    Chen H, Ding L, Sun W, Jiang Q, Hu J, Li J (2015) Synthesis and characterization of Ni-doped SnO2 microspheres with enhanced visible-light photocatalytic activity. RSC Adv 5:56401CrossRefGoogle Scholar
  35. 35.
    Azam A, Ahmed AS, Habib SS, Naqvi AH (2012) Effect of Mn doping on the structural and optical properties of SnO2 nanoparticles. J Alloy Compd 523:83–87CrossRefGoogle Scholar
  36. 36.
    Srinivas K, Vithal M, Sreedhar B, Raja MM, Reddy PV (2009) Structural, optical, and magnetic properties of nanocrystalline Co doped SnO2 based diluted magnetic semiconductors. J Phys Chem C 113:3543–3552CrossRefGoogle Scholar
  37. 37.
    Fang LM, Zu XT, Li ZJ, Zhu S, Liu CM, Zhou WL, Wang LM (2008) Synthesis and characteristics of Fe3+-doped SnO2 nanoparticles via sol–gel-calcination or sol–gel-hydrothermal route. J Alloy Compd 454:261–267CrossRefGoogle Scholar
  38. 38.
    Mandal SK, Nath TK, Das A (2007) Reduction of magnetization in Zn0.9Fe0.1O diluted magnetic semiconducting nanoparticles by doping of Co or Mn ions. J Appl Phys 101:123920CrossRefGoogle Scholar
  39. 39.
    Fukai Y, Kondo Y, Mori S, Suzuki E (2007) Highly efficient dye-sensitized SnO2 solar cells having sufficient electron diffusion length. Electrochem Commun 9:1439–1443CrossRefGoogle Scholar
  40. 40.
    Krishnamoorthy T, Tang MZ, Verma A, Nair AS, Pliszka D, Mhaisalkar SG, Ramakrishna S (2012) A facile route to vertically aligned electrospun SnO2 nanowires on a transparent conducting oxide substrate for dye-sensitized solar cells. J Mater Chem 22:2166CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media, LLC 2017

Authors and Affiliations

  • M. S. Pereira
    • 1
    Email author
  • F. A. S. Lima
    • 1
    • 3
  • C. B. Silva
    • 2
  • P. T. C. Freire
    • 2
  • I. F. Vasconcelos
    • 1
  1. 1.Department of Metallurgical and Materials EngineeringUniversidade Federal do CearáFortalezaBrazil
  2. 2.Department of PhysicsUniversidade Federal do CearáFortalezaBrazil
  3. 3.Organic Electronics Division, CSEM BrasilBelo HorizonteBrazil

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