Journal of Sol-Gel Science and Technology

, Volume 78, Issue 1, pp 50–59 | Cite as

Role of ionic and nonionic surfactant on the phase formation and morphology of Ba(Ce,Zr)O3 solid solution

  • Nurul Asyikin Mazlan
  • Nafisah Osman
  • Abdul Mutalib Md Jani
  • Mohd Hafiz Yaakob
Original Paper: Fundamentals of sol-gel and hybrid materials processing

Abstract

Ceramic powder of BaCe0.54Zr0.36Y0.1O2.95 (BCZY) was successfully synthesized via a modified sol–gel method using metal nitrate salts as precursors. The synthesis was accomplished by using three different types of surfactants which are cationic (benzalkonium chloride), anionic (sodium dodecyl sulfate) and a nonionic surfactant (polyoxyethylene (10) oleyl ether). Citric acid and ethylene glycol were used as a chelating and a polymerization agent, respectively. The crystal form and morphology of the powders were characterized by Fourier transform infrared (FTIR) spectroscopy, X-ray diffractometer and scanning electron microscope (SEM). FTIR spectra showed the traces of carbonate residues in all samples due to the presence of hydrocarbon group in the surfactant structure even after calcination process at T = 1100 °C. Samples prepared using cationic and anionic surfactant consists of the multi-phases compounds which are dominated by BaCO3, BaCeO3, CeO2 and BaZrO3. On the other hand, the samples prepared by using nonionic surfactants produce a single phase of BCZY perovskite-type oxide. SEM images revealed that the sample prepared without surfactant exhibits severe agglomeration. Morphology of the particles for the BCZY prepared by applying the cationic and anionic surfactant was, respectively, cubical and spherical in shape. As for nonionic surfactant, the particle obtained was spherical and uniform in shape. The optimum result was obtained by adding a nonionic surfactant, Brij97, which indicates high crystallinity of the BCZY powder at a temperature of 950 °C and the particle size ranging from 20 to 80 nm. It can be concluded that surfactant affects the phase formation of BCZY ceramic powder as well as its morphology.

Graphical Abstract

Keywords

Solid electrolyte Cerate–zirconate ceramic Modified sol–gel routes Surfactants Phase formation Morphology 

Notes

Acknowledgments

The authors would like to thank the Minister of Higher Education for the Research Grant 600-RMI/RAGS 5/3 (1/2012), Fundamental Research Grant 600-RMI/FRGS 5/3 (8/2014) and Universiti Teknologi MARA (UiTM) for facilities and supports.

References

  1. 1.
    Barison S, Fabrizio M, Fasolin S, Montagner F, Mortalò C (2010) Mater Res Bull 45(9):1171–1176CrossRefGoogle Scholar
  2. 2.
    Iwahara H (1995) Solid State Ion 77:289–298CrossRefGoogle Scholar
  3. 3.
    Yang K, Wang JX, Xue YJ, Wang MS, He CR, Wang Q, Miao H, Wang WG (2014) Ceram Int 40(9):15073–15081CrossRefGoogle Scholar
  4. 4.
    Chakroborty A, Sharma AD, Maiti B, Maiti HS (2002) Mater Lett 57:862–867CrossRefGoogle Scholar
  5. 5.
    Wang S, Zhao F, Zhang L, Chen F (2012) Solid State Ion 213:29–35CrossRefGoogle Scholar
  6. 6.
    Li Y, Zhao J, Wang B (2004) Mater Res Bull 39(3):365–374CrossRefGoogle Scholar
  7. 7.
    Abdullah NA, Hasan S, Osman N (2013) J Chem 2013:1–7Google Scholar
  8. 8.
    Osman N, Jani AM, Talib IA (2007) Ionics 12(6):379–384CrossRefGoogle Scholar
  9. 9.
    Kobayashi Y, Iizuka Y, Tanase T, Konno M (2005) J Sol-Gel Sci Tech 33:315–321CrossRefGoogle Scholar
  10. 10.
    Emami S, Hosseini HRM, Dolati A (2012) Trans Nonferrous Met Soc China 53(4):308–314Google Scholar
  11. 11.
    Huang GY, Xu SM, Li LY, Wang XJ (2014) Trans Nonferrous Met Soc China 24:3739–3746CrossRefGoogle Scholar
  12. 12.
    Cioatera N, Pârvulescu V, Su BL (2010) Mater Chem Phys 120(2–3):697–701CrossRefGoogle Scholar
  13. 13.
    Wang YD, Ma CL, Sun XD, Li HD (2002) Inorg Chem Commun 5:751–755CrossRefGoogle Scholar
  14. 14.
    Chandradass J, Kim KH (2009) J Cryst Growth 311(14):3631–3635CrossRefGoogle Scholar
  15. 15.
    Graeve OA, Fathi H, Kelly JP, Saterlie MS, Sinha K, Rojas-George G, Kanakala R, Brown DR, Lopez EA (2013) J Colloid Interf Sci 407:302–309CrossRefGoogle Scholar
  16. 16.
    Wang Y, Wang C, Li C, Cheng Y, Chi F (2014) Ceram Int 40(3):4305–4310CrossRefGoogle Scholar
  17. 17.
    Tao Y, Shao J, Wang J, Wang WG (2009) J Alloy Compd 484(1–2):729–733CrossRefGoogle Scholar
  18. 18.
    Abdullah NA, Osman S, Hasan H, Hassan OH (2012) Int J Electrochem Sc 7:9401–9409Google Scholar
  19. 19.
    Ejehi F, Marashi SPH, Ghaani MR, Haghshenas DF (2012) Ceram Int 38(8):6857–6863CrossRefGoogle Scholar
  20. 20.
    Motta M, Deimling CV, Saeki MJ, Lisboa-Filho PN (2008) J Sol-Gel Sci Tech 46(2):201–207CrossRefGoogle Scholar
  21. 21.
    Osman N, Talib IA, Hamid HA (2010) Ionics 16(6):561–569CrossRefGoogle Scholar
  22. 22.
    Kuo WK, Lo B, Ling YC (1999) Mater Chem Phys 60(2):132–136CrossRefGoogle Scholar
  23. 23.
    Namnam JS, Philip J (2012) J Colloid Interf Sci 366(1):88–95CrossRefGoogle Scholar
  24. 24.
    Guan H, Bestland E, Zhu C, Zhu H, Albertsdottir D, Hutson J, Simmons T, Ginic-Markovic M, Tao X, Ellis AV (2010) J Hazardous Mater 183:616–621CrossRefGoogle Scholar
  25. 25.
    Khomane RB, Agrawal AC, Kulkarni BD, Gopukumar S, Sivashanmugam A (2008) Mater Res Bull 43(8–9):2497–2503CrossRefGoogle Scholar
  26. 26.
    Abu Bakar SN (2010) Abu Talib I, Osman N. World Appl Sci 9:26–28Google Scholar
  27. 27.
    Cizauskaite S, Reichlova V, Nenartaviciene G, Beganskiene A, Pinkas J, Kareiva A (2007) Mater Sci 25(3):755–765Google Scholar
  28. 28.
    Osman N, Talib IA, Hamid HA (2009) Sains Malays 38(3):401–405Google Scholar
  29. 29.
    Liu Y, Guo Y, Ran R, Shao Z (2013) J Membrane Sci 437:189–195CrossRefGoogle Scholar
  30. 30.
    Robert CL, Ansart F, Castillo S, Richard G (2002) Solid State Sci 4:1053–1059CrossRefGoogle Scholar
  31. 31.
    Kumari L, Li WZ, Kulkarni S, Wu KH, Chen W, Wang C, Vannoy CH, Leblanc RM (2009) Nanoscale Res Lett 5(1):149–157CrossRefGoogle Scholar
  32. 32.
    Lin XF, Zhou RM, Zhang JQ, Sheng XH (2010) Mater Sci 28(2):503–511Google Scholar
  33. 33.
    Zhang S, Jiang F, Qu G, Lin C (2008) Mater Lett 62(15):2225–2228CrossRefGoogle Scholar
  34. 34.
    Wang M, Gao Y, Dai L, Cao C, Guo X (2012) J Solid State Chem 189:49–56CrossRefGoogle Scholar
  35. 35.
    Wang Z, Li X, Feng Z (2011) Bull Korean Chem Soc 32(4):1310–1314CrossRefGoogle Scholar
  36. 36.
    Rai P, Song MK, Song HM, Kim JH, Kim YS, Lee IH, Yu YT (2012) Ceram Int 38:235–242CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media New York 2015

Authors and Affiliations

  • Nurul Asyikin Mazlan
    • 1
  • Nafisah Osman
    • 2
  • Abdul Mutalib Md Jani
    • 2
  • Mohd Hafiz Yaakob
    • 2
  1. 1.Faculty of Applied SciencesUniversiti Teknologi MARAShah AlamMalaysia
  2. 2.Faculty of Applied SciencesUniversiti Teknologi MARAArauMalaysia

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