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Journal of Sol-Gel Science and Technology

, Volume 75, Issue 2, pp 291–297 | Cite as

A crystallization and structural study of the compound Pb2V2O7 synthesized by a facile sol–gel-based chemical route

  • A. Suárez-GómezEmail author
  • Santiago J. A. Figueroa
  • Diego G. Lamas
  • Julio C. Cezar
Original Paper

Abstract

In this work, we carried out the synthesis of lead(II) divanadate(V) by means of a soft chemistry reaction based on a sol–gel-derived route. The final organic precursor was heat treated (T = 400, 500, 600, 750 and 800 °C) and structurally analyzed for each temperature by taking into account the results of FTIR spectroscopy, synchrotron X-ray powder diffraction and X-ray absorption near-edge structure. As an overall result, we report a final compound with remarkable crystallographic and morphological qualities that seem to keep all its structural features in the temperature range 450–700 °C before the structure incongruently melts. As a highlight, the desired material was obtained following a highly reproducible, low-cost, low-temperature and quite straightforward chemical route. Besides, this synthesis route could also allow the appropriate integration of lead(II) divanadate(V) nanoparticles, or nanolayers, into more complex systems as well as the feasibility for being expanded to other materials.

Graphical Abstract

Keywords

Divanadates Synchrotron Pb2V2O7 Sol–gel Nanoparticles 

Notes

Acknowledgments

This work has been supported by Project No. 221541/CUValles(DECyT)/P3e-2014, Project PROINPEP-2014/CUValles and Project PROMEP-NPTC No. UDG-PTC-1080. The authors would also like to thank to CNPEM, in particular to the LNNano and LNLS staff and, most of all, to Dr. C.A. Ospina Ramírez for his kind support with SEM characterizations. Besides, the help provided by Dr. C. Velásquez-Ordoñez, CUVALLES-UdG must also be acknowledged and highly appreciated. We also thank Dr. M. Saleta from Unicamp for help on XAFS acquisition.

Supplementary material

10971_2015_3698_MOESM1_ESM.docx (3.3 mb)
Supplementary material 1 (DOCX 3397 kb)

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Copyright information

© Springer Science+Business Media New York 2015

Authors and Affiliations

  • A. Suárez-Gómez
    • 1
    Email author
  • Santiago J. A. Figueroa
    • 2
  • Diego G. Lamas
    • 3
  • Julio C. Cezar
    • 2
  1. 1.Universidad de Guadalajara, Centro Universitario de Los VallesAmecaMexico
  2. 2.Brazilian Synchrotron Light Laboratory (LNLS)/Brazilian Center of Energy and Materials (CNPEM)CampinasBrazil
  3. 3.CONICET - Escuela de Ciencia y TecnologíaUniversidad Nacional de Gral. San MartínSan MartínArgentina

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