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Journal of Sol-Gel Science and Technology

, Volume 70, Issue 2, pp 245–253 | Cite as

Click approaches in sol–gel chemistry

  • Xavier Cattoën
  • Achraf Noureddine
  • Jonas Croissant
  • Nirmalya Moitra
  • Kristýna Bürglová
  • Jana Hodačová
  • Olivia de los Cobos
  • Martine Lejeune
  • Fabrice Rossignol
  • Delphine Toulemon
  • Sylvie Bégin-Colin
  • Benoît P. Pichon
  • Laurence Raehm
  • Jean-Olivier Durand
  • Michel Wong Chi Man
Original Paper

Abstract

The combination of the copper-catalyzed alkyne-azide cycloaddition (CuAAC) reaction with sol–gel processing enables the versatile preparation of sol–gel materials under different shapes with targeted functionalities through a diversity-oriented approach. In this account, the development of the CuAAC reaction under anhydrous conditions for the synthesis of sol–gel precursors and for the assembling of magnetic nanoparticles on self-assembled monolayers is related, as well as the use of the classical CuAAC methodologies for the functionalization of mesoporous silica nanoparticles and microdots arrays. Coupling CuAAC and Sol–Gel will result in simplified preparations of multifunctional materials with controlled morphologies.

Keywords

Sol–gel Click chemistry CuAAC Organosilanes Nanoparticles 

Notes

Acknowledgments

The CNRS, the Agence Nationale pour la Recherche (ANR P2N 2010 MECHANANO and ANR P2N 2012 NanoptPDT), the Direction Générale de l’Armement (PhD Grant to DT), the Czech Science Foundation (P108/12/1356), the BARRANDE project (MSMT 7AMB12FR004), the French embassy in Prague (Grant to KB), the Limousin region through Theranostic program and the Partner University Fund, a program of FACE, are gratefully acknowledged for financial support.

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Copyright information

© Springer Science+Business Media New York 2013

Authors and Affiliations

  • Xavier Cattoën
    • 1
    • 2
    • 3
  • Achraf Noureddine
    • 1
  • Jonas Croissant
    • 1
  • Nirmalya Moitra
    • 1
  • Kristýna Bürglová
    • 1
    • 4
  • Jana Hodačová
    • 4
  • Olivia de los Cobos
    • 5
  • Martine Lejeune
    • 5
  • Fabrice Rossignol
    • 5
  • Delphine Toulemon
    • 6
  • Sylvie Bégin-Colin
    • 6
  • Benoît P. Pichon
    • 6
  • Laurence Raehm
    • 1
  • Jean-Olivier Durand
    • 1
  • Michel Wong Chi Man
    • 1
  1. 1.Institut Charles Gerhardt Montpellier (UMR 5253 CNRS-UM2-ENSCM-UM1)MontpellierFrance
  2. 2.Univ. Grenoble Alpes, Inst NEELGrenobleFrance
  3. 3.CNRS, Inst NEELGrenobleFrance
  4. 4.Department of Organic ChemistryInstitute of Chemical TechnologyPraha 6Czech Republic
  5. 5.Laboratoire de Science des Procédés Céramiques et de Traitements de Surface (SPCTS)UMR CNRS 7315, CECLimogesFrance
  6. 6.Institut de Physique et Chimie des Matériaux de Strasbourg, UMR 7504 (CNRS-UdS-ECPM)Strasbourg Cedex 2France

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