Journal of Sol-Gel Science and Technology

, Volume 67, Issue 2, pp 267–272 | Cite as

The electrical properties of chemically obtained barium titanate improved by attrition milling

  • M. M. Vijatović Petrović
  • J. D. Bobić
  • H. Uršič
  • J. Banys
  • B. D. Stojanović
Original Paper

Abstract

Barium titanate ceramics were prepared using the nanopowder resulting from a polymeric precursor method, a type of modified Pechini process. The obtained nanopowder was observed to agglomerate and in order to de-agglomerate the powder and enhance the properties of the barium titanate the material was attrition milled. The impact of this attrition milling on the electrical properties of the barium titanate was analysed. The temperature dependence of the relative dielectric permittivity showed three structural phase transitions that are characteristic for ferroelectric barium titanate ceramics. The relative dielectric permittivity at the Curie temperature was higher for the attrition-treated sample than for the non-treated barium titanate. The dielectric losses were below 0.04 in both barium titanate ceramics. The grain and grain-boundary contributions to the total resistivity were observed using impedance analyses for both ceramics. A well-defined ferroelectric hysteresis loop and piezoelectric coefficient d33 = 150 pC/N were obtained for the ceramics prepared from the de-agglomerated powder. In this way we were able to demonstrate that by attrition milling of chemically obtained powders the ferroelectric and piezoelectric properties of the ceramics could be enhanced.

Keywords

Barium titanate Agglomeration Dielectric properties Ferroelectric properties Piezoelectric properties 

References

  1. 1.
    Jona F, Shirane G (1993) Ferroelectric crystals. Dover Publications, New YorkGoogle Scholar
  2. 2.
    Moulson AJ, Herbert JM (2003) Electroceramics, 2nd edn. Wiley, EnglandCrossRefGoogle Scholar
  3. 3.
    Shiau FS, Fang TT, Leu TH (1998) Effects of milling and particle size distribution on the sintering behavior and the evolution of the microstructure in sintering powder compacts. Mater Chem Phys 57:33–40CrossRefGoogle Scholar
  4. 4.
    Tusseau-Nenez S, Ganne JP, Maglione M, Morell A, Niepce JC, Pate M (2004) BST ceramics: effect of attrition milling on dielectric properties. J Eur Ceram Soc 24:3003–3011CrossRefGoogle Scholar
  5. 5.
    Pechini MP, Adams N (1967) United States patent No 3, 330, 697 Google Scholar
  6. 6.
    Ramajo L, Parra R, Roboredo M, Zaghete M, Castro M (2008) Heating rate and temperature effect on the BaTiO3 formation by thermal decomposition of (BaTi) organic precursors during the pechini process. Mat Chem Phys 107:110–114CrossRefGoogle Scholar
  7. 7.
    Vijatović Petrović MM, Bobić JD, Radojković AD, Banys J, Stojanović BD (2012) Improvement of barium titanate properties induced by attrition milling. Ceram Inter 38:5347–5354CrossRefGoogle Scholar
  8. 8.
    Dabhade VV, Rama Mohan TR, Ramakrishnan P (2007) Nanocrystalline titanium powders by high energy attrition milling. Powder Technol 171:177–183CrossRefGoogle Scholar
  9. 9.
    Thakur OP, Prakash C, James AR (2009) Enhanced dielectric properties in modified barium titanate ceramics through improved processing. J Alloys Compd 470:548–551CrossRefGoogle Scholar
  10. 10.
    Horchidan N, Ianculescu A, Curecheriu L, Tudorache F, Musteata V, Stoleriu S, Dragan N, Grisan D, Tascu S, Mitoseriu L (2011) Preparation and characterization of barium titanate stannate solid solutions. J Alloys Compd 509:4731–4737CrossRefGoogle Scholar
  11. 11.
    Vijatovic Petrovic MM, Bobic JD, Ramoska T, Banys J, Stojanovic BD (2011) Antimony doping effect on barium titanate structure and electrical properties. Ceram Int 37:2669–2677CrossRefGoogle Scholar
  12. 12.
    West AR, Sinclair DC, Hirose N (1997) Characterization of electrical materials, especially ferroelectrics by impedance spectroscopy. J Electroceram 1(1):65–71CrossRefGoogle Scholar
  13. 13.
    Devi S, Jha AK (2009) Phase transition and electrical characteristics of tungsten substituted barium titanate. Physica B 404:4290–4294CrossRefGoogle Scholar
  14. 14.
    Thakur OP, Feteira A, Kundys B, Sinclair DC (2007) Influence of attrition milling on the electrical properties of undoped-BaTiO3. J Eur Ceram Soc 27:2577–2589CrossRefGoogle Scholar
  15. 15.
    Sinclair DC, West AR (1989) Impedance and modulus spectroscopy of semiconducting BaTiO3 showing positive temperature coefficient of resistance. J Appl Phys 66:3850–3856CrossRefGoogle Scholar
  16. 16.
    Jaffe B, Cook WR, Jr, Jaffe H (1971) Piezoelectric ceramics. Academic press, LondonGoogle Scholar
  17. 17.
    Sonia Patel RK, Kumar P, Prakash C, Agrawal DK (2012) Low temperature synthesis and dielectric, ferroelectric and piezoelectric study of microwave sintered BaTiO3 ceramics. Ceram Int 38:1585–1589CrossRefGoogle Scholar
  18. 18.
    Chandramani Singh K, Nath AK (2011) Barium titanate nanoparticles produced by planetary ball milling and piezoelectric properties of corresponding ceramics. Mater Lett 65:970–973CrossRefGoogle Scholar
  19. 19.
    Thakur OP, Prakash C, Agrawal DK (2002) Structural and electrical properties of microwave-processed BaTiO3 ceramics. J Ceram Process Res 3:75–79Google Scholar
  20. 20.
    Shao S, Zhang J, Zhang Z, Zheng P, Zhao M, Li J, Wang C (2008) High piezoelectric properties and domain configuration in BaTiO3 ceramics obtained through the solid-state reaction route. J Phys D Appl Phys 41:125408CrossRefGoogle Scholar
  21. 21.
    Takahashi H (2012) Development of Lead-Free BaTiO3 ceramics possessing enhanced piezoelectric properties. Electron Commun Jpn 95([4):1168–1173Google Scholar

Copyright information

© Springer Science+Business Media New York 2013

Authors and Affiliations

  • M. M. Vijatović Petrović
    • 1
  • J. D. Bobić
    • 1
  • H. Uršič
    • 2
  • J. Banys
    • 3
  • B. D. Stojanović
    • 1
  1. 1.Institute for Multidisciplinary ResearchUniversity of BelgradeBelgradeSerbia
  2. 2.Jožef Stefan InstituteLjubljanaSlovenia
  3. 3.Faculty of Physics, Vilnius UniversityVilniusLithuania

Personalised recommendations