Journal of Sol-Gel Science and Technology

, Volume 65, Issue 2, pp 121–129 | Cite as

Hydrothermally assisted complex polymerization method for barium strontium titanate powder synthesis

  • Jovana Ćirković
  • Katarina Vojisavljević
  • Maja Šćepanović
  • Aleksander Rečnik
  • Goran Branković
  • Zorica Branković
  • Tatjana Srećković
Original Paper

Abstract

Barium strontium titanate was obtained by hydrothermal treatment of barium strontium titanate citric precursor solution, previously prepared by complex polymerization method. The thermally induced phase evolution was followed at various temperatures up to 800 °C using thermogravimetric and differential thermal analysis, X-ray diffraction analysis, and Raman spectroscopy. Microstructural characterization of barium strontium titanate powders was performed by scanning and transmission electron microscopy. The proposed synthesis route has been proven as a better and faster method for barium strontium titanate powder preparation as compared to the conventional complex polymerization route. The method was found efficient for production of low agglomerated, fine, nanosized barium strontium titanate powder with well defined stoichiometry, and sub-micron particle size. The results of structural and microstructural characterization showed the complete crystallization of carbonate-free barium strontium titanate powder at 700 °C with an average size of crystallites below 50 nm.

Keywords

Barium strontium titanate Sol–gel processes Hydrothermal synthesis X-ray diffraction Raman spectroscopy Transmission electron microscopy 

Notes

Acknowledgments

This work was financially supported by the Serbian Ministry of Educations, Science and Technological Development through the project No. III45007.

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Copyright information

© Springer Science+Business Media New York 2012

Authors and Affiliations

  • Jovana Ćirković
    • 1
  • Katarina Vojisavljević
    • 1
  • Maja Šćepanović
    • 2
  • Aleksander Rečnik
    • 3
  • Goran Branković
    • 1
  • Zorica Branković
    • 1
  • Tatjana Srećković
    • 1
  1. 1.Institute for Multidisciplinary ResearchUniversity of BelgradeBelgradeSerbia
  2. 2.Center for Solid State Physics and New Materials, Institute of PhysicsUniversity of BelgradeBelgradeSerbia
  3. 3.Department for Nanostructured MaterialsJožef Stefan InsituteLjubljanaSlovenia

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