Journal of Sol-Gel Science and Technology

, Volume 64, Issue 1, pp 209–218 | Cite as

Dual-target sensors: the effect of the encapsulation route on pH measurements and ammonia monitoring

  • Larissa Brentano Capeletti
  • João Henrique Z. Dos Santos
  • Edwin Moncada
Original paper

Abstract

Six different sensors were prepared using hydrolytic and non-hydrolytic sol–gel routes and three different pH indicators as receptor elements. These materials were employed as dual-target sensors for ammonia gas sensing and pH measurements in real samples. Ultraviolet–visible diffuse reflectance spectroscopy and a colorimetric analysis were used to evaluate the pH transitions and the color change that resulted from the ammonia that was employed as a probe for gas sensing. The colorimetric analysis was performed using the CIELAB color space model with the D65 standard illuminant. The resulting \( \Updelta {\text{E}}_{\text{ab}}^{*} \) values correlated with the response time for the observation of the first visible color change detected by the human eye (N = 50), and the average time values ranged from 48 to 117 s. In addition, the response times were evaluated as a function of sample characteristics, namely, the gender, age and eye color. Only groups of these characteristics exhibited relevance to the response time and could be associated with a specific range of time. The sensors were also employed for pH measurements of an aqueous solution, and a double-color scale could be established both with the sensors synthesized by the acid route and with the pH indicators alizarin red and brilliant yellow. From this color scale, it was possible to identify a shift in the turning point of the pH indicator from the free molecule to the encapsulated molecule. The double-color scale was applied to evaluate real samples from a galvanic industry using the synthesized encapsulated sensors.

Keywords

Sol–gel pH indicator Encapsulated sensor Dual-target sensors 

Notes

Acknowledgments

This project was partially financed by the CNPq and FAURGS-Braskem. L. B. Capeletti is grateful to the CNPq for providing a grant. We are also grateful to the NAE statistics group from UFRGS for their assistance in the statistical treatment of the data.

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Copyright information

© Springer Science+Business Media, LLC 2012

Authors and Affiliations

  • Larissa Brentano Capeletti
    • 1
  • João Henrique Z. Dos Santos
    • 1
  • Edwin Moncada
    • 2
  1. 1.Instituto de Química, UFRGSPorto AlegreBrazil
  2. 2.Instituto Tecnológico Metropolitano, RobledoMedellínColombia

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