Journal of Sol-Gel Science and Technology

, Volume 63, Issue 1, pp 146–152 | Cite as

Three-dimensional flower-like nickel oxide supported on graphene sheets as electrode material for supercapacitors

Original Paper

Abstract

Dispersed three-dimensional (3D) flower-like nickel oxide on graphene sheets was synthesized by incorporating a facile hydrothermal process with a thermal treatment process. The possible growth mechanism of 3D flower-like NiO is discussed. When used as electrode materials for supercapacitors, the resultant composite exhibits a specific capacitance of 346F/g (1.5A/g), a good rate performance and cycle stability in 2 M KOH. NiO in the composite could provide a specific capacitance as high as 778.7F/g, compared to that of bare NiO of only 220F/g. The functional features of unique 3D flower-like NiO morphology, high conductivity of graphene sheets and its protective effect to the structure of NiO result in an improved electrochemical performance.

Keywords

Graphene sheets NiO Supercapacitor Hydrothermal 

Notes

Acknowledgments

This work was partly supported by National Natural Science Foundation of China (Grant No. 50802028), Hunan Provincial Natural Science Foundation of China (Grant No.10JJ2036), Research Foundation of Education Bureau of Hunan Province, China (Grant No. 09A036) and Innovation Platform Open Fund Projects in Higher Educational Institutions of Hunan Province (09K096).

References

  1. 1.
    Zheng YZ, Zhang ML (2007) Preparation and electrochemical properties of nickel oxide by molten-salt synthesis. Mater Letts 61:3967–3969CrossRefGoogle Scholar
  2. 2.
    Ding SJ, Zhu T, Chen JS, Wang ZY, Yuan CL, Lou XW (2011) Controlled synthesis of hierarchical NiO nanosheet hollow spheres with enhanced supercapacitive performance. J Mater Chem 21:6602–6606CrossRefGoogle Scholar
  3. 3.
    Liu HJ, Peng TY, Zhao DE, Dai K, Peng ZH (2004) Fabrication of nickel oxide nanotubules by anionic surfactant-mediated templating method. Mater Chem Phys 87:81–86CrossRefGoogle Scholar
  4. 4.
    Wang DS, Xu R, Wang X, Li YD (2006) NiO nanorings and their unexpected catalytic property for CO oxidation. Nanotechnology 17:979CrossRefGoogle Scholar
  5. 5.
    Yang O, Sha J, Ma XY, Yang DR (2005) Synthesis of NiO nanowires by a sol-gel process. Mater Letts 59:1967–1970CrossRefGoogle Scholar
  6. 6.
    Wang W, Liu Y, Xu C, Zheng C, Wang G (2002) Synthesis of NiO nanorods by a novel simple precursor thermal decomposition approach. Chem Phys Lett 362:119–122CrossRefGoogle Scholar
  7. 7.
    Wang L, Zhao Y, Lai QY, Hao YJ (2010) Preparation of 3D rose-like NiO complex structure and its electrochemical property. J Alloys Compd 495:82–87CrossRefGoogle Scholar
  8. 8.
    Ni XM, Zhang YF, Tian DY, Zheng HG, Wang XW (2007) Synthesis and characterization of hierarchical NiO nanoflowers with porous structure. J Crystal Growth 306:418–421CrossRefGoogle Scholar
  9. 9.
    Cao X, Xu YJ, Wang N (2011) Facile synthesis of NiO nanoflowers and their electrocatalytic performance. Sens Actuators B 153:434–438CrossRefGoogle Scholar
  10. 10.
    Gao B, Yuan CZ, Su LH, Chen SY, Zhang XG (2009) High dispersion and electrochemical capacitive performance of NiO on benzenesulfonic functionalized carbon nanotubes. Electrochim Acta 54:3561–3567CrossRefGoogle Scholar
  11. 11.
    Zhu JH, Jiang J, Liu JP, Ding RM, Ding H, Feng YM, Wei GM, Huang XT (2011) Direct synthesis of porous NiO nanowall arrays on conductive substrates for supercapacitor application. J Solid State Chem 184:578–583CrossRefGoogle Scholar
  12. 12.
    Yuan CZ, Gao B, Su LH, Zhang XG (2008) NiO loaded on hydrothermally treated mesocarbon microbeads (h-MCMB) and their supercapacitive behaviors. Solid State Ion 178:1859–1866CrossRefGoogle Scholar
  13. 13.
    Zou YQ, Wang Y (2011) NiO nanosheets grown on graphene nanosheets as superior anode materials for Li-ion batteries. Nanoscale 3:2615–2620CrossRefGoogle Scholar
  14. 14.
    Wang XY, Zhou XF, Yao K, Zhang JG, Liu ZP (2011) A SnO2/graphene composite as a high stability electrode for lithium ion batteries. Carbon 49:133–139CrossRefGoogle Scholar
  15. 15.
    Wang HL, Cui LF, Yang Y, Casalongue HS, Robinson JT (2010) Mn3O4-graphene hybrid as a high-capacity anode material for lithium ion batteries. J Am Chem Soc 132:13978–13980CrossRefGoogle Scholar
  16. 16.
    Wu ZS, Wang DW, Ren WC, Zhao JP, Zhou GM, Li F, Cheng HM (2010) Anchoring hydrous RuO2 on graphene sheets for high-performance electrochemical capacitors. Adv Funct Mater 20:3595–3602CrossRefGoogle Scholar
  17. 17.
    Hummers WS, Offeman RE (1958) Preparation of graphitic oxide. J Am Chem Soc 80:1339CrossRefGoogle Scholar
  18. 18.
    Nam KW, Kim KB (2002) A study of the preparation of NiOx electrode via electrochemical route for supercapacitor applications and their charge storage mechanism. J Electrochem Soc 149:A346–A354CrossRefGoogle Scholar
  19. 19.
    Gao YY, Chen SL, Cao DX, Wang GL, Yin JL (2010) Electrochemical capacitance of Co3O4 nanowire arrays supported on nickel foam. J Power Sources 195:1757–1760CrossRefGoogle Scholar
  20. 20.
    Meyer JC, Geim AK, Katsnelson MI, Novoselov KS, Booth TJ, Roth S (2007) The structure of suspended graphene sheets. Nature 446:60–63CrossRefGoogle Scholar
  21. 21.
    Wei X, Li L, Yan ZF, Lu GQ (2005) Synthesis and characterization of mesoporous nickel oxide and its application to electrochemical capacitor. Chimica Sinica 63:1775–1781Google Scholar
  22. 22.
    Atkin R, Warr GG (2005) Self-assembly of a nonionic surfactant at the graphite/ionic liquid interface. J Am Chem Soc 127:11940–11941CrossRefGoogle Scholar
  23. 23.
    Srinivas G, Nielsen SO, Moore PB, Klein ML (2006) Molecular dynamics simulations of surfactant self-organization at a solid–liquid interface. J Am Chem Soc 128:848–853CrossRefGoogle Scholar
  24. 24.
    Huo QS, Margolese DI, Ciesla U, Demuth DG, Feng PY, Gier TE, Sieger P, Firouzi A, Chmelka BF (1994) Organization of organic molecules with inorganic molecular species into nanocomposite biphase arrays. Chem Mater 6:1176–1191CrossRefGoogle Scholar
  25. 25.
    Zhong LS, Hu JS, Liang HP, Cao AM, Song WG, Wan LJ (2006) Self-assembled 3D flowerlike iron oxide nanostructures and their application in water treatment. Adv Mater 18:2426–2431CrossRefGoogle Scholar
  26. 26.
    Zeng SY, Tang KB, Li TW, Liang ZH, Wang D, Wang YK, Qi YX, Zhou WW (2008) Facile route for the fabrication of porous hematite nanoflowers: its synthesis, growth mechanism, application in the lithium ion battery, and magnetic and photocatalytic properties. J Phys Chem C 112:4836–4843CrossRefGoogle Scholar
  27. 27.
    Ren Y, Gao L (2010) From three-dimensional flower-like α-Ni(OH)2 nanostructures to hierarchical porous nio nanoflowers: microwave-assisted fabrication and supercapacitor properties. J Am Ceram Soc 93:3560–3564CrossRefGoogle Scholar
  28. 28.
    Wang YG, Xia YY (2006) Electrochemical capacitance characterization of NiO with ordered mesoporous structure synthesized by template SBA-15. Electrochim Acta 51:3223–3227CrossRefGoogle Scholar
  29. 29.
    Yuan CZ, Zhang XG, Su LH, Gao B, Shen LF (2009) Facile synthesis and self-assembly of hierarchical porous NiO nano/micro spherical superstructures for high performance supercapacitors. J Mater Chem 19:5772–5777CrossRefGoogle Scholar
  30. 30.
    Kottegoda IRM, Idris NH, Lu L, Wang JZ, Liu HK (2011) Synthesis and characterization of graphene-nickel oxide nanostructures for fast charge–discharge application. Electrochim Acta 56:5815–5822CrossRefGoogle Scholar
  31. 31.
    Wang Y, Shi ZQ, Huang Y, Ma YF, Wang CY, Chen MM, Chen YS (2009) Supercapacitor devices based on graphene materials. J Phys Chem C 113:13103–13107CrossRefGoogle Scholar
  32. 32.
    Brug GJ, Eeden AV, Sluyters-Rehbach M, Sluyters JH (1984) The analysis of electrode impedances complicated by the presence of a constant phase element. J Electroanal Chem 176:275–295CrossRefGoogle Scholar
  33. 33.
    Wang C, Zhou Y, Ge MY, Xu XB, Zhang ZL, Jiang JZ (2010) Large-scale synthesis of SnO2 nanosheets with high lithium storage capacity. J Am Chem Soc 132:46–47CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media, LLC 2012

Authors and Affiliations

  1. 1.College of Chemistry and Chemical EngineeringHunan Institute of Science and TechnologyYueyangChina
  2. 2.College of Chemistry and Chemical EngineeringHunan UniversityChangshaChina

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