Study of spin coated multilayer zirconia and silica films for non-quarterwavelength optical design based antireflection effect at 1,054 nm
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A non-quarterwavelength optical design (design wavelength, λo = 1,054 nm) based antireflection (AR) coating was prepared by sol–gel spin coating technique. Two materials, zirconia and silica were chosen for the deposition of AR layers on borosilicate crown glass, refractive index (R. I. = 1.51). For this design, the bottom and middle layers were of zirconia with the R. I. range 1.941–1.958 while the top layer was of silica with R. I. 1.455. To understand the surface feature after each deposition, refractive index and physical thickness of the layers were measured ellipsometrically (λ = 632.8 nm) at different points over the area, 10 mm × 10 mm with an interval of 0.5 mm along the centre based perpendicular projection made on an imaginary chord. The surface feature was examined by plotting the measured values of the optical parameters against the displacement. The surface roughness decreased with increasing layers. This was verified by the study of AFM images of the layers. Specular reflection of the antireflection coated product at λ0 was comparable to that of the theoretically simulated curve.
KeywordsSol–gel process Multilayer zirconia Film thickness Refractive index Antireflection property
The authors thank the Director, CSIR-CGCRI, Kolkata for his permission to publish this paper. The developmental work on AR coating was carried out under the sponsorship of BRNS, DAE, Govt. of India. One of the authors N. D thanks to BRNS for providing her research fellowship.
- 1.Brinker CJ, Scherer GW (1990) Sol–gel science. Academic Press, San DiegoGoogle Scholar
- 7.Roy S, Pal P, Patra A, Ganguli D, Kamath MP, Joshi AS, Biswas PK (2000) In: Lahiri SK, Gangopadhyay R, Datta AK, Mathur BK, Roy SK, Das S (eds) International conference on fiber optics and photonics-2000, vol 2, p 693Google Scholar
- 9.Biswas P K (2011) J Sol Gel Sci Technol. doi: 10.1007/s10971-010-2368-5
- 13.Nakamoto K (1970) Infrared spectra of inorganic and co-ordination compounds, 2nd edn. Wiley/Interscience, New YorkGoogle Scholar
- 15.Biswas PK, Sujatha Devi P, Chakraboarty PK, Chatterjee M, Kamath MP, Joshi AS, Ganguli D (1999). In: Mallik A, Dayal RR (eds) Laser materials and devices. Allied Publishers Ltd., New Delhi, p 314Google Scholar
- 16.Knittl Z (1976) Optics of thin films. Wiley, LondonGoogle Scholar
- 18.Floch HG, Belleville PF (1994) J Sol Gel Sci Tech 2:695Google Scholar
- 19.Popovici M, Graaf J, Verschuuren MA, Graat PCJ, Verheijen (2010) Thin Solid Films 519:630Google Scholar
- 20.Obreja P, Cristea D, Teodorescu VS, Dinescu A, Obreja AC, Comanescu F, Rebigan R (2010) J Optoelectron Adv Mater 12:2007Google Scholar
- 22.Wu GM, Wang J, Shen J, Yang TH, Lai ZQ, Zhang HL, Zhang QY (1999) Atom Energy Sci Technol 33:332Google Scholar
- 24.Berring PH (1996) Physics of Thin Films, vol 1. Academic Press, New York, p 87Google Scholar