Reactivity of CO2 traps in aerogel–wollastonite composites
- 311 Downloads
Synthetic wollastonite has been used as the active phase embedded into two different silica aerogel composites. These composites are different in respect of the route used for the synthesis of the wollastonite powder. Texture and composition of both types of composite have been characterized. In addition, several factors (pH, reaction time, CO2 saturation, etc.) that could help to optimize the carbonation process at room temperature and pressure have been studied. Under the same conditions, both composites confirm previous results showing efficiencies as CO2 sequesters between 80% and 100% in only 15 min of gas flow. The textural characteristics of the aerogel, together with the grain size of the synthetic wollastonite powder, not only increase the speed of the reaction, but also inhibit the appearance of a passivating layer on the surface of the wollastonite grains attacked by the CO2. This is an outstanding feature as it insists on a cutting-edge challenge of the CO2 research: its economical availability.
KeywordsAerogel Wollastonite CO2 sequestration Passivating layer Carbonation Porous matrix
The authors are grateful to the Consejería de Innovación Ciencia y Empresa of the Junta de Andalucía (Spain), Agencia Española de Cooperación Internacional and the Spanish Ministerio de Medio Ambiente, for supporting this work with the Projects TEP790, AECI A/5575/06 and A266/2007/3-11.1, respectively.
- 3.Fernandez-Bastero S, Garcia T, Santos A, Gago-Duport L (2005) Ciencias Marinas 31:593Google Scholar
- 5.O'Connor WK, Dahlin DC, Rush GE, Dahlin CL, Collins WK (2002) Miner Metall Proc 19:95Google Scholar
- 10.Santos A, Ajbary M, Kherbeche A, Piñero M, de la Rosa-Fox N, Esquivias L (2008) J Sol-Gel Sci Technol, Available on line. doi: 10.1007/s10971-007-1672-1
- 15.Nicolaon GA, Teichner SJ (1968) Bull Soc Chim Fr 1900Google Scholar