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Journal of Radioanalytical and Nuclear Chemistry

, Volume 322, Issue 2, pp 861–868 | Cite as

Performance of biopolymer/graphene oxide gels for the effective adsorption of U(VI) from aqueous solution

  • Wei Peng
  • Guolin HuangEmail author
  • Shasha Yang
  • Chenglun Guo
  • Jeffery Shi
Article
  • 29 Downloads

Abstract

In exploration of an efficient and economical means for the treatment of radioactive wastewater, the performance of biopolymer/graphene oxide gels have been evaluated in the application for the separation of U(VI). The microscopic morphology and crystal structure of the obtained gels were analyzed by scanning electron microscopy, X-ray diffraction, Fourier transformed infrared spectra, and energy dispersive spectroscopy. The effects of adsorption factors such as solution pH and contact time were discussed to obtain the suitable process conditions. The experimental data were found to be agreed well with the Langmuri isotherm and the pseudo-second-order kinetic model.

Keywords

Biopolymer Uranium Kinetics Langmuir Freundlich isotherm 

Notes

Acknowledgements

The present work was sponsored by the national science foundation of China (21866005) and the item of State Key Laboratory of Nuclear Resources and Environment (NRE 1611).

References

  1. 1.
    Liu SJ, Zhang HX, Peng DF, Yuan DZ, Wu LP, Ma JG (2017) Uranium uptake with grapheme oxide sponge prepared byfacile EDTA-assisted hydrothermal process. Int J Energy Res 41(2):263–273CrossRefGoogle Scholar
  2. 2.
    Shao DD, Liu XH, Hayat T, Li JX, Re XM (2019) Poly(amidoxime) functionalized MoS2 for efficient adsorption of uranium(VI) in aqueous solutions. J Radioanal Nucl Chem 319:379–386CrossRefGoogle Scholar
  3. 3.
    Huang GL, Wi Peng, Yang SS (2018) Synthesis of magnetic chitosan/graphene oxide nanocomposites and its application for U(VI) adsorption from aqueous solution. J Radioanal Nucl Chem 317:337–344CrossRefGoogle Scholar
  4. 4.
    Huang GL, Zou LX, Su Y, Lv TT, Wang LL (2016) Adsorption of uranium(VI) from aqueous solutions using cross-linked magnetic chitosan beads. J Radioanal Nucl Chem 307:1135–1140CrossRefGoogle Scholar
  5. 5.
    Hu T, Ding SJ, Deng HJ (2016) Application of three surface complexation models on U(VI) adsorption onto graphene oxide. Chem Eng J 289:270-276CrossRefGoogle Scholar
  6. 6.
    Zhou LM, Ouyang JB, Liu ZR, Huang GL, Wang Y, Li Z, Adesina AA (2019) Highly efficient sorption of U(VI) from aqueous solution using amino/amine-functionalized magnetic mesoporous silica nanospheres. J Radioanal Nucl Chem.  https://doi.org/10.1007/s10967-018-6381-4 CrossRefGoogle Scholar
  7. 7.
    Zheng H, Zhou LM, Liu ZR, Le ZG, Ouyang JB, Huang GL, Shehzad H (2019) Functionalization of mesoporous Fe3O4@SiO2 nanospheres for highly efficient U(VI) adsorption. Micropor Mesopor Mat 279:16–322CrossRefGoogle Scholar
  8. 8.
    Mohamud H, Ivanov P, Russell BC, Regan PH, Ward NI (2018) Selective sorption of uranium from aqueous solution by graphene oxide-modified materials. J Radioanal Nucl Chem 316:839–848CrossRefGoogle Scholar
  9. 9.
    Liu X, Li JX, Wang XX, Chen CL, Wang XK (2015) High performance of phosphate-functionalized graphene oxide for the selective adsorption of U(VI) from acidic solution. J Nucl Mater 466:56–64CrossRefGoogle Scholar
  10. 10.
    Yang PP, Liu Q, Liu JY, Zhang HS, Li ZH, Li RM, Liu LH (2017) Bovine serum albumin-coated graphene oxide for effective adsorption of Uranium(VI) from aqueous solutions. Ind Eng Chem Res 56:3588–3598CrossRefGoogle Scholar
  11. 11.
    Huang ZW, Li ZJ, Zheng LR, Zhou LM, Chai ZF, Wang XL, Shi WQ (2017) Interaction mechanism of uranium(VI) with three-dimensional grapheme oxide-chitosan composite: insights from batch experiments, IR, XPS, and EXAFS spectroscopy. Chem Eng J 328:1066–1074CrossRefGoogle Scholar
  12. 12.
    Wang S, Ning HM, Hu N, Huang KY, Weng SY, Wu XP, Wu LK, Liu J, Alamusi S (2019) Preparation and characterization of graphene oxide/silk fibroin hybrid aerogel for dye and heavy metal adsorption. Compos B 163:716–722CrossRefGoogle Scholar
  13. 13.
    Cheng CS, Deng J, Lei B, He A, Zhang X, Ma L, Li S, Zhao CS (2013) Toward 3D graphene oxide gels based adsorbents for high-efficient water treatment via the promotion of biopolymers. J Hazard Mater 263:467–478CrossRefGoogle Scholar
  14. 14.
    Pan N, Li L, Ding J, Li S, Wang R, Jin Y, Wang X, Xia C (2016) Preparation of graphene oxide-manganese dioxide for highly efficient adsorption and separation of Th(IV)/U(VI). J Hazard Mater 309:107–115CrossRefGoogle Scholar
  15. 15.
    Song W, Wang X, Wang Q, Shao D, Wang X (2015) Plasma-induced grafting of polyacrylamide on graphene oxide nanosheets for simultaneous removal of radionuclides. Phys Chem Chem Phys 17(1):398–406CrossRefGoogle Scholar
  16. 16.
    Cheng HX, Zeng KF, Yu JT (2013) Adsorption of uranium from aqueous solution by graphene oxide nanosheets supported on sepiolite. J Radioanal Nucl Chem 298:599–603CrossRefGoogle Scholar

Copyright information

© Akadémiai Kiadó, Budapest, Hungary 2019

Authors and Affiliations

  1. 1.State Key Laboratory of Nuclear Resources and EnvironmentEast China University of TechnologyNanchangChina
  2. 2.School of Chemical and Biomolecular EngineeringThe University of SydneySydneyAustralia

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