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Journal of Radioanalytical and Nuclear Chemistry

, Volume 321, Issue 3, pp 1035–1044 | Cite as

Efficient scavenging of uranium (VI) using porous hexagonal boron nitride by a combined process of surface adsorption and induced precipitation crystallization

  • Li Li
  • Yin Zhao
  • Yang JinEmail author
  • Wensheng Linghu
  • Chaogui ChenEmail author
  • Abdullah M. Asiri
  • Hadi M. Marwani
  • Guodong ShengEmail author
Article
  • 8 Downloads

Abstract

An ammonium/hydroxyl-enriched p-BN microrods were synthesized and the adsorption behavior of uranyl on p-BN was systematically studied. The adsorption kinetic and isotherm studies revealed the adsorption behavior is independent on electrostatic attraction or chemisorption. The results demonstrate uranyl hydrolyzed precipitated crystals are formed on the surface of p-BN at an optimized pH of 2.86 and the maximum adsorption capacity can reach 413 mg g−1 at T = 303 K. A hypothetical adsorption mechanism with a combination of surface adsorption and induced precipitation crystallization was proposed.

Keywords

Porous hexagonal boron nitride Adsorption Uranyl Uranyl hydrolyzed precipitate 

Notes

Acknowledgements

Financial supports from the National Natural Science Foundation of China (21577093, and 21777102), Natural Science Foundation of Zhejiang Province (LY15B070001) is greatly acknowledged.

Supplementary material

10967_2019_6644_MOESM1_ESM.docx (1.3 mb)
Supplementary material 1 (DOCX 1282 kb)

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Copyright information

© Akadémiai Kiadó, Budapest, Hungary 2019

Authors and Affiliations

  1. 1.College of Chemistry and Chemical EngineeringShaoxing UniversityShaoxingPeople’s Republic of China
  2. 2.Chemistry Department, Faculty of ScienceKing Abdulaziz UniversityJeddahSaudi Arabia

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