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Evaluation of Co and Zn competitive sorption by zeolitic material synthesized from fly ash using 60Co and 65Zn as radioindicators

  • Martin PipíškaEmail author
  • Eva Florková
  • Peter Nemeček
  • Lucia Remenárová
  • Miroslav Horník
Article
  • 26 Downloads

Abstract

Zeolitic material prepared by hydrothermal treatment of brown coal fly ash was used for sorption separation of Co2+ and Zn2+ ions from single and binary solutions. Adsorption in single systems was rapid, pH dependent and follow the Langmuir isotherm. 3D sorption surfaces revealed competitive effects and mutual interactions between Co2+ and Zn2+ and significant preference for Zn2+ in binary system was confirmed. Surface retention and ion-exchange were most probably the principal mechanisms of Co2+ and Zn2+ removal. Zeolitic material with markedly high sorption capacity for Co2+ and Zn2+ can be a promising sorbent for removal of toxic metals and radionuclides.

Keywords

Fly ash conversion Zeolitic material 60Co 65Zn Competitive adsorption 

Notes

Acknowledgements

This work was supported by the Slovak Research and Development Agency under the Contract No. APVV-15-0098.

Compliance with ethical standards

Conflict of interest

The authors declare that there are no conflicts of interest.

References

  1. 1.
    Burakov AE, Galunin EV, Burakova IV, Kucherova AE, Agarwal S, Tkachev AG, Gupta VK (2018) Adsorption of heavy metals on conventional and nanostructured materials for wastewater treatment purposes: a review. Ecotoxicol Environ Saf 148:702–712CrossRefGoogle Scholar
  2. 2.
    Pandey S (2017) A comprehensive review on recent developments in bentonite-based materials used as adsorbents for wastewater treatment. J Mol Liq 241:1091–1113CrossRefGoogle Scholar
  3. 3.
    Wang X, Liu Y, Pang H, Yu S, Ai Y, Ma X, Song G, Hayat T, Alsaedi A, Wang X (2018) Effect of graphene oxide surface modification on the elimination of Co(II) from aqueous solutions. Chem Eng J 344:380–390CrossRefGoogle Scholar
  4. 4.
    Frišták V, Micháleková-Richveisová B, Víglašová E, Ďuriška L, Galamboš M, Moreno-Jimenéz E, Pipíška M, Soja G (2017) Sorption separation of Eu and As from single-component systems by Fe-modified biochar: kinetic and equilibrium study. J Iran Chem Soc 14:521–530CrossRefGoogle Scholar
  5. 5.
    Ibrahim HA, Abdel Moamen OA, Abdel Monem N, Ismail IM (2018) Assessment of kinetic and isotherm models for competitive sorption of Cs+ and Sr2+ from binary metal solution onto nanosized zeolite. Chem Eng Commun 205:1274–1287CrossRefGoogle Scholar
  6. 6.
    Luo H, Law WW, Wu Y, Zhu W, Yang E-H (2018) Hydrothermal synthesis of needle-like nanocrystalline zeolites from metakaolin and their applications for efficient removal of organic pollutants and heavy metals. Microporous Mesoporous Mater 272:8–15CrossRefGoogle Scholar
  7. 7.
    Li J, Wang X, Zhao G, Chen C, Chai Z, Alsaedi A, Hayat T, Wang X (2018) Metal-organic framework-based materials: superior adsorbents for the capture of toxic and radioactive metal ions. Chem Soc Rev 47:2322–2356CrossRefGoogle Scholar
  8. 8.
    Yu S, Wang X, Pang H, Zhang R, Song W, Fu D, Hayat T, Wang X (2018) Boron nitride-based materials for the removal of pollutants from aqueous solutions: a review. ChemEng J 333:343–360Google Scholar
  9. 9.
    Zou Y, Wang X, Khan A, Wang P, Liu Y, Alsaedi A, Hayat T, Wang X (2016) Environmental remediation and application of nanoscale zero-valent iron and its composites for the removal of heavy metal ions: a review. Environ Sci Technol 50:7290–7304CrossRefGoogle Scholar
  10. 10.
    Gu P, Zhang S, Li X, Wang X, Wen T, Jehan R, Alsaedi A, Hayat T, Wang X (2018) Recent advances in layered double hydroxide-based nanomaterials for the removal of radionuclides from aqueous solution. Environ Pollut 240:493–505CrossRefGoogle Scholar
  11. 11.
    Liu Y, Wang G, Wang L, Li X, Luo Q, Na P (2018) Zeolite P synthesis based on fly ash and its removal of Cu(II) and Ni(II) ions. Chin J Chem Eng.  https://doi.org/10.1016/j.cjche.2018.03.032 CrossRefGoogle Scholar
  12. 12.
    Hałas P, Kołodyńska D, Płaza A, Gęca M, Hubicki Z (2017) Modified fly ash and zeolites as an effective adsorbent for metal ions from aqueous solution. Adsorpt Sci Technol 35:519–533CrossRefGoogle Scholar
  13. 13.
    Ji XD, Ma YY, Peng SH, Gong YY, Zhang F (2017) Simultaneous removal of aqueous Zn2+, Cu2+, Cd2+, and Pb2+ by zeolites synthesized from low-calcium and high-calcium fly ash. Water Sci Technol 76:2106–2119CrossRefGoogle Scholar
  14. 14.
    Remenárová L, Pipíška M, Florková E, Horník M, Rozložník M, Augustín J (2014) Zeolites from coal fly ash as efficient sorbents for cadmium ions. Clean Technol Environ Policy 16:1551–1564CrossRefGoogle Scholar
  15. 15.
    Reynel-Avila HE, Mendoza-Castillo DI, Olumide AA, Bonilla-Petriciolet A (2016) A survey of multi-component sorption models for the competitive removal of heavy metal ions using bush mango and flamboyant biomasses. J Mol Liq 224:1041–1054CrossRefGoogle Scholar
  16. 16.
    Merrikhpour H, Jalali M (2013) Comparative and competitive adsorption of cadmium, copper, nickel, and lead ions by Iranian natural zeolite. Clean Technol Environ Policy 15:303–316CrossRefGoogle Scholar
  17. 17.
    Querol X, Moreno N, Umaña JC, Alastuey A, Hermández E (2002) Synthesis of zeolites from fly ash: an overview. Int J Coal Geol 50:413–423CrossRefGoogle Scholar
  18. 18.
    Butler JAV, Ockrent C (1930) Studies in electrocapillarity. Part III. The surface tensions of solutions containing two surface-active solutes. J Phys Chem 34:2841–2845CrossRefGoogle Scholar
  19. 19.
    Jha B, Singh DN (2016) Mechanism of zeolitization of fly ash. In: Jha B, Singh DN (eds) Fly ash zeolites. Advanced structured materials, vol 78. Springer, Singapore, pp 53–62.  https://doi.org/10.1007/978-981-10-1404-8_4. ISBN 978-981-10-1404-8CrossRefGoogle Scholar
  20. 20.
    Algoufi YT, Hameed BH (2014) Synthesis of glycerol carbonate by transesterification of glycerol with dimethyl carbonate over K-zeolite derived from coal fly ash. Fuel Process Technol 126:5–11CrossRefGoogle Scholar
  21. 21.
    Ríos CAR, Williams CD, Roberts CL (2009) A comparative study of two methods for the synthesis of fly ash-based sodium and potassium type zeolites. Fuel 88:1403–1416CrossRefGoogle Scholar
  22. 22.
    Koukouzas N, Vasilatos C, Itskos G, Mitsis I, Moutsatsou A (2010) Removal of heavy metals from wastewater using CFB-coal fly ash zeolitic materials. J Hazard Mater 173:581–588CrossRefGoogle Scholar
  23. 23.
    Kalvachev Y, Zgureva D, Boycheva S, Barbov B, Petrova N (2016) Synthesis of carbon dioxide adsorbents by zeolitization of fly ash. J Therm Anal Calorim 124:101–106CrossRefGoogle Scholar
  24. 24.
    Ahmed NM, Emira HS, Selim MM (2011) Anticorrosive performance of ion-exchange zeolites in alkyd-based paints. Pigm Resin Technol 40:91–99CrossRefGoogle Scholar
  25. 25.
    Izidoro JC, Fungaro DA, Abbott JE, Wang S (2013) Synthesis of zeolites X and A from fly ashes for cadmium and zinc removal from aqueous solutions in single and binary ion systems. Fuel 103:827–834CrossRefGoogle Scholar
  26. 26.
    Ojha K, Pradhan NC, Samanta AN (2004) Zeolite from fly ash: synthesis and characterization. Bull Mater Sci 27:555–564CrossRefGoogle Scholar
  27. 27.
    Mužek MN, Svilović S, Ugrina M, Zelić J (2016) Removal of copper and cobalt ions by fly ash-based geopolymer from solutions-equilibrium study. Desalin Water Treat 57:10689–10699CrossRefGoogle Scholar
  28. 28.
    Shah B, Mistry C, Shah A (2013) Seizure modeling of Pb(II) and Cd(II) from aqueous solution by chemically modified sugarcane bagasse fly ash: isotherms, kinetics, and column study. Environ Sci Pollut Res 20:2193–2209CrossRefGoogle Scholar
  29. 29.
    Remenárová L, Pipíška M, Florková E, Augustín J, Rozložník M, Hostin S, Horník M (2014) Radiocesium adsorption by zeolitic materials synthesized from coal fly ash. Nova Biotechnol Chim 13:57–72Google Scholar
  30. 30.
    Lu X, Shi D, Chen J (2017) Sorption of Cu2+ and Co2+ using zeolite synthesized from coal gangue: isotherm and kinetic studies. Environ Earth Sci 76: Art. No. 591Google Scholar
  31. 31.
    Hui KS, Chao CYH, Kot SC (2005) Removal of mixed heavy metal ions in wastewater by zeolite A4 and residual products from recycled coal fly ash. J Hazard Mater B 127:89–101CrossRefGoogle Scholar
  32. 32.
    Mužek MN, Svilović S, Zelić J (2016) Kinetic studies of cobalt ion removal from aqueous solutions using fly ash-based geopolymer and zeolite NaX as sorbents. Sep Sci Technol 51:2868–2875CrossRefGoogle Scholar
  33. 33.
    Ahmaruzzaman M (2010) Review on the utilization of fly ash. Prog Energy Combust Sci 36:327–363CrossRefGoogle Scholar
  34. 34.
    Franus W (2012) Characterization of X-type zeolite prepared from coal fly ash. Pol J Environ Stud 21:337–343Google Scholar
  35. 35.
    Covarrubias C, Arriagada R, Yanez J, Garcia R, Angelica M, Barros SD, Arroyo P, Sousa-Aguiar EF (2005) Removal of chromium(III) from tannery effluents, using a system of packed columns of zeolite and activated carbon. J Chem Technol Biotechnol 80:899–908CrossRefGoogle Scholar
  36. 36.
    Chen G, Shi L (2017) Removal of Cd(II) and Pb(II) ions from natural water using a low-cost synthetic mineral: behavior and mechanisms. RSC Adv 7:43445–43454CrossRefGoogle Scholar
  37. 37.
    Erdem E, Karapinar N, Donat R (2004) The removal of heavy metal cations by natural zeolites. J Colloid Interface Sci 280:309–314CrossRefGoogle Scholar
  38. 38.
    Wang C, Li J, Sun X, Wang L, Sun X (2009) Evaluation of zeolites synthesized from fly ash as potential adsorbents for wastewater containing heavy metals. J Environ Sci 21:127–136CrossRefGoogle Scholar
  39. 39.
    Solache-Rios M, Olguín MT, Martínez-Miranda V, Ramírez-García J, Zárate-Montoya N (2015) Removal behavior of cobalt from aqueous solutions by a sodium-modified zeolitic tuff. Water Air Soil Pollut 226: Art. No. 2688Google Scholar
  40. 40.
    Ma B, Shin WS, Oh S, Park Y-J, Choi S-J (2010) Adsorptive removal of Co and Sr ions from aqueous solution by synthetic hydroxyapatite nanoparticles. Sep Sci Technol 45:453–462CrossRefGoogle Scholar
  41. 41.
    Araissi M, Ayed I, Elaloui E, Moussaoui Y (2016) Removal of barium and strontium from aqueous solution using zeolite 4A. Water Sci Technol 73:1628–1636CrossRefGoogle Scholar

Copyright information

© Akadémiai Kiadó, Budapest, Hungary 2019

Authors and Affiliations

  • Martin Pipíška
    • 1
    • 2
    Email author
  • Eva Florková
    • 2
  • Peter Nemeček
    • 3
  • Lucia Remenárová
    • 2
  • Miroslav Horník
    • 2
  1. 1.Department of ChemistryTrnava University in TrnavaTrnavaSlovakia
  2. 2.Department of Ecochemistry and RadioecologyUniversity of SS. Cyril and MethodiusTrnavaSlovakia
  3. 3.Department of ChemistryUniversity of SS. Cyril and MethodiusTrnavaSlovakia

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