Abstract
In Brazil impounded vehicle scrapyards (IVS) are often overcrowded and may pose a source of potentially toxic elements (PTEs). In this study, PTEs content in soil cores and groundwater of an IVS located at a municipality of the São Paulo metropolitan region was assessed. INAA, XRF and ICP-MS were the analytical techniques employed. PTEs results and statistical approaches indicated that As, Pb, Ni, Cu and Nb are mostly anthropic. Pb, Cu, Ni and Nb mass fraction increased with depth indicating some downward mobility. Arsenic may represent a moderate to very high potential ecological risk. PTEs groundwater levels were bellow drinking water recommendation limits.
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IBGE (2010) Instituto Brasileiro de Geografia e Estatística (Brazilian Institute of Geography and Statistics). Censo Demográfico 2010 http://7a12.ibge.gov.br/vamos-conhecer-o-brasil/nosso-povo/caracteristicas-da-populacao.html (accessed 21 Jul 17)
IBGE (2016) Instituto Brasileiro de Geografia e Estatística (Brazilian Institute of Geography and Statistics). Cidades http://cidades.ibge.gov.br/xtras/perfil.php?codmun=3550308 (accessed 21 Jul 17)
Soriano E et al (2016) Water crisis in São Paulo evaluated under the disaster’s point of view. Ambiente Soc 19(1):21–42
Nwachukwu MA, Feng H, Alinnor J (2011) Trace metal deposition in soil from auto-mechanic village to urban residential areas in Owerri, Nigeria. Proc Environ Sci 4:310–322
Doumett S, Lamperi L, Checchini L, Azzarello E, Mugnai S, Mancuso S, Petruzzelli G, Del Bubba M (2008) Heavy metal distribution between contaminated soil and Paulownia tomentosa, in a pilot-scale assisted phytoremediation study: influence of different complexing agents. Chemosphere 72:1481–1490
Chokor AA (2016) Soil profile distribution of heavy metals in automobile workshops in Sapele, Nigeria. Int J Basic Sci Technol 2(1):30–38
Lange CN, Figueiredo AMG, Enzweiler J, Castro L (2017) Trace elements status in the terrain of an impounded vehicle scrapyard. Radioanal Nucl Chem 311(2):1323–1332
Werkenthin M, Kluge B, Wessolek G (2014) Metals in European roadside soils and soil solution—a review. Environ Pollut 189:98–110
Teng Y, Feng D, Wu J, Zuo R, Song L, Wang J (2015) Distribution, bioavailability, and potential ecological risk of Cu, Pb and Zn in soil in a potential groundwater source area. Environ Monit Assess 187:293–306
Imperato M, Adamo P, Arienzo M, Stanzione D, Violante P (2003) Spatial distribution of heavy metals in urban soils of Naples city (Italy). Eviron Pollut 124:247–256
Almeida FFM (1958) O Planalto Paulistano. In: Azevedo A (ed) A cidade de São Paulo. São Paulo, Associação dos Geógrafos Brasileiros, pp 113–167
Riccomini C, Coimbra AM (1992) Geologia da Bacia Sedimentar de São Paulo. In: Negro A, Ferreira AA, Alonso UR, Luz PAC (eds) Solos da cidade de São Paulo. ABMS-ABEF, São Paulo, pp 37–94
Crozera EH (2001) Identificação das áreas contaminadas no município de Ribeirão Pires—São Paulo. 205. Tese (Doutorado)—Instituto de Geociências, Universidade de São Paulo, São Paulo
Rocha G (ed) (2005) Mapa de Águas Subterrâneas do Estado de São Paulo, escala 1:1,000,000. CD-ROOM, São Paulo
CETESB (2016a) Companhia Ambiental do Estado de São Paulo. Relatório de qualidade de águas subterrâneas no Estado período de 1998–2000 http://aguassubterraneas.cetesb.sp.gov.br/wp-content/uploads/sites/13/2013/11/1998-2000-Relatorio-de-Qualidade-das-aguas-subterraneas.pdf (accessed 03 Mar 2016)
CETESB (2016b) Companhia Ambiental do Estado de São Paulo. Relatório de qualidade de águas subterrâneas no Estado período de 2004–2006 http://aguassubterraneas.cetesb.sp.gov.br/wp-content/uploads/sites/42/2013/11/qual_precambriano_2004_2006.pdf (accessed 03 Mar 2016)
Camargo OA, Moniz AC, Jorge JA, Valadares JMAS (2009) Métodos de Analise Química, Mineralógica e Física de Solos do Instituto Agronômico de Campinas. Campinas, Instituto Agronômico 77 (Boletim técnico, 106, Edição revista e atualizada)
Zambello F, Enzweiler J (2002) Multi-element analysis of soils and sediments by wavelength-dispersive X-ray fluorescence spectrometry. J Soils Sediment 2:29–36
APHA (1985) Standard methods for the examination of water and wastewater, 12th edn. American Public Health Assoc, New York
Müller G (1969) Index of geoaccumulation in sediments of the Rhine River. GeoJournal 2:108–118
Håkanson L (1980) An ecological risk index for aquatic pollution control. A sedimentological approach. Water Res 14:975–1001
Taylor SR, McLennan SH (1995) The geochemical evolution of the continental crust. Rev Geophys 33:241–265
Xu ZQ, Ni SJ, Tuo XG, Zhang CJ (2008) Calculation of heavy metals’ toxicity coefficient in the evaluation of potential ecological risk index. Environ Sci Technol 31(2):112–115
Statsoft (2005) Statistica 7.0 software. Tucksa
Alloway BJ (1995) Heavy metals in soils, 2nd edn. Blackie Academic & Professional, Great Britain
Guagliardi I, Cicchella D, de Rosa R, Ricca N, Buttafuoco N (2016) Geochemical souces of vanadium in soils: evidences in a Southern Italy área. J Geochem Explor. https://doi.org/10.1016/j.gexplo.2016.11.017
dos Santos-Araujo SN, Alleoni LRF (2016) Concentrations of potentially toxic elements in soils and vegetables from the macroregion of São Paulo, Brazil: availability for plant uptake. Environ Monit Assess 188:92
Oloye FF, Ololade IA, Oluwole OD, Bello MO, Olyuede OP, Ololade O (2014) Fate and potential mobility of arsenic (As) in the soil of mechanic workshops. Environ Pollut 3(4):70–78
Facchinelli A, Sacchi E, Mallen L (2001) Multivariate statistical and GIS-based approach to identify heavy metal sources in soils. Environ Pollut 114(3):313–324
Duong TTT, Lee BK (2001) Determining contamination level of heavy metals in road dust from busy traffic areas with different characteristics. J Environ Manage 92:554–562
CBMM (2017) Uses & End users of niobum http://www.cbmm.com.br/en/Pages/Uses-EndUsers-Niobium.aspx (accessed 23 Aug 17)
Mandal BK, Suzuki KT (2002) Arsenic round the world: a review. Talanta 58(1):201–235
US EPA (2001) National primary drinking water regulations: arsenic and clarifications to compliance and new source contaminants monitoring. In: Final Rule, Code of Federal Regulations 141–142
McMahon P, Chapelle F (2007) Redox processes and water quality of selected principal aquifer systems. Ground Water 46:259–271
Guo H, Zhang B, Wang G, Shen Z (2010) Geochemical controls on arsenic and rare earth elements approximately along a groundwaterflow path in the shallow aquifer of the Hetao Basin, Inner Mongolia. Chem Geol 270:112–117
Acknowledgements
We are grateful to Ribeirão Pires Municipality for permission to carry out this project and to Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq), for financial support. The author C.N. Lange thanks for the fellowship from the Brazilian Nuclear Energy Comission (CNEN).
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Lange, C.N., Figueiredo, A.M.G., Enzweiler, J. et al. Potentially toxic elements downward mobility in an impounded vehicle scrapyard. J Radioanal Nucl Chem 316, 819–830 (2018). https://doi.org/10.1007/s10967-018-5729-0
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DOI: https://doi.org/10.1007/s10967-018-5729-0