Journal of Radioanalytical and Nuclear Chemistry

, Volume 300, Issue 3, pp 1061–1073 | Cite as

Mass spectrometric analysis of selected radiolyzed amino acids in an astrochemical context

Article

Abstract

A selection of amino acids, namely arginine, proline and tyrosine previously irradiated to 3.2 mega-Gray in the solid state and analyzed by differential scanning calorimetry (DSC) and optical rotatory dispersion (ORD) were analyzed in the present work by mass spectrometry with the purpose to identify the radiolysis products and validate the results obtained previously with DSC and ORD. The radiolysis of amino acids is a top-down approach of a research program designed to assess the radiolysis resistance of these molecules for 4.6 × 109 years once buried in primitive bodies of the Solar System.

Keywords

Amino acids Radiolysis Mass spectrometry Arginine Proline Tyrosine 

Notes

Acknowledgments

We wish to thank Professor G. Angelini for helpful and lively discussion of the results.

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Copyright information

© Akadémiai Kiadó, Budapest, Hungary 2014

Authors and Affiliations

  • Cristina Cherubini
    • 1
  • Ornella Ursini
    • 1
  • Franco Cataldo
    • 2
  • Susana Iglesias-Groth
    • 3
  • Maria Elisa Crestoni
    • 4
  1. 1.CNR-Istituto di Metodologie ChimicheMonterotondoItaly
  2. 2.Actinium Chemical Research srlRomeItaly
  3. 3.Instituto de Astrofisica de CanariasTenerifeSpain
  4. 4.Dipartimento di Chimica e Tecnologie del FarmacoUniversità di Roma SapienzaRomeItaly

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