Journal of Radioanalytical and Nuclear Chemistry

, Volume 299, Issue 1, pp 591–598 | Cite as

Non-destructive radioanalytical technique in characterization of anion exchangers Amberlite IRN78 and Indion H-IP

  • P. U. SingareEmail author


The present study deals with characterization of industrial grade anion exchange resins Amberlite IRN78 and Indion H-IP for which non-destructive radiotracer technique using 131I and 82Br was used. The radioisotopes were used to trace the kinetics of iodide and bromide ion-isotopic exchange reactions taking place in the two resins. It was observed that under identical experimental conditions of 40.0 °C, 1.000 g of ion exchange resins and 0.003 M labeled iodide ion solution for iodide ion-isotopic exchange reaction, the values of specific reaction rate (min−1), amount of iodide ion exchanged (mmol), initial rate of iodide ion exchange (mmol min−1) and log K d were 0.285, 0.544, 0.155 and 12.6 respectively for Amberlite IRN78 resin, which was higher than 0.093, 0.315, 0.029 and 4.9 respectively as that obtained by using Indion H-IP resins. Also at a constant temperature of 40.0 °C, as the concentration of labeled iodide ion solution increases 0.001–0.004 M, the percentage of iodide ions exchanged increases from 68.10 to 74.00 % for Amberlite IRN78 resin, which was higher than the increase of 40.20–42.80 % as observed for Indion H-IP resins. The identical trend was observed for the two resins during bromide ion-isotopic exchange reaction. The overall results indicate that that under identical experimental conditions Amberlite IRN78 resins shows superior performance over Indion H-IP resins.


Non-destructive technique Radio analytical technique Reaction kinetics Ion-isotopic exchange reaction Amberlite IRN78 Indion H-IP 



The author is thankful to Professor Dr. R.S. Lokhande (Retired) for his valuable help and support by providing the required facilities so as to carry out the experimental work in Radiochemistry Laboratory, Department of Chemistry, University of Mumbai, Vidyanagari, Mumbai-58.


  1. 1.
    Application of ion exchange processes for the treatment of radioactive waste and management of spent ion exchangers (2002) Technical Reports Series No. 408, International Atomic Energy Agency, ViennaGoogle Scholar
  2. 2.
    Matsuda M, Funabashi K, Kawamura F, Uchida S, Ohsumi K (1987) Application of carboxylic acid cation exchange resin towater purification in nuclear power plants. Nucl Technol 78:62Google Scholar
  3. 3.
    Samanta SK, Ramaswamy M, Misra BM (1992) Studies on cesium uptake by phenolic resins. Sep Sci Technol 27:255–267CrossRefGoogle Scholar
  4. 4.
    Samanta SK, Theyyunni TK, Misra BM (1995) Column behavior of a resorcinol-formaldehyde polycondensate resin for radiocesium removal from simulated solution. J Nucl Sci Technol 32:425–429CrossRefGoogle Scholar
  5. 5.
    Bray LA, Elovich RJ, Carson KJ (1990) Cesium recovery using Savannah River Laboratory resorcinol-formaldehyde ion exchange resin, rep. PNL-7273. Pacific Northwest Lab, RichlandCrossRefGoogle Scholar
  6. 6.
    Singare PU, Lokhande RS, Madyal RS (2011) Thermal degradation studies of some strongly acidic cation exchange resins. Open J Phys Chem 1(2):45–54CrossRefGoogle Scholar
  7. 7.
    Singare PU, Lokhande RS, Madyal RS (2010) Thermal degradation studies of polystyrene sulfonic and polyacrylic carboxylic cationites. Rus J Gen Chem 80(3):527–532CrossRefGoogle Scholar
  8. 8.
    Tomoi M, Yamaguchi K, Ando R, Kantake Y, Aosaki Y, Kubota H (1997) Synthesis and thermal stability of novel anion exchange resins with spacer chains. J Appl Poly Sci 64(6):1161–1167CrossRefGoogle Scholar
  9. 9.
    Zhu L, Liu Y, Chen J (2009) Synthesis of N-methylimidazolium functionalized strongly basic anion exchange resins for adsorption of Cr(VI). Ind Eng Chem Res 48(7):3261–3267CrossRefGoogle Scholar
  10. 10.
    Kumaresan R, Sabharwal KN, Srinivasan TG, Vasudeva Rao PR, Dhekane G (2006) Evaluation of new anion exchange resins for plutonium processing. Solvent Extr Ion Exch 24(4):589–602CrossRefGoogle Scholar
  11. 11.
    Cortina JL, Warshawsky A, Kahana N, Kampel V, Sampaio CH, Kautzman RM (2003) Kinetics of goldcyanide extraction using ion-exchange resins containing piperazine functionality. React Funct Polym 54(1–3):25–35CrossRefGoogle Scholar
  12. 12.
    de Villiers JP, Parrish JR (1964) Rapid characterization of ion-exchange resins by NMR. J Polym Sci Part A 2(3):1331–1340Google Scholar
  13. 13.
    Harland CE (1994) Ion exchange 2nd edn. RSC Publishing, Cambridge, p 49–89. doi:  10.1039/9781847551184-00049, ISBN: 978-0-85186-484-6, eISBN: 978-1-84755-118-4
  14. 14.
    Zeng X, Murray GM (1996) Synthesis and characterization of site-selective ion-exchange resins templated for lead (II) ion. Sep Sci Technol 31(17):2403–2418CrossRefGoogle Scholar
  15. 15.
    Patel SA, Shah BS, Patel RM, Patel PM (2004) Synthesis, characterization and ion exchange properties of acrylic copolymers derived from 8-quinolinyl methacrylate. Iran Polym J 13(6):445–453Google Scholar
  16. 16.
    Liu H, Zhang S, Nie S, Zhao X, Sun X, Yang X, Pan W (2005) Preparation and characterization of a novel pH-sensitive ion exchange resin. Chem Pharm Bull (Tokyo) 53(6):631–633CrossRefGoogle Scholar
  17. 17.
    Masram DT, Kariya KP, Bhave NS (2010) A novel resin sef: synthesis, characterization and ion- exchange properties. Appl Sci Segm 1(1) APS/1513Google Scholar
  18. 18.
    Sood DD, Reddy AVR, Ramamoorthy N (2004) Applications of radioisotopes in agriculture and industry, in fundamentals of radiochemistry. Indian Association of Nuclear Chemists and Allied Scientists (IANCAS), p 289–297Google Scholar
  19. 19.
    Radiotracer Applications in Industry-A Guidebook (2004) Technical Reports Series No. 423, IAEA, ViennaGoogle Scholar
  20. 20.
    Clark MW, Harrison JJ, Payne TE (2011) The pH-dependence and reversibility of uranium and thorium binding on a modified bauxite refinery residue using isotopic exchange techniques. J Colloid Interface Sci 356(2):699–705CrossRefGoogle Scholar
  21. 21.
    Dagadu CPK, Akaho EHK, Danso KA, Stegowski Z, Furman L (2012) Radiotracer investigation in gold leaching tanks. Appl Radiat Isot 70(1):156–161CrossRefGoogle Scholar
  22. 22.
    Koron N, Bratkic A, Ribeiro Guevara S, Vahcic M, Horvat M (2012) Mercury methylation and reductionpotentials in marine water: an improved methodology using 197Hg radiotracer. Appl Radiat Isot 70(1):46–50CrossRefGoogle Scholar
  23. 23.
    Iwai Y, Yamanishi T, Hiroki A, Tamada M (2009) Radiation-induced degradation in ion exchange resins for a water detritiation system. Fusion Sci Technol 56(1):163–167Google Scholar
  24. 24.
    Lokhande RS, Ingale MN (1996) γ-Radiation effects on the nuclear grade ion exchanger resin-Indion-223. Asian J Chem 8(2):265–268Google Scholar
  25. 25.
    Singare PU, Lokhande RS (2012) Studies on ion-isotopic exchange reactions using nuclear grade ion exchange resins. Ionics 18(4):351–357CrossRefGoogle Scholar
  26. 26.
    Lokhande RS, Singare PU (2007) Comparative study on ion-isotopic exchange reaction kinetics by application of tracer technique. Radiochim Acta 95(03):173–176CrossRefGoogle Scholar
  27. 27.
    Lokhande RS, Singare PU, Patil VV (2008) Application of radioactive tracer technique to study the kinetics and mechanism of reversible ion-isotopic exchange reaction using strongly basic anion exchange resin Indion-850. Radiochemistry 50(06):638–641CrossRefGoogle Scholar
  28. 28.
    Lokhande RS, Singare PU (2008) Comparative study on iodide and bromide ion-isotopic exchange reactions by application of radioactive tracer technique. J Porous Mater 15(03):253–258CrossRefGoogle Scholar
  29. 29.
    Lokhande RS, Singare PU, Dole MH (2006) Comparative study on bromide and iodide ion-isotopic exchange reactions using strongly basic anion exchange resin duolite A-113. J Nucl Radiochem Sci 7(02):29–32CrossRefGoogle Scholar
  30. 30.
    Heumann KG, Baier K (1982) Chloride distribution coefficient on strongly basic anion-exchange resin: dependence on co-ion in alkali fluoride solutions. Chromatographia 15(11):701–703CrossRefGoogle Scholar
  31. 31.
    Singare PU, Lokhande RS, Patil VV, Prabhavalkar TS, Tiwari SRD (2010) Study on distribution coefficient of bromide ions from aqueous solution on ion exchange resins Indion-850, Indion-860 and Indion FF-IP. Eur J Chem 1(1):47–49CrossRefGoogle Scholar
  32. 32.
    Adachi S, Mizuno T, Matsuno R (1995) Concentration dependence of the distribution coefficient of malto oligosaccharides on a cation-exchange resin. J Chromatogr A 708:177–183CrossRefGoogle Scholar
  33. 33.
    Shuji A, Takcshi M, Ryuichi M (1996) Temperature dependence of the distribution coefficient of Malto oligosaccharides on cation-exchange resin in Na+ form. Biosci Biotechnol Biochem 60(2):338–340CrossRefGoogle Scholar

Copyright information

© Akadémiai Kiadó, Budapest, Hungary 2013

Authors and Affiliations

  1. 1.Department of ChemistryBhavan’s CollegeMumbaiIndia

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