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Journal of Radioanalytical and Nuclear Chemistry

, Volume 298, Issue 2, pp 835–845 | Cite as

Application of modified multiwall carbon nanotubes as a sorbent for zirconium (IV) adsorption from aqueous solution

  • R. YavariEmail author
  • R. Davarkhah
Article

Abstract

Modified multiwall carbon nanotubes (MWCNTs) by nitric acid solution were used to investigate the adsorption behavior of zirconium from aqueous solution. Pristine and oxidized MWCNTs were characterized using nitrogen adsorption/desorption isotherm, Boehm’s titration method, thermogravimetry analysis, transmission electron microscopy and Fourier transform infrared spectroscopy. The results showed that the surface properties of MWCNTs such as specific surface area, total pore volume, functional groups and the total number of acidic and basic sites were improved after oxidation. These improvements are responsible for their hydrophobic properties and consequently an easy dispersion in water and suitable active sites for more adsorption of zirconium. The adsorption of Zr(IV) as a function of initial concentration of zirconium, contact time, MWCNTs dosage, HCl and HNO3 concentration and also ionic strength was investigated using a batch technique under ambient conditions. The experimental results indicated that sorption of Zr(IV) was strongly influenced by zirconium concentrations, oxidized MWCNTs content and acid pH values. The calculated correlation coefficient of the linear regressions values showed that Langmuir model fits the adsorption equilibrium data better than the Freundlich model. Kinetic data of sorption indicated that equilibrium was achieved within 60 min and the adsorption process can be described by the pseudo second-order reaction rate model. Based on the experimental results, surface complexation is the major mechanism for adsorption of Zr(IV) onto MWCNTs. Also, Study on the desorption process of zirconium showed that the complete recovery can be obtained using nitric or hydrochloric acids of 4 M.

Keywords

Multiwall carbon nanotubes Zirconium (IV) Adsorption Desorption Functional groups 

References

  1. 1.
    Iijima S (1991) Helical microtubules of graphitic carbon. Nature 354:56–58CrossRefGoogle Scholar
  2. 2.
    Iijima S, Ichihashi T (1993) Single-shell carbon nanotubes of 1 nm diameter. Nature 363:603–605CrossRefGoogle Scholar
  3. 3.
    Dai LM, Mau AWH (2001) Controlled synthesis and modification of carbon nanotubes and C60: carbon nanostructures for advanced polymeric composite materials. Adv Mater 13:899–913CrossRefGoogle Scholar
  4. 4.
    Merkoci A (2006) Carbon nanotubes in analytical sciences. Microchim Acta 152:157–174CrossRefGoogle Scholar
  5. 5.
    Ren X, Chen C, Nagatsu M, Wang X (2011) Carbon nanotubes as adsorbents in environmental pollution management: a review. Chem Eng J 170:395–410CrossRefGoogle Scholar
  6. 6.
    Chena GC, Shana XQ, Wanga YS, Wena B, Peia ZG, Xiec YN, Liuc T, Pignatellod JJ (2009) Adsorption of 2,4,6-trichlorophenol by multi-walled carbon nanotubes as affected by Cu(II). Water Res 43:2409–2418CrossRefGoogle Scholar
  7. 7.
    Lu C, Chung YL, Chang KF (2006) Adsorption thermodynamic and kinetic studies of trihalomethanes on multiwalled carbon nanotubes. J Hazard Mater 138:304–310CrossRefGoogle Scholar
  8. 8.
    Yang K, Wang X, Zhu L, Xing B (2006) Competitive sorption of pyrene, phenanthrene, and naphthalene on multi walled carbon nanotubes. Environ Sci Technol 40:5804–5810CrossRefGoogle Scholar
  9. 9.
    Kombarakkaran J, Clewett CFM, Pietra T (2007) Ammonia adsorption on multi-walled carbon nanotubes. Chem Phys Lett 441:282–285CrossRefGoogle Scholar
  10. 10.
    Du D, Wang M, Zhang J, Cai J, Tu H, Zhang A (2008) Application of multiwalled carbon nanotubes for solid-phase extraction of organophosphate pesticide. Electrochem Commun 10:85–89CrossRefGoogle Scholar
  11. 11.
    Kuo CY, Lin HY (2009) Adsorption of aqueous cadmium (II) onto modified multi-walled carbon nanotubes following microwave/chemical treatment. Desalination 249:792–796CrossRefGoogle Scholar
  12. 12.
    Shamspur T, Mostafavi A (2009) Application of modified multiwalled carbon nanotubes as a sorbent for simultaneous separation and preconcentration trace amounts of Au(III) and Mn(II). J Hazard Mater 168:1548–1553CrossRefGoogle Scholar
  13. 13.
    Yang S, Li J, Shao D, Hu J, Wang K (2009) Adsorption of nickel (II) on oxidized multiwall carbon nanotubes. J Hazard Mater 66:109–116CrossRefGoogle Scholar
  14. 14.
    Xu D, Tan X, Chen C, Wang X (2008) Removal of lead (II) from aqueous solution by oxidized multiwalled carbon nanotubes. J Hazard Mater 154:407–416CrossRefGoogle Scholar
  15. 15.
    Wu CH (2007) Studies of the equilibrium and thermodynamics of the adsorption of copper (II) onto as-produced and modified carbon nanotubes. J Colloid Interface Sci 311:338–346CrossRefGoogle Scholar
  16. 16.
    Tuzen M, Soylak M (2007) Multiwall carbon nanotubes for speciation of chromium in environmental samples. J Hazard Mater 147:219–225CrossRefGoogle Scholar
  17. 17.
    Lu C, Chiu H, Liu C (2006) Removal of zinc (II) from aqueous solution by purified carbon nanotubes: kinetics and equilibrium studies. Ind Eng Chem Res 45:2850–2855CrossRefGoogle Scholar
  18. 18.
    Wang XK, Chen CL, Hu WP, Ding AP, Xu D, Zhou X (2005) Sorption of Amersium-243 to multi-wall carbon nanotubes. Environ Sci Technol 39:2856–2860CrossRefGoogle Scholar
  19. 19.
    Chen CL, Li XL, Wang XK (2007) Application of oxidized multi-wall carbon nanotubes for thorium (IV) adsorption. Radiochim Acta 95:261–266CrossRefGoogle Scholar
  20. 20.
    Tan XL, Xu D, Chen CL, Wang XK, Hu WP (2008) Adsorption and kinetic desorption study of 152+154Eu(III) on multiwall carbon nanotubes from aqueous solution by using chelating resin and XPS methods. Radiochim Acta 96:23–30Google Scholar
  21. 21.
    Sun Y, Yang S, Sheng G, Guo Z, Wang Z (2012) The removal of U(VI) from aqueous solution by oxidized multiwalled carbon nanotubes. J Environ Radioact 105:40–47CrossRefGoogle Scholar
  22. 22.
    Yavari R, Huang YD, Ahmadi SJ (2011) Adsorption of cesium (I) from aqueous solution using oxidized multiwall carbon nanotubes. J Radioanal Nucl Chem 287:393–401CrossRefGoogle Scholar
  23. 23.
    Yavari R, Huang YD, Mostofizadeh A (2012) Sorption of strontium ions from aqueous solutions by oxidized multiwall carbon nanotubes. J Radioanal Nucl Chem 285:703–710CrossRefGoogle Scholar
  24. 24.
    Xiong BK, Wen WG, Yang XM, Li HY, Luo FL, Zhang W, Guo JM (2006) Zirconium and hafnium metallurgy [M]. Metallurgical Industry Press, BeijingGoogle Scholar
  25. 25.
    Pourreza N, Mouradzadegun A, Mohammadi S (2011) Solid phase extraction of zirconium as arseazo (III) complex on agar and spectrophotometric determination. J Iran Chem Soc 8:951–957CrossRefGoogle Scholar
  26. 26.
    Zhang A, Wei A, Kumagai M (2003) Properties and mechanism of molybdenum and zirconium adsorption by a macroporous silica-based extraction resin in the MAREC process. Solvent Extr Ion Exch 21:591–611CrossRefGoogle Scholar
  27. 27.
    Rajmane MM, Sargar BM, Mahamuni SV, Anuse MA (2006) Solvent extraction separation of zirconium (IV) from succinate media with N-n-octylaniline. J Serbian Chem Soc 71:223–234CrossRefGoogle Scholar
  28. 28.
    Basargin NN, Oskotskaya ER, Simakov PE, Rozovskii YG (2008) Zirconium sorption by chelating polymer sorbents with an o, o′-dihydroxyazo analytical functional group. Russ J Inorg Chem 53:1972–1976CrossRefGoogle Scholar
  29. 29.
    Bradbrook JS, Lorimer GW, Ridley N (1972) The precipitation of zirconium hybrides in zirconium and zircaloy-2. J Nucl Mater 42:142–160CrossRefGoogle Scholar
  30. 30.
    Nguyen HV, Luu ST, Rakov EG (2012) Ion-exchange zirconium sorption by functionalized carbon nanofibers. Inorg Mater 48:128–131CrossRefGoogle Scholar
  31. 31.
    Rao GP, Lu C, Su F (2007) Sorption of divalent metal ions from aqueous solution by carbon nanotubes: a review. Sep Purif Technol 58:224–231CrossRefGoogle Scholar
  32. 32.
    Vukovic GD, Marinkovic AD, Colic M, Ristic MD, Aleksic R, Peric-Grujic AA, Uskokovic PS (2010) Removal of cadmium from aqueous solutions by oxidized and ethylenediamine-functionalized multi-walled carbon nanotubes. Chem Eng J 157:238–248CrossRefGoogle Scholar
  33. 33.
    Kosa SA, Al-Zhrani G, Abdel Salam M (2012) Removal of heavy metals from aqueous solutions by multi-walled carbon nanotubes modified with 8-hydroxyquinoline. Chem Eng J 181–182:159–168CrossRefGoogle Scholar
  34. 34.
    Boehm HP (1994) Some aspects of the surface chemistry of carbon blacks and other carbons. Carbon 2:759–769CrossRefGoogle Scholar
  35. 35.
    Sing K, Everett D, Haul R, Moscou L, Pierotti R, Rouquerol J, Siemieniewska T (1985) Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity. Pure Appl Chem 57:603–619CrossRefGoogle Scholar
  36. 36.
    Kiselev AV (1968) Adsorption properties of hydrophobic surface. J Colloid Interface Sci 28:430–442CrossRefGoogle Scholar
  37. 37.
    Li YH, Wang S, Luan Z (2003) Adsorption of cadmium (II) from aqueous solution by surface oxidized carbon nanotubes. Carbon 41:1057–1062CrossRefGoogle Scholar
  38. 38.
    Malik DJ, Warwick GL, Venturi M, Streat M, Hellgardt K, Hoenich NA (2004) Preparation of novel mesoporous carbons for the adsorption of an inflammatory cytokine (IL-1). Biomaterials 24:2933–2940CrossRefGoogle Scholar
  39. 39.
    Xu J, Yao P, Li X, He F (2008) Synthesis and characterization of water soluble and conducting sulfonated polyaniline/para- henylenediaminefunctionalized multi-walled carbon nanotubes nano-composite. Mater Sci Eng B 151:210–219CrossRefGoogle Scholar
  40. 40.
    Bustero I, Ainara GA, Isabel O, Roberto MO, Inés RN, Amaya A (2006) Control of the properties of carbon nanotubes synthesized by CVD for application in electrochemical biosensors. Microchim Acta 152:239–247CrossRefGoogle Scholar
  41. 41.
    Atkins PW, Paula JD (2009) Physical chemistry. Oxford University Press, OxfordGoogle Scholar
  42. 42.
    Velickovic Z, Vukovic GD, Marinkovic AD, Moldovan MS, Peric-Grujic AA, Uskokovic PS, Risti MD (2012) Adsorption of arsenate on iron (III) oxide coated ethylenediamine functionalized multiwall carbon nanotubes. Chem Eng J 181–182:174–181CrossRefGoogle Scholar
  43. 43.
    Hsieh SH, Horng JJ (2007) Adsorption behavior of heavy metal ions by carbon nanotubes grown. J Univ Sci Technol Beijing 14:77–84CrossRefGoogle Scholar
  44. 44.
    Pourbaix M (1974) Atlas of electrochemical equilibria in aqueous solutions. The University of Michigan: National Association of Corrosion Engineers, HoustonGoogle Scholar
  45. 45.
    Johnson JS, Kraus KA, Holmberg RW (1956) Hydrolytic behavior of metal ions. J Am Chem Soc 78:26–32CrossRefGoogle Scholar
  46. 46.
    Wang SG, Gong WX, Liu XW, Yao YW, Gao BY, Yue QY (2007) Removal of lead(II) from aqueous solution by adsorption onto manganese oxide-coated carbon nanotubes. Sep Purif Technol 58:17–23CrossRefGoogle Scholar

Copyright information

© Akadémiai Kiadó, Budapest, Hungary 2013

Authors and Affiliations

  1. 1.Nuclear Science and Technology Research Institute, NFCSTehranIran

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