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Copolymers of isobornylacrylate with methylmethacrylate or acrylonitrile and its optical properties


Materials based on copolymers of isobornylacrylate (IBA) with methylmethacrylate (MMA) or acrylonitrile (AN) have been synthesized by radical copolymerization using monomeric mixtures with different composition. The copolymer compositions were determined and relative activities of monomers were calculated by different methods. All copolymers have transparency up to 80% in the ultraviolet region. The mechanical and thermophysical properties of the copolymers depend on composition. The best combination of optical transparency and tensile strength is achieved in the copolymers containing 13% and 49% units of IBA (in the case of MMA and AN, respectively. The prospects of application of the copolymers as a matrix for creating photoinduced nanocomposites containing CdS are shown. Using the specially selected compounds of cadmium, materials with new optical properties were obtained by UV irradiation.

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  1. 1.

    Batishche SA, Kouzmouk AA, Tatur GA (2013) A high-efficiency stimulated Raman scattering (SRS) converter of laser radiation of nanosecond duration on the basis of quartz optical fibers. Instrum Exp Tech 56:193–199

  2. 2.

    Fedotov YV, Chernavskaya OA, Belov ML, Gorodnichev VA, Shteingart AD (2015) Laser remote method of detection and classification of the oil spill on the ground surface. Radiooptics of the Bauman MSTU 3:27–41

  3. 3.

    CERN (2009) PH/DT, CERN, PH-EP-Tech-Note-2009-003, Accessed 26 Oct 2009

  4. 4.

    Lamonte R, McNally D, Summit NJ (2000) Uses and processing of cyclic olefin copolymers (COC). Plast Eng 56:51–56

  5. 5.

    Nielsen T, Nilsson D, Bundgaard F, Shi P, Szabo P, Geschke O, Kristensen A (2004) Nanoimprint lithography in the cyclic olefin copolymer, Topas, a highly ultraviolet-transparent and chemically resistant thermoplast. J Vac Sci Technol B 22:1770–1775

  6. 6.

    Bundgaard F, Geschke O (2006) Prototyping of multilayer waveguides with V-grooves in COC/TOPAS®. 4M 2006 - second international conference on multi-material micro manufacture, pp 75–78

  7. 7.

    Yuan W, Khan L, Webb DJ, Kalli K, Rasmussen HK, Stefani A, Bang O (2011) Humidity insensitive Topas polymer fiber bragg grating sensor. Opt Express 19:19731–19739

  8. 8.

    Biron M (2007) Thermoplastics and thermoplastic composites: technical information for plastic users. Elsevier Science, Oxford

  9. 9.

    Shepurev EI (1986) Optical properties of glassy organic polymers. Soviet Journal of Optical Technology 1:51–55

  10. 10.

    Haselwandel TFA, Heitz W, Kriugel SA, Wendorff JH (1996) Polynorbornene: synthesis, properties and simulations. Macromol Chem Phys 197:3435–3453

  11. 11.

    Kim BS, Park JH, Hong N, Bae J, Yang C, Shin K (2013) Ultrathin carbon film from carbonization of spin-cast polyacrylonitrile film. J Ind Eng Chem 19:1631–1637

  12. 12.

    Liu Y, Liu Y, Lee JH, Lee C, Park M, Kim HY (2015) Ultrafine formation of optically transparent Polyacrylonitrile/polyacrylic acid nanofibre fibrils via electrospinning at high relative humidity. Compos Sci Technol 117:404–409

  13. 13.

    Alexandrov A, Smirnova L, Yakimovich N, Sapogova N, Soustov L, Kirsanov A, Bityurin N (2005) UV initiated growth of gold nanoparticles in PMMA matrix. Appl Surf Sci 248:181–184

  14. 14.

    Camposeo A, Polo M, Neves AAR, Fragouli D, Persano L, Molle S, Laera AM, Piscopiello E, Resta V, Athanassiou A, Cingolani R, Tapfer L, Pisignano D (2012) Multi-photon in situ synthesis and patterning of polymer-embedded nanocrystals. J Mater Chem 22:9787–9793

  15. 15.

    Scalbi S, Fantin V, Antolini F (2017) Environmental assessment of new technologies: production of a quantum dots-light emitting diode. J Clean Prod 142:3702–3718

  16. 16.

    Ramasamy K, Malik MA, Helliwell M, Raftery J, O’Brien P (2011) Thio- and dithio-biuret precursors for zinc sulfide, cadmium sulfide, and zinc cadmium sulfide thin films. Chem Mater 23:1471–1481

  17. 17.

    Smirnov AA, Afanasiev A, Ermolaev N, Bityurin N (2016) LED induced green luminescence in visually transparent PMMA films with CdS precursor. Optical Materials Express 6:290–295

  18. 18.

    Tudos F, Kelen T, Foldes-Berezhnykh T, Turcsanyi B (1975) Evaluation of high conversion copolymerization data by a linear graphical method. React Kinet Catal Lett 2:439–447

  19. 19.

    Begantsova YE, Malyshev AS, Zaitsev SD, Semchikov YD (2002) Copolymerization of styrene with acrylamide in dimethylsulfoxide. Polymer Science А 44:329–334

  20. 20.

    Kulikov EE, Zaitsev SD, Semchikov YD (2015) Reversible addition-fragmentation chain transfer (RAFT) (co)polymerization of isobornyl acrylate. Polymer Science C 57:120–127

  21. 21.

    Ehlert S, Stegelmeier C, Pirner D, Forster S (2015) A general route to optically transparent highly filled polymer nanocomposites. Macromolecules 48(15):5323–5327

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This work was carried out with the financial support of the Russian Scientific Foundation (project No. 14-19-01702) and partly the Common Use “New Materials and Resource-Saving Technologies” (N.I. Lobachevsky State University of Nizhny Novgorod, project No. 14.594.21.0005 - RFMEFI59414X0005).

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Correspondence to L. A. Smirnova.

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Budnikov, S.Y., Smirnov, A.A., Vorozhtsov, D.L. et al. Copolymers of isobornylacrylate with methylmethacrylate or acrylonitrile and its optical properties. J Polym Res 27, 59 (2020).

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  • Radical copolymerization
  • Relative activities
  • Optical transparency
  • Photoinduced nanocomposites