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Thiophene decorated block copolymers templated from poly(styrene-alt-maleic anhydride)-block-poly(styrene) one-shot block copolymer: effect of thiophene inclusion on morphology

  • Benoît H. Lessard
  • Milan Marić
Original Paper

Abstract

Poly(styrene-alt-maleic anhydride) copolymer and poly(styrene-alt-maleic anhydride)-block-poly(styrene) block copolymer with narrow molecular weight distributions were synthesized by nitroxide mediated radical polymerization (NMP) and the anhydride units were selectively converted to thiophene units. The thiophene decorated poly(styrene-alt-maleic anhydride) copolymer was emulsified in water, resulting in rod-like or cylindrical morphologies with diameters ≈ 90 nm while the non-decorated copolymers and thiophene decorated block copolymer resulted in spheres.

Keywords

Styrene and maleic anhydride Water dispersible Worm/rod-like morphology Thiophene Nitroxide mediated polymerization (NMP) 

Notes

Acknowledgments

We thank the Canada Foundation for Innovation (CFI) New Opportunities Fund and the NSERC Discovery Grant 288125–09 for funding this work. We would also like to thank Dr. Dmitrii Perepichka for the use of his laboratory and equipment to run the conductivity measurements along with Dr. Brandon Djukic for his help in performing the conductivity measurements. We would also like to thank the Centre for Self-Assembled Chemical Structures (CSACS) for the use of the FT-IR.

Supplementary material

10965_2016_931_MOESM1_ESM.doc (362 kb)
ESM 1 (DOC 361 kb)

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Copyright information

© Springer Science+Business Media Dordrecht 2016

Authors and Affiliations

  1. 1.Department of Chemical and Biological EngineeringUniversity of OttawaOttawaCanada
  2. 2.Department of Chemical EngineeringMcGill UniversityMontrealCanada

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