New biosourced alternated poly(ether)Ester-Amides (PeEA): synthesis and combined NMR/MALDI ToF MS characterization

  • Raouf MedimaghEmail author
  • Asma Saadaoui
  • Salma Mghirbi
  • Sylvain Marque
  • Damien Prim
  • Aurélie Fildier
  • Audrey Bulete
  • Guy Raffin
  • Saber ChattiEmail author
Original Paper


New biosourced alternated poly(ether)Ester-Amides PeEA were prepared by polycondensation in solution or in bulk of unprecedented aminoalcohols based on 1,4:3,6-dianhydrohexitols (DAH) with aromatic and aliphatic diacyl chlorides (sebacoyl, terephtaloyl and isophtaloyl). Optimization of the polymerization in solution has been investigated using MALDI ToF MS and NMR spectroscopy to ascertain the structures and end chain nature of the resulting polymers. The influence of the DAH stereochemistry and the polymerization mode on the structures and thermal properties was demonstrated by MALDI ToF and complementary analytical techniques (DSC and SEC). Isomannide based polymers revealed amorphous but showed higher Tg (around 80 °C for sebacoyl and 180 °C for isophtaloyl) whereas the isosorbide based polymers were semi crystalline. Best properties were obtained in bulk using isomannide based aminoalcohol and sebacoyl chloride (Tg of 82 °C and Mw of 32 kDa, PDI = 1.41).


1,4-3,6-dianhydrohexitols Alternated poly(ether)Ester-Amides Biobased MALDI ToF mass spectrometry Polycondensation 



Authors are grateful to Société Roquette Lestrem for a kind gift of Isosorbide and Isomannide. The authors want to thank the Tunisian Ministry of Higher Education and Research and the French Foreign affairs Ministry for Financial support (Project “PHC Utique” 13G/1211). Authors want to thanks all INRAP staff especially (Mr Chaouki Belgacem and Mohamed Mezni, Mrs Saloua Ben Aissa and Monia Elouni) for analysis and helpful discussions.


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Copyright information

© Springer Science+Business Media Dordrecht 2014

Authors and Affiliations

  • Raouf Medimagh
    • 1
    Email author
  • Asma Saadaoui
    • 1
    • 2
  • Salma Mghirbi
    • 1
  • Sylvain Marque
    • 2
  • Damien Prim
    • 2
  • Aurélie Fildier
    • 3
  • Audrey Bulete
    • 3
  • Guy Raffin
    • 3
  • Saber Chatti
    • 3
    Email author
  1. 1.Laboratoire des Substances Naturelles (LSN), LR10 INRAP 02Institut National de Recherche et d’Analyse Physico-chimique INRAPArianaTunisia
  2. 2.Université de Versailles-St-Quentin (UVSQ)Institut Lavoisier de Versailles (ILV) UMR CNRS 8180Versailles CedexFrance
  3. 3.Université de Lyon, UMR 5280Institut des Sciences Analytiques (ISA)VilleurbanneFrance

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