Determination of the cross-linking degree of commercial ethylene-vinyl-acetate polymer by luminescence spectroscopy
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Abstract
Ethylene-Vinyl-Acetate is the most common encapsulation polymer in photovoltaic modules. Its degree of crosslinking is a critical parameter of the production process, greatly influencing the durability of the product. The luminescence of Ethylene-Vinyl-Acetate with UV excitation is presented here as a non-destructive method to determine the degree of crosslinking. The luminescence intensity increases with the degree of crosslinking. Supposing a linear correlation the method allows determining the degree of crosslinking with a relative precision of 12 %. This optical method it is suitable and comparatively easy to apply for an industrial in-line measurement.
Keywords
Luminescence Spectroscopy EVA Photovoltaics Cross-linkingReferences
- 1.Hirschl C, Biebl - Rydlo M, DeBiasio M, Mühleisen W, Neumaier L, Scherf W, Oreski G, Eder G, Chernev B, Schwab W, Kraft M (2013) Determining the degree of crosslinking of ethylene vinyl acetate photovoltaic module encapsulants—a comparative study. Sol Energy Mater Sol Cells 116(0):203–218. doi: 10.1016/j.solmat.2013.04.022 CrossRefGoogle Scholar
- 2.Czanderna AW, Pern FJ (1996) Encapsulation of PV modules using ethylene vinyl acetate copolymer as a pottant: a critical review. Sol Energy Mater Sol Cells 43(2):101–181CrossRefGoogle Scholar
- 3.Jordan DC, Kurtz SR (2013) Photovoltaic degradation rates—an analytical review. Prog Photovolt Res Appl 21(1):12–29. doi: 10.1002/pip.1182 CrossRefGoogle Scholar
- 4.Morlier A, Klotz S, Sczuka S, Kunze I, Schaumann I, Blankemeyer S, Siegert M, Döring T, Alshuth T, Giese U, Denz M, Köntges M Influence of the curing state of ethylene-vinyl acetate on photovoltaic modules aging. In: 28th European Photovoltaic Solar Energy Conference, 2013.Google Scholar
- 5.Jurga J, Voelkel A, Strzemiecka B (2009) Application of different analytical methods used in the study of the cross-linking of resins in intermediate-product used in manufacturing of abrasive articles. J Appl Polym Sci 112(6):3305–3312. doi: 10.1002/App.29840 CrossRefGoogle Scholar
- 6.Kajari-Schröder S, Eitner U, Oprisoni C, Alshuth T, Köntges M, Brendel R (2010) Modelling the Curing Dynamics of Ethylene-Vinyl Acetate. Paper presented at the 25th European Photovoltaic Solar Energy Conference, Valencia, Spain,Google Scholar
- 7.ASTM International (2006) Standard Test Methods for Determination of Gel Content and Swell Ratio of Crosslinked Ethylene Plastics. ASTM International; SAI Global,Google Scholar
- 8.Schubnell M (2010) Investigation of curing reaction of EVA by DSC and DMA. Photovoltaics Int 7:131–137Google Scholar
- 9.Xia Z, Cunningham D, Wohlgemuth J (2009) A new Method for measuring crosslinking density in ethylene vinyl acetate-based encapsulant. Photovoltaics International 5 (150)Google Scholar
- 10.Stark W, Jaunich M, Bohmeyer W, Lange K (2012) Investigation of the crosslinking behaviour of ethylene vinyl acetate (EVA) for solar cell encapsulation by rheology and ultrasound. Polym Test 31:904–908CrossRefGoogle Scholar
- 11.Mühleisen W, Biebl-Rydlo M, Spielberger M (2011) Acoustic in situ Determination of EVA features. Paper presented at the 26th European Photovoltaic Solar Energy Conference,Google Scholar
- 12.Schulze S (2010) Verfahren und Vorrichtung zur Steuerung der Temperaturführung bei einem thermischen Laminationsprozess.Google Scholar
- 13.Li H-Y, Perret-Aebi L-E, Théron R, Ballif C, Luo Y, Lange RFM (2011) Optical transmission as a fast and non-destructive tool for determination of ethylene-co-vinyl acetate curing state in photovoltaic modules. Prog Photovolt: Res App:187–194Google Scholar
- 14.Schlothauer J, Jungwirth S, Köhl M, Röder B (2012) Degradation of the encapsulant polymer in outdoor weathered photovoltaic modules: spatially resolved inspection of EVA ageing by fluorescence and correlation to electroluminescence. SolEnergy Mater SolCells. doi: 10.1016/j.solmat.2012.03.022 Google Scholar
- 15.Köntges M, Kajari-Schröder S, Kunze I Cell cracks measured by UV fluorescence in the field. In: Proceedings of the 27th European Photovoltaic Solar Energy Conference, 2012.Google Scholar
- 16.Röder B, Ermilov EA, Philipp D, Köhl M Observation of polymer degradation processes in photovoltaic modules via luminescence detection. In: SPIE 7048, Reliability of Photovoltaic Cells, Modules, Components, and Systems, 2008.Google Scholar
- 17.Jolliffe IT (2002) Principal Component Analysis. Springer series in statistics, 2nd Edition edn. Springer Series in Statistics,Google Scholar
- 18.Duarte AC, Capelo S (2006) Application of chemometrics in separation science. J Liq Chromatogr Relat Technol 29:1143–1176. doi: 10.1080/10826070600574929 CrossRefGoogle Scholar
- 19.Strzemiecka B, Heberger K, Voelkel A (2013) Similarity and grouping of perlite and zeolite abrasive fillers: a replacement test. J Appl Polym Sci 127(5):3839–3847. doi: 10.1002/App.37695 CrossRefGoogle Scholar
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