Journal of Polymer Research

, 19:9744

Easy one-pot method to control the morphology of polyethylene/carbon nanotube nanocomposites using metallocene catalysts

  • Bijal Kottukkal Bahuleyan
  • Muataz Ali Atieh
  • Sadhan Kumar De
  • Masihullah Jabarulla Khan
  • Mamdouh A. Al-Harthi
Original Paper

Abstract

An easy one pot method is demonstrated for the controlled periodical surface coating of polyethylene over multiwalled carbon nanotubes (MWCNT) by insitu polymerization of ethylene using highly active metallocene catalysts (Cp2ZrCl2 and Cp2TiCl2) in combination with methylalumoxane. The crystallinity of the nanocomposite was increased and its morphology could be tuned from “sausage” like to “shish-kebab” in the presence of CNT depending on the experimental condition and choice of metal atom.

Figure

A convenient one-pot method is illustrated to control the morphology of polymer nanocomposite by simple mixing of metallocene catalyst (Cp2ZrCl2 or Cp2TiCl2) and MWCNT in toluene at normal conditions followed by the activation with MAO. The crystallinity of the nanocomposite is increased and the polymer morphology could be tuned from “sausage” like to “shish-kebab”, depending on the experimental conditions.

Keywords

Carbon nanotube Metallocene catalysts Nanocomposites Polymerization Polyolefins 

References

  1. 1.
    Jancar J, Douglas JF, Starr FW, Kumar SK, Cassagnau P, Lesser AJ, Sternstein SS, Buehler MJ (2010) Polymer 51:3321–3343CrossRefGoogle Scholar
  2. 2.
    Jeon IY, Baek JB (2010) Materials 3:3654–3674CrossRefGoogle Scholar
  3. 3.
    Sahooa NG, Ranab S, Chob JW, Li L, Chan SH (2010) Prog Polym Sci 35:837–867CrossRefGoogle Scholar
  4. 4.
    Moniruzzaman M, Winey KI (2006) Macromolecules 39:5194–5205CrossRefGoogle Scholar
  5. 5.
    Yi L, Meziani MJ, Ya-Ping S (2007) J Mater Chem 17:1143–1148CrossRefGoogle Scholar
  6. 6.
    Xiea XL, Maia YW, Zhoub XP (2005) Mater Sci Eng 49:89–112CrossRefGoogle Scholar
  7. 7.
    As’habi L, Jafari SH, Khonakdar HA, Baghaei B (2011) J Polym Res 18:197–205CrossRefGoogle Scholar
  8. 8.
    Saeed K, Park SY (2010) J Polym Res 17:535–540CrossRefGoogle Scholar
  9. 9.
    Alexandre M, Martin E, Dubois P, Marti M, Jerome R (2001) Chem Mater 13:236–237CrossRefGoogle Scholar
  10. 10.
    Bonduel D, Mainil M, Alexandre M, Monteverde F, Dubois P (2005) Chem. Commun. 781–783Google Scholar
  11. 11.
    Funck A, Kaminsky W (2006) Compos Sci Technol 67:906–915CrossRefGoogle Scholar
  12. 12.
    Dubois P, Alexandre M (2006) Adv Eng Mater 8:147–154CrossRefGoogle Scholar
  13. 13.
    Peeterbroeck S, Lepoittevin B, Pollet E, Benali S, Broekaert C, Alexandre M (2006) Polym Eng Sci 46:1022–1030CrossRefGoogle Scholar
  14. 14.
    Dong X, Wang L, Sun T, Zhou J, Yang J (2006) Mol Catal A: Chem 255:10–15CrossRefGoogle Scholar
  15. 15.
    Dong X, Wang L, Deng L, Li J, Hao J (2007) Mater Lett 61:3111–3115CrossRefGoogle Scholar
  16. 16.
    Bredeau S, Peeterbroeck S, Bonduel D, Alexandre M, Dubois P (2008) Polym Int 57:547–553CrossRefGoogle Scholar
  17. 17.
    Bahuleyan BK, Lee U, Ha CS, Kim I (2008) Appl Catal A: Gen 351:36–44CrossRefGoogle Scholar
  18. 18.
    Xia W, Taniike T, Terano M, Fujitani T, Liu B, Soares JBP (2009) Macromol Symp 285:74–80CrossRefGoogle Scholar
  19. 19.
    Monrabal B, Tello JS, Mayo N, Romero L (2007) Macromol Symp 257:71–79CrossRefGoogle Scholar
  20. 20.
    Bahuleyan BK, Jermy BR, Ahn IY, Park DW, Ha CS, Kim I (2009) Catal Commun 11:252–256CrossRefGoogle Scholar
  21. 21.
    Bahuleyan BK, Son BC, Ha YS, Lee SH, Suh H, Kim I (2010) J Mater Chem 20:7150–7157CrossRefGoogle Scholar
  22. 22.
    Park S, Yoon SW, Choi H, Lee JS, Cho WK, Kim J, Park HJ, Yun WS, Choi CH, Do Y, Choi IS (2008) Chem Mater 20:4588–4594CrossRefGoogle Scholar
  23. 23.
    Park S, Yoon SW, Lee KB, Kim DJ, Jung YH, Do Y, Park HJ, Choi IS (2006) Macromol Rapid Commun 27:47–50CrossRefGoogle Scholar
  24. 24.
    Kaminsky W (1998) J. Chem Soc. Dalton Trans. 1413–1418Google Scholar
  25. 25.
    Hlatky GG (1996) Coord Chem Rev 181:243–296CrossRefGoogle Scholar
  26. 26.
    Kang KK, Oh JK, Jeong YT, Shiono T, Ikeda T (1999) Macromol Rapid Commun 20:308–311CrossRefGoogle Scholar
  27. 27.
    Qian Y, Zhang H, Zhou J, Zhao W, Sun X, Huang J (2004) J Mol Catal A: Chem 208:45–54CrossRefGoogle Scholar
  28. 28.
    Bahuleyan BK, Son GW, Park DW, Ha CS, Kim I (2008) J Polym Sci Part A: Polym Chem 46:1066–1082CrossRefGoogle Scholar
  29. 29.
    Trujillo M, Arnal MLA, Muller J, Laredo E, Bredeau S, Bonduel D, Dubois P (2007) Macromolecules 40:6268–6276CrossRefGoogle Scholar
  30. 30.
    Bonduel D, Bredeau S, Alexandre M, Monteverde F, Dubois P (2007) J Mater Chem 17:2359–2366CrossRefGoogle Scholar
  31. 31.
    Srarck P, Lehmus P, Seppala JV (1999) Polym Eng Sci 39:1444–1455CrossRefGoogle Scholar
  32. 32.
    Nieto J, Oswald T, Blanco F, Soares JBP, Monrabal B (2001) J Polym Sci, Part B: Polym Phys 39:1616–1628CrossRefGoogle Scholar
  33. 33.
    Soares JBP, Anantawaraskul S (2005) J Polym Sci, Part B: Polym Phys 43:1557–1570CrossRefGoogle Scholar
  34. 34.
    Britto LJD, Soares JBP, Penlidis A, Monrabal B (1999) J Polym Sci, Part B: Polym Phys 37:539–552CrossRefGoogle Scholar
  35. 35.
    Lee S, Kim MS, Ogale AA (2007) J Appl Polym Sci 106:2605–2614CrossRefGoogle Scholar
  36. 36.
    Kim J, Hong SM, Kwak S, Seo Y (2009) Phys Chem Chem Phys 11:10851–10859CrossRefGoogle Scholar
  37. 37.
    Toti A, Giambastiani G, Bianchini C, Meli A, Bredeau S, Dubois P, Bonduel D, Claes M (2008) Chem Mater 20:3092–3098CrossRefGoogle Scholar
  38. 38.
    Li L, Li CY, Ni C (2006) J Am Chem Soc 128:1692–1699CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media B.V. 2012

Authors and Affiliations

  • Bijal Kottukkal Bahuleyan
    • 1
  • Muataz Ali Atieh
    • 1
  • Sadhan Kumar De
    • 1
  • Masihullah Jabarulla Khan
    • 1
  • Mamdouh A. Al-Harthi
    • 1
    • 2
  1. 1.Department of Chemical EngineeringKing Fahd University of Petroleum and MineralsDhahranSaudi Arabia
  2. 2.Center of Research Excellence in NanotechnologyKing Fahd University of Petroleum and MineralsDhahranSaudi Arabia

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