Journal of Polymer Research

, Volume 18, Issue 4, pp 477–482

Fluorescent poly(p-phenylene vinylene)/poly(ethylene oxide) nanofibers obtained by electrospinning

  • Yi Xin
  • Zonghao Huang
  • Zijiang Jiang
  • Liguang Che
  • Man Sun
  • Cheng Wang
  • Sidong Liu
Original Paper

Abstract

Poly(p-phenylene vinylene) (PPV)/poly(ethylene oxide) (PEO) hybrid nanofibers were prepared by electrospinning a composite solution of PPV precursor/PEO in a mixture of ethanol and water, followed by thermal conversion. The precursor/PEO composite solutions were successfully electrospun into nanofibers with diverse helical, helical and linear, and helical bead-on-string morphologies by controlling the amount of aqueous PEO solution in a composite solution. Moreover, adding aqueous PEO solution to a precursor ethanol solution decreased the diameters of the fibers. The experimental data suggest that the viscosity, conductivity, and surface tension of the electrospinning solution are the main factors that influence the morphology of the fibers. Fourier transform infrared (FT-IR) and X-ray diffraction (XRD) investigations indicated that the PPV precursor reacts with PEO during thermal conversion. Ultraviolet–visible (UV-vis) and photoluminescence (PL) spectra of the PPV-PEO nanofibers exhibited appreciable blue shifts with the addition of PEO, which made it possible to fabricate nanofibers with fluorescence ranging from yellow-green to blue. These highly fluorescent PPV/PEO nanofibers with various morphologies are potentially interesting for many applications, such as micro- and nanooptoelectronic devices and systems.

Keywords

Electrospinning Nanofibers Semiconductors Poly(p-phenylene vinylene) (PPV) 

References

  1. 1.
    Zhao WJ, Ma L, Lu K (2007) J Poly Res 14:1–4CrossRefGoogle Scholar
  2. 2.
    Huang ZM, Zhang YZ, Kotaki M, Ramakrishna S (2003) Comp Sci Technol 63:2223–2253CrossRefGoogle Scholar
  3. 3.
    Li D, Xia Y (2004) Adv Mater 16:1151–1170CrossRefGoogle Scholar
  4. 4.
    Greiner A, Wendorff JH (2007) Angew Chem Int Ed 46:5670–5703CrossRefGoogle Scholar
  5. 5.
    Tomczak N, van Hulst NF, Vancso GJ (2005) Macromolecules 38:7863–7866CrossRefGoogle Scholar
  6. 6.
    Kessick R, Tepper G (2004) Appl Phys Lett 84:4807–4809CrossRefGoogle Scholar
  7. 7.
    Burroughes JH, Bradley DDC, Brown AR, Marks RN, Mackay K, Friend RH, Burns PL, Holmes AB (1990) Nature 347:539–7541CrossRefGoogle Scholar
  8. 8.
    Tang AW, Teng F, Jin H, Gao YH, Hou YB, Liang CJ, Wang YS (2007) Mater Lett 61:2178–2181CrossRefGoogle Scholar
  9. 9.
    Parad PE, Williams DJ (1991) Introduction to nonlinear optical effects in molecules and polymers. Wiley, New YorkGoogle Scholar
  10. 10.
    Roger JA, Bao Z, Dhar L (1998) Appl Phys Lett 73:294–296CrossRefGoogle Scholar
  11. 11.
    Zong X, Kim K, Shaofeng R, Hsiao BS, Chu B (2002) Polmer 43:4403–4412CrossRefGoogle Scholar
  12. 12.
    Fong H, Chun I, Reneker DH (1999) Polymer 40:4585–4592CrossRefGoogle Scholar
  13. 13.
    Baraton MI, Merhari L, Wang JZ, Gonsalves KE (1998) Nanotechnology 9:356–359CrossRefGoogle Scholar
  14. 14.
    Seoul C, Kang JI, Mah SI, Lee CH (1999) Synthetic Met 99:35–43CrossRefGoogle Scholar
  15. 15.
    Bjorklund TG, Lim S-H, Bardeen CJ (2004) Synthetic Met 142:195–200CrossRefGoogle Scholar
  16. 16.
    Gagnon DR, Capistran JD, Karasz FE (1987) Polymer 28:567–573CrossRefGoogle Scholar
  17. 17.
    Peeters E, Ramos AM, Mesker SCJ, Janssen RAJ (2000) J Chem Phys 112:9445–9454CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media B.V. 2010

Authors and Affiliations

  • Yi Xin
    • 1
  • Zonghao Huang
    • 1
  • Zijiang Jiang
    • 2
  • Liguang Che
    • 1
  • Man Sun
    • 1
  • Cheng Wang
    • 3
  • Sidong Liu
    • 1
  1. 1.Department of ChemistryNortheast Normal UniversityChangchunPeople’s Republic of China
  2. 2.Changchun Institute of Applied ChemistryChinese Academy of SciencesChangchunPeople’s Republic of China
  3. 3.Department of Chemistry and Materials ScienceHeilongjiang UniversityHarbinPeople’s Republic of China

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