Journal of Polymer Research

, Volume 17, Issue 4, pp 481–488 | Cite as

Synthesis and characterization of novel ion-exchange resin based on polyimide containing 8-hydroxyquinoline as a pendent groups

  • Bharat Chandrashekhar Dixit
  • Ritu B. Dixit
  • Dhirubhai J. Desai
Original Paper
First Online:
Received:
Accepted:

Abstract

Novel ion-exchange resin (PBMDDMCMHQ polyimide) having 8-hydroxyuinoline as a pendent groups was prepared using phenylenebismaleimide-diamine polyimide (PBMDDM) and 5-chloromethyl-8-hydroxyquinoline hydrochloride (CMHQ). Phenylenebismaleimide-diamine polyimide (PBMDDM) was prepared by Michael addition reaction of 1,3-phenylenebismaleimide (PBM) and 4,4’-diaminodiphenyl methane (DDM). The resulting ion-exchange resin was characterized by spectral techniques. Polymeric metal chelates of ion-exchange resin were also prepared using transition metal ions Zn(II), Cu(II), Ni(II), Co(II) and Mn(II), and were duly characterized. Ion-exchange properties of ion-exchange resin (PBMDDMCMHQ) for Fe(III), Zn(II), Ni(II) and Cu(II) metal ions were also studied by batch-equilibration method. The produced ion-exchange resin (PBMDDMCMHQ) has thermal stability up to 220°C and can be used over a wide pH range. It has good metal up take capacity at varying pH range and can be recycled.

Keywords

1,3-phenylenebismaleimide-diamine polyimide Ion-exchange resin Thermogravimetric analysis Polymeric chelates Batch-equilibration method 
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Notes

Acknowledgement

The author is thankful to University Grants Commission, Pune, for providing the financial assistance. The authors are also thankful to Principal Dr. D. J. Desai, V. P. & R. P. T. P. Science College, Vallabh Vidyanagar for providing the necessary research facilities.

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Copyright information

© Springer Science+Business Media B.V. 2009

Authors and Affiliations

  • Bharat Chandrashekhar Dixit
    • 1
  • Ritu B. Dixit
    • 2
  • Dhirubhai J. Desai
    • 1
  1. 1.Chemistry DepartmentV. P. & R. P. T. P. Science CollegeVallabh VidyanagarIndia
  2. 2.Ashok & Rita Patel Institute of Integrated Study & Research in Biotechnology and Allied SciencesNew Vallabh VidyanagarIndia

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