Journal of Polymer Research

, 16:755 | Cite as

Polymer-metal complexes of phenolic resin with Ln (III): thermal, catalytic and antimicrobial aspects

Article
First Online:
Received:
Accepted:

Abstract

The polycondensation of 2-hydroxy-4-ethoxybenzophenone with 1, 3 butane diol was carried out in presence of polyphosphoric acid as a catalyst at 155 °C for 10 h to synthesize desired resin. The resin was used to synthesize polymer-metal complexes with 4f-block elements. The resin and its polymer-metal complexes were characterized on the basis of elemental analyses, electronic spectra, magnetic susceptibilities, FTIR, NMR and Thermogravimetric analyses. Morphology of resin and its polymer-metal complexes was studied by SEM. Catalytic activity of selected polymer-metal complexes in organic synthesis was examined. Antimicrobial activity of polymer-metal complexes against Escherichia coli, Bacillus subtilis, Staphylococcus aureus (bacteria) and Saccharomyces cerevisiae (yeast) were measured. It is observed that polymer-metal complexes are efficient and effective catalysts and antimicrobial agents.

Keywords

Polymer-metal complexes Thermal study Catalysts Antimicrobial study 
This is a preview of subscription content, log in to check access.

Notes

Acknowledgement

The authors thank the Heads of the, Department of Chemistry and Bioscience, Sardar Patel University, Vallabh Vidyanagar, for providing laboratory facilities. One of the authors (MMP) is thankful to UGC, New Delhi, for the award of a research fellowship for meritorious students (RFSMS).

References

  1. 1.
    Carlucci L, Ciani G, Proserpio DM (2003) Coord Chem Rev 246(1–2):247. doi: 10.1016/S0010-8545(03)00126-7 CrossRefGoogle Scholar
  2. 2.
    Manners I (1999) Pure Appl Chem 71(8):1471. doi: 10.1351/pac199971081471 CrossRefGoogle Scholar
  3. 3.
    Manners I (2002) J Polym Sci Part Polym Chem 40(2):179. doi: 10.1002/pola.10069 CrossRefGoogle Scholar
  4. 4.
    Cyr PW, Tzolov M, Manners I, Sargent EH (2003) Macromol Chem Phys 204(7):915. doi: 10.1002/macp.200390061 CrossRefGoogle Scholar
  5. 5.
    Kaya I, Cihangiroglu N (2004) J Polym Res 11:37. doi: 10.1023/B:JPOL.0000021746.50347.34 CrossRefGoogle Scholar
  6. 6.
    Nair VA, Mustafa SM, Krishnapillai S (2003) J Polym Res 10:267. doi: 10.1023/B:JPOL.0000004629.53837.b3 CrossRefGoogle Scholar
  7. 7.
    Eddaoudi M, Li H, Yaghi OM (2000) J Am Chem Soc 122(7):1391. doi: 10.1021/ja9933386 CrossRefGoogle Scholar
  8. 8.
    Guo X, Chen M, Tianhong Lu T, Huang X (2008) J Polym Res 15:141. doi: 10.1007/s10965-007-9153-3 CrossRefGoogle Scholar
  9. 9.
    Parac-Vogt TN, Binnemans K (2004) Tetrahedron Lett 45(15):3137. doi: 10.1016/j.tetlet.2004.02.084 CrossRefGoogle Scholar
  10. 10.
    Gaona-Tiburcio C, Almeraya-Caldero’n F, Chacon-Nava JG, Matutes-Aquino JA, Martinez-Villafan’e A (2004) J Alloy Comp 369(1–2):78. doi: 10.1016/j.jallcom.2003.09.050 CrossRefGoogle Scholar
  11. 11.
    Cao RD, Sun F, Liang YC Y, Hong MC, Tatsumi K, Shi Q (2002) Inorg Chem 41:2087. doi: 10.1021/ic0110124 CrossRefGoogle Scholar
  12. 12.
    Lin HM, Qing CX, Qian M, Ping XH (2005) Russ J Coord Chem 31(5):368. doi: 10.1007/s11173-005-0106-2 CrossRefGoogle Scholar
  13. 13.
    Evans CH (1992) Biochemistry of the Lanthanides, vol 8. Plenum press, New York and LondonGoogle Scholar
  14. 14.
    Shah TB, Patel HS, Dixit RB (2001) Int J Polymeric Mater 49(3):271. doi: 10.1080/00914030108039779 CrossRefGoogle Scholar
  15. 15.
    Patel MM, Kapadia MA, Patel GP, Joshi JD (2007) J Appl Polym Sci 106(2):1307. doi: 10.1002/app.26711 CrossRefGoogle Scholar
  16. 16.
    Stanier RY (1986) Introduction to the Microbial World, 5th edn. Prentice Hall Inc, NJ, p 16Google Scholar
  17. 17.
    Vogel AI (1978) A Text Book of Quantitative Inorganic Analysis, 4th edn. Longmans Green and Co. Ltd., LondonGoogle Scholar
  18. 18.
    Dwivedi DK, Shukla RK, Shukla BK (1991) Acta Cienc Indica Chem 17c (14): 383, Chem Abstr 117:14241n, (1992)Google Scholar
  19. 19.
    Ursu M, Frey H, Neuner I, Thomann R, Rusu M (2004) Rep Romanian Phys 56(3):445Google Scholar
  20. 20.
    Ahamad T, Kumar V, Nishat N (2006) Polym Int 55(12):1398. doi: 10.1002/pi.1999 CrossRefGoogle Scholar
  21. 21.
    Nikolaev AV, Logvinenko VA, Myachina LT (1969) Thermal Analysis. Academic Press, New York, p 79Google Scholar
  22. 22.
    Pittman CW Jr, Voes RL, Elder J (1971) Macromolecules 5:302. doi: 10.1021/ma60021a008 CrossRefGoogle Scholar
  23. 23.
    Upadhyaya HD, Patel PP, Patel MM (1990) Synth React Inorg Met-Org Chem 20:1153. doi: 10.1080/00945719008048625 CrossRefGoogle Scholar
  24. 24.
    Patel MM, Kapadia MA, Patel GP, Joshi JD (2007) J Appl Polym Sci 106(2):1307. doi: 10.1002/app.26711 CrossRefGoogle Scholar
  25. 25.
    Shah BA, Shah AV, Shah PM (2006) Iran. Polym J 15(10):809Google Scholar
  26. 26.
    Samal S, Das RR, Dey RK, Acharya S (2000) J Appl Polym Sci 77(5):967. doi: 10.1002/1097-4628(20000801)77:5<967::AID-APP3>3.0.CO;2-5 CrossRefGoogle Scholar
  27. 27.
    Gudasi KB, Havanur VC, Patil SA, Patil BR (2007) Metal-Based Drugs . doi: 10.1155/2007/37348 Google Scholar
  28. 28.
    Kappe CO (2000) Eur J Med Chem 35:1043. doi: 10.1016/S0223-5234(00)01189-2 CrossRefGoogle Scholar
  29. 29.
    Overman LE, Rabiniwitz MH, Renhowe PA (1995) J Am Chem Soc 117(9):2657. doi: 10.1021/ja00114a034 CrossRefGoogle Scholar
  30. 30.
    Partha P, Baruah PP, Gadhwal S, Prajapati D, Sandhu JS (2002) Chem Lett 31(10):1038Google Scholar
  31. 31.
    Sabita G, Reddy KK, Reddy KB, Yadav JS (2003) Tetrahedron Lett 44(34):6497. doi: 10.1016/S0040-4039(03)01564-8 CrossRefGoogle Scholar
  32. 32.
    Paraskar AS, Dewkar GK, Sudalai A (2003) Tetrahedron Lett 44(16):3305. doi: 10.1016/S0040-4039(03)00619-1 CrossRefGoogle Scholar
  33. 33.
    Nishat N, Ahmad S, Ahamad RT (2006) J Appl Polym Sci 100(2):928. doi: 10.1002/app.23064 CrossRefGoogle Scholar
  34. 34.
    Nishat N, Ahmad S, Ahamad RT (2006) J Appl Polym Sci 101(3):1347. doi: 10.1002/app.23036 CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media B.V. 2009

Authors and Affiliations

  1. 1.Department of ChemistrySardar Patel UniversityVallabh VidyanagarIndia

Personalised recommendations