Journal of Polymer Research

, Volume 15, Issue 5, pp 397–402 | Cite as

Synthesis and characterization of nanostructured PZT encapsulated PVA–PAA hydrogel

Short Communication

Abstract

Hydrogel/PZT composite was prepared by encapsulating, Pb(Zr0.52Ti0.48)O3 (PZT) nanoparticles in an electroactive (PVA–PAA) hydrogel. The XRD studies confirmed the presence of pure tetragonal phase in PZT with crystallite size of 13 nm in the composite matrix. PZT nanoparticles were found to be embedded in the micro pores of PVA–PAA hydrogel as indicated by the SEM images. The composite shows three step degradation process in the TG/DTA measurements. Dielectric properties were studied from room temperature to 120 °C within wide frequency range of 100 Hz–600 kHz. At room temperature and intermediate frequency range, the composite shows a high dielectric constant of ~225 to 600 and low dielectric loss of 0.08.

Keywords

PZT Hydrogel Composite Dielectric PVA PAA 

Notes

Acknowledgements

One of the authors (PKP) sincerely acknowledge to Department of Science and Technology (DST), New Delhi for the financial support under SERC, FAST TRACK Scheme. We are thankful to Prof K Shahi, Dept of Mater Sc Eng, IIT Kanpur for the infrastructural facility to dielectric measurements.

References

  1. 1.
    Yong-Qiu Z, Guang HY, Chang TQ (1983) Ferroelectrics 39:241Google Scholar
  2. 2.
    Shrout TR, Schulze WA, Biggers JV (1979) Mater Res Bull 14:1553CrossRefGoogle Scholar
  3. 3.
    Dong L, Xiong C, Quan H, Zhao G (2006) Scr Mater 55:835CrossRefGoogle Scholar
  4. 4.
    Gebhardta S, Scho Neckera A, Steinhausenb R, Seifertb W, Beigeb H (2003) J Eur Ceram Soc 23:153CrossRefGoogle Scholar
  5. 5.
    Ting RY (1983) Ferroelectrics 49:251Google Scholar
  6. 6.
    Das-Gupta DK, Abdulla MJ (1988) J Mater Sci Lett 7:167CrossRefGoogle Scholar
  7. 7.
    Popielarz R, Chiang CK, Nozaki R, Obrzut J (2001) Macromolecules 34:5910CrossRefGoogle Scholar
  8. 8.
    Yang T, Kofinas P (2007) Polymer 48:791CrossRefGoogle Scholar
  9. 9.
    Sinha D, Pillai PKC (1989) J Mater Sci Lett 8:673CrossRefGoogle Scholar
  10. 10.
    Nayak S, Lyon LA (2005) Angew Chem 44:7686CrossRefGoogle Scholar
  11. 11.
    Osada Y, Gong JP (1998) Adv Mater 10:827CrossRefGoogle Scholar
  12. 12.
    Vanderah TA (2002) Science 298:1182CrossRefGoogle Scholar
  13. 13.
    Zhang QM, Li H, Poh M, Xu H, Cheng ZY, Xia F (2002) Nature 419:284CrossRefGoogle Scholar
  14. 14.
    Gajbhiye NS, Pandey PK, George L, Kumar A (2007) J Nanosci Nanotechnol 7:1975CrossRefGoogle Scholar
  15. 15.
    Gajbhiye NS, Pandey PK, George L, Kumar A (2006) Solid State Phys 50:267Google Scholar
  16. 16.
    Jianqi F, Lixia G (2002) Eur Polymer J 38:1653CrossRefGoogle Scholar
  17. 17.
    Kim SJ, Kim HI, Park SJ, Kim IY, Lee SH, Lee TS, Kim SI (2005) Smart Mater Struct 14:511CrossRefGoogle Scholar
  18. 18.
    Nobert MB (ed) (1971) Encyclopedia of polymer science and technology, vol. 14. Wiley, New York, p 149 (Chap. 5)Google Scholar
  19. 19.
    Nakanishi K, Solomon PH (1977) Infrared Absorption Spectroscopy. Holden-Day, San FransciscoGoogle Scholar
  20. 20.
    Arndt KF, Richter A, Ludwig S, Zimmermann J, Kressler J, Kuckling D, Adler HJ (1999) Acta Polym 50:383CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media B.V. 2008

Authors and Affiliations

  1. 1.Department of ChemistryIndian Institute of Technology KanpurKanpurINDIA

Personalised recommendations