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Journal of Polymer Research

, Volume 13, Issue 6, pp 495–506 | Cite as

Organosoluble, Low-Colored Fluorinated Polyimides Based on 1,1-Bis[4-(4-amino-2-trifluoromethylphenoxy)phenyl]-1-phenyl-2,2,2-trifluoroethane

  • Cheng-Lin Chung
  • Tuan-Wen Tzu
  • Sheng-Huei Hsiao
Article

Abstract

A novel trifluoromethyl-substituted bis(ether amine) monomer, 1,1-bis[4-(4-amino-2-trifluoromethylphenoxy)phenyl]-1-phenyl-2,2,2-trifluoroethane, was synthesized that led to a series of novel fluorinated polyimides via chemical imidization route when reacted with various commercially available aromatic tetracarboxylic dianhydrides. These polyimides were highly soluble in a variety of organic solvents such as N-methyl-2-pyrrolidone and N,N -dimethylacetamide, and most of them could afford transparent, low-colored, and tough films. These polyimides exhibited glass-transition temperatures (T gs) of 227–269 °C and showed no significant decomposition below 500 °C under either nitrogen or air atmosphere. These polyimides had low dielectric constants of 2.87–3.17 at 10 kHz, low water uptake of 0.13%–0.58%, and an ultraviolet-visible absorption cutoff wavelength at 364–410 nm. For a comparative study, a series of analogous polyimides based on 1,1-bis[4-(4-aminophenoxy)phenyl]-1-phenyl-2,2,2-trifluoroethane were also prepared and characterized.

Key words

fluorinated polyimides low color dielectric property 

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Copyright information

© Springer 2006

Authors and Affiliations

  • Cheng-Lin Chung
    • 1
  • Tuan-Wen Tzu
    • 1
  • Sheng-Huei Hsiao
    • 1
  1. 1.Department of Chemical EngineeringTatung UniversityTaipeiRepublic of China

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