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Journal of Solution Chemistry

, Volume 48, Issue 10, pp 1337–1356 | Cite as

Study of Intermolecular Interactions in Binary Mixtures of 2-Methoxyaniline with Chlorinated Ethanes at Various Temperatures

  • B. Mukesh
  • T. SreekanthEmail author
  • M. Gowrisankar
  • M. Raveendra
Article
  • 39 Downloads

Abstract

Densities (ρ), speeds of sound (u), and viscosities (η) are reported for binary mixtures of 2-methoxyaniline with chlorinated ethane components (1,2-dichloroethane, 1,1,2-trichloroethane and 1,1,2,2-tetrachloroethane) over the entire composition range of mole fraction at T = (303.15–313.15) K and at atmospheric pressure (0.1 MPa). The excess properties: excess molar volume, excess isentropic compressibility and deviation in viscosity are calculated from the experimental density, speed of sound and viscosity. Excess properties are correlated using the Redlich–Kister polynomial equation. The excess partial molar volumes and excess partial molar isentropic compressibilities are calculated for all the binary systems throughout the composition range and at infinite dilutions. The results are analyzed in terms of electron donor–acceptor interactions leading to the formation of intermolecular complexes and hydrogen bonding between 2-methoxyaniline and chlorinated ethane molecules. The VE results are analyzed in light of the Prigogine–Flory–Patterson theory. Analysis of each of the three contributions viz. interactional, free volume and P* to VE has shown that the interactional contribution are positive for all studied systems, the free volume and P* contributions are negative for all the binary mixtures.

Keywords

Density Speed of sound Viscosity 2-Methoxyaniline Chlorinated ethane molecules PFP theory 

Notes

Acknowledgements

The authors are thankful to M/s. Anton Paar, Hyderabad for providing the research facilities and the Managements of Vignan Institute of Technology & Science, Hyderabad and J.K.C College, Guntur for their encouragement towards the research work.

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Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2019

Authors and Affiliations

  • B. Mukesh
    • 1
  • T. Sreekanth
    • 2
    Email author
  • M. Gowrisankar
    • 3
  • M. Raveendra
    • 4
  1. 1.Department of PhysicsVignan Institute of Technology and ScienceDeshmukhiIndia
  2. 2.Department of PhysicsJ.N.T.U.H-College of EngineeringMedakIndia
  3. 3.Department of ChemistryJ.K.C.C. Acharya Nagarjuna UniversityGunturIndia
  4. 4.Department of ChemistryRajiv Gandhi University of Knowledge Technologies, Dr. APJ Abdul Kalam, IIITOngoleIndia

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