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Journal of Solution Chemistry

, Volume 41, Issue 1, pp 53–74 | Cite as

Excess Molar Volumes, Excess Viscosities and Ultrasonic Speeds of Sound of Binary Mixtures of 1,2-Dimethoxyethane with Some Aromatic Liquids at 298.15 K

  • Bipul Kumar Sarkar
  • Ankan Choudhury
  • Biswajit Sinha
Article

Abstract

Densities, viscosities and ultrasonic speeds of sound for binary mixtures of 1,2-dimethoxyethane (DME) with benzene, toluene, chlorobenzene, benzyl chloride, benzaldehyde, nitrobenzene, and aniline are reported over the entire composition range at ambient pressure and temperature (i.e., T=298.15 K and p=1.01×105 Pa). These experimental data were utilized to derive the excess molar volumes (\(V_{\mathrm{m}}^{\mathrm{E}}\)), excess viscosities (η E), and various acoustic parameters including the deviation in isentropic compressibility (Δκ S ), internal pressure (π I), and excess enthalpy (H E). From the excess molar volumes (\(V_{\mathrm{m}}^{\mathrm{E}}\)), the excess partial molar volumes (\(\overline{V}_{\mathrm{m},1}^{\mathrm{E}}\) and \(\overline{V}_{\mathrm{m},2}^{\mathrm{E}}\)) and excess partial molar volumes at infinite dilution (\(\overline{V}_{\mathrm{m},1}^{0,\mathrm{E}}\) and \(\overline{V}_{\mathrm{m},2}^{0,\mathrm{E}}\)) were derived and discussed for each liquid component in the mixtures. The excess/deviation properties were found to be either negative or positive, depending on the molecular interactions and the nature of the liquid mixtures.

Keywords

Excess molar volumes Excess viscosities Acoustic parameters 1,2-Dimethoxyethane Aromatic liquids 

Notes

Acknowledgements

The authors are grateful to the Departmental Special Assistance Scheme under the University Grants Commission, New Delhi (No. F 540/27/DRS/2007, SAP-1) for financial support.

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Copyright information

© Springer Science+Business Media, LLC 2011

Authors and Affiliations

  • Bipul Kumar Sarkar
    • 1
  • Ankan Choudhury
    • 1
  • Biswajit Sinha
    • 1
  1. 1.Department of ChemistryUniversity of North BengalDarjeelingIndia

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