Journal of Solution Chemistry

, Volume 39, Issue 5, pp 701–708

Dielectric Constants of Water, Methanol, Ethanol, Butanol and Acetone: Measurement and Computational Study



The dielectric constants (relative permittivities) of water, methanol, ethanol, butanol and acetone were measured at 91.3 kPa and (283.15 and 293.15) K and are reported here. The dielectric constants were determined by using a new setup based on a low-pass filter. The obtained dielectric constant values are compared with those reported in the literature, and are consistent with those reported in the literature. The obtained dielectric constant data were also compared with those calculated by the Kirkwood model. The comparisons indicated that Kirkwood model can be successfully used for calculation of dielectric constants of the pure fluids.


Dielectric constant Low-pass-filter Capacitor Kirkwood model 


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  1. 1.
    Jennings, S.G.: A method of measurement of the dielectric constant of some liquids. Phys. Educ. 12, 40–42 (1977) CrossRefGoogle Scholar
  2. 2.
    Fernandez, D.P., Goodwin, A.R.H., Levelt Sengers, J.M.H.: Measurements of the relative permittivity of liquid water at frequencies in the range of 0.1 to 10 kHz and at temperatures between 273.1 and 373.2 K at ambient. Int. J. Thermophys. 16, 929–955 (1995) CrossRefGoogle Scholar
  3. 3.
    Goodwin, R.H., Mehl, J.B., Moldover, M.R.: Reentrant radio-frequency resonator for automated phase-equilibria and dielectric measurements in fluids. Rev. Sci. Instrum. 67, 4294–4298 (1996) CrossRefGoogle Scholar
  4. 4.
    Kaatze, U.: The dielectric properties of water in its different states of interaction. J. Solution Chem. 26, 1049–1112 (1997) CrossRefGoogle Scholar
  5. 5.
    Anderson, G.S., Miler, R.C., Goodwin, R.H.: Static dielectric constants for liquid water from 300 K to 350 K at pressure to MPa using a new radio-frequency resonator. J. Chem. Eng. Data 45, 549–554 (2000) CrossRefGoogle Scholar
  6. 6.
    Buckley, F., Maryott, A.A.: Tables of dielectric dispersion data for pure liquids and dilute solutions. NBS Circular No. 589, National Bureau of Standards, Washington, DC (1958) Google Scholar
  7. 7.
    Dunn, L.A., Stokes, R.H.: Pressure and temperature dependence of the electrical permittivities of formamide and water. Trans. Faraday Soc. 65, 2906–2912 (1996) CrossRefGoogle Scholar
  8. 8.
    Åkerlöf, G.: Dielectric constants of some organic solvent-water mixtures at various temperatures. J. Am. Chem. Soc. 54, 4125–4139 (1932) CrossRefGoogle Scholar
  9. 9.
    Archer, D.G., Wang, P.: The dielectric constant of water and Debye–Hückel limiting law slopes. J. Phys. Chem. Ref. Data 19, 371–411 (1990) CrossRefGoogle Scholar
  10. 10.
    Owen, B.B., Miller, R.C., Milner, C.E., Cogan, H.L.: The dielectric constant of water as a function of temperature and pressure. J. Phys. Chem. 65, 2065–2070 (1961) CrossRefGoogle Scholar
  11. 11.
    Dannhauser, W., Bahe, L.W.: Dielectric constant of hydrogen bonded liquids. III. Superheated alcohols. J. Chem. Phys. 40, 3058–3066 (1964) CrossRefGoogle Scholar
  12. 12.
    Floriano, W.B., Nascimento, M.A.C.: Dielectric constant and density of water as a function of pressure at constant temperature. Braz. J. Phys. 34, 38–41 (2004) CrossRefGoogle Scholar
  13. 13.
    Hamelin, J., Mehl, J.B., Moldover, M.R.: The static dielectric constant of liquid water between 274 and 418 K near the saturated vapor pressure. Int. J. Thermophys. 19, 1359–1380 (1998) CrossRefGoogle Scholar
  14. 14.
    Hamelin, J., Mehl, J.B., Moldover, M.R.: Resonators for accurate dielectric measurements in conducting liquids. Rev. Sci. Instrum. 69, 255–260 (1998) CrossRefGoogle Scholar
  15. 15.
    Marcus, Y., Hefter, G.: On the pressure and electric field dependencies of the relative permittivity of liquids. J. Solution Chem. 28, 575–592 (1999) CrossRefGoogle Scholar
  16. 16.
    Sivasubramanian, S., Widom, A., Srivastava, Y.N.: The Clausius–Mossotti phase transition in polar liquids. Physica A 345, 356–366 (2005) CrossRefGoogle Scholar
  17. 17.
    Wang, P., Anderko, A.: Computation of dielectric constants of solvent mixtures and electrolyte solutions. Fluid Phase Equil. 186, 103–122 (2001) CrossRefGoogle Scholar
  18. 18.
    Hasted, J.B., Ritson, D.M., Collie, C.H.: Dielectric properties of aqueous ionic solutions. Parts I and II. J. Chem. Phys. 16, 1–21 (1948) CrossRefGoogle Scholar
  19. 19.
    Akhadov, Y.Y.: Dielectric Properties of Binary Solutions. Pergamon, New York (1980) Google Scholar
  20. 20.
    Lowery, T.H., Richardson, K.S.: Mechanism and Theory in Organic Chemistry, 3d edn. Harper Collins Publishers, New York (1987) Google Scholar
  21. 21.
    Tanford, C.: The Hydrophobic Effect: Formation of Micelles and Biological Membranes, 2nd edn. Wiley, New York (1973) Google Scholar
  22. 22.
    Taylor, J.T., Huang, Q. (eds.): CRC Handbook of Electrical Filters. CRC Press, Boca Raton (1997) Google Scholar
  23. 23.
    Garland, C.W., Niber, J.W., Shomaker, D.: Experiment in Physical Chemistry, 7th edn. McGraw-Hill, Boston (2003) Google Scholar
  24. 24.
    Gregory, A.P., Clarke, R.N.: Traceable measurements of the static permittivity of dielectric reference liquids over the temperature range 5–50°C. Meas. Sci. Technol. 16, 1506–1516 (2005) CrossRefGoogle Scholar
  25. 25.
    Lide, D.R.: Handbook of Chemistry and Physics, 85th edn. CRC Press, Boca Raton (2004) Google Scholar

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© Springer Science+Business Media, LLC 2010

Authors and Affiliations

  1. 1.Thermodynamic Research LaboratoryUniversity of KashanKashanIran
  2. 2.Department of PhysicsUniversity of KashanKashanIran

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