Journal of Solution Chemistry

, Volume 34, Issue 12, pp 1371–1386 | Cite as

Thermodynamic Properties of Binary Mixtures of Cyclohexanone with n-Alkanols (C1–C5) at 293.15 K

  • Nikos G. Tsierkezos
  • Ioanna E. Molinou
  • Alexander C. Filippou
Article

Abstract

The excess molar volumes (VE), excess surface tensions (σE), and deviations in molar refraction (RE) and isentropic compressibility (ksE) of binary mixtures of cyclohexanone with methanol, ethanol, 1-propanol, 1-butanol, and 1-pentanol have been determined over the entire composition range at 293.15 K. The results were fitted by the Redlich–Kister polynomial equation and the corresponding binary coefficients Ak have been derived. The standard deviations between the calculated and the experimental excess properties have been determined. The results provide information on the interactions of the molecules in the pure liquids as well as in the binary mixtures.

Keywords

Cyclohexanone n-alkanols binary mixtures excess molar volume excess surface tension deviation in molar refraction deviation in isentropic compressibility 

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Copyright information

© Springer Science + Business Media, Inc. 2005

Authors and Affiliations

  • Nikos G. Tsierkezos
    • 1
  • Ioanna E. Molinou
    • 2
  • Alexander C. Filippou
    • 1
  1. 1.Institut für ChemieHumboldt-Universität zu BerlinBerlinGermany
  2. 2.Physical Chemistry Laboratory, Department of ChemistryUniversity of AthensPanepistimiopolisGreece

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