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Journal of Superconductivity and Novel Magnetism

, Volume 31, Issue 9, pp 2907–2914 | Cite as

Structural, Magnetic, and XPS Studies of the Double-Perovskite Mn2VSbO6

  • G. V. BazuevEmail author
  • A. P. Tyutyunnik
  • M. V. Kuznetsov
  • Yu. G. Zainulin
Original Paper
  • 343 Downloads

Abstract

The double-perovskite Mn2VSbO6 has been synthesized by solid-state reaction under pressure at 6 GPa and temperature of 1200°C, and its crystal structure has been refined by X-ray powder diffraction date. Mn2VSbO6 crystallizes in monoclinic space group P121/n1 with the following parameters: a =  5.2340 Å (2), b =  5.3932 Å (2), c =  7.6460 Å (3), β =  89.6075° (23), V =  215.826 Å3 (14), Z =  2. It found that V and Sb atoms are completely ordered in 2d and 2c positions of double-perovskite structure, respectively. According to XPS measurements, manganese in this compound is present as Mn2+, while vanadium is V3+. The magnetization date suggests that Mn2VSbO6 transforms to an antiferromagnetic state due to simultaneous ordering of V3+ and Mn2+ magnetic sublattices at low temperature.

Keywords

High pressure Crystal structure XPS Magnetic properties 

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Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2018

Authors and Affiliations

  • G. V. Bazuev
    • 1
    Email author
  • A. P. Tyutyunnik
    • 1
  • M. V. Kuznetsov
    • 1
  • Yu. G. Zainulin
    • 1
  1. 1.Institute of Solid State ChemistryUral Branch RASEkaterinburgRussia

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