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Journal of Structural Chemistry

, Volume 47, Issue 6, pp 1103–1110 | Cite as

Synthesis of [M(NH3)5Cl](ReO4)2 (M = Cr, Co, Ru, Rh, Ir) and investigation of thermolysis products. Crystal structure of [Rh(NH3)5Cl](ReO4)2

  • Yu. V. Shubin
  • E. Yu. Filatov
  • I. A. Baidina
  • K. V. Yusenko
  • A. V. Zadesenetz
  • S. V. Korenev
Article

Abstract

Complex salts [M(NH3)5Cl](ReO4)2, where M = Cr, Co, Ru, Rh, Ir, have been prepared. The crystal structure of [Rh(NH3)5Cl](ReO4)2 was determined by single crystal X-ray diffraction. Crystal data: a = 17.369(4) Å, b = 7.7990(16) Å, c = 11.218(2) Å, V = 1430.5(5) Å3, space group C2/m, Z = 4, d calc = 3.19 g/cm3, R = 0.0447. Complex salts from the above series are shown to be isostructural; they were defined by X-ray crystallography. Thermal decomposition of the compounds in an inert atmosphere and under hydrogen has been studied. According to X-ray phase analysis (XRPA) data, the M0.33Re0.67 (M = Co, Ru, Rh, Ir) monophase solid solutions are the products of reduction of the salts under hydrogen.

Keywords

chromium cobalt ruthenium rhodium rhenium chloropentaammine chlorocomplexes X-ray phase analysis X-ray analysis crystal chemistry 

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Copyright information

© Springer Science+Business Media, Inc. 2006

Authors and Affiliations

  • Yu. V. Shubin
    • 1
  • E. Yu. Filatov
    • 2
  • I. A. Baidina
    • 1
  • K. V. Yusenko
    • 1
  • A. V. Zadesenetz
    • 1
  • S. V. Korenev
    • 1
  1. 1.A. V. Nikolaev Institute of Inorganic ChemistryRussian Academy of Sciences, Siberian DivisionNovosibirsk
  2. 2.Novosibirsk State UniversityRussia

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