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Journal of Structural Chemistry

, Volume 47, Issue 4, pp 735–739 | Cite as

Re-determination of the crystal structure and investigation of thermal decomposition of the Chugaev’s salt, [Pt(NH3)5Cl]Cl3·H2O

  • K. V. Yusenko
  • A. V. Zadesenets
  • I. A. Baidina
  • Yu. V. Shubin
  • D. B. Vasil’chenko
  • S. V. Korenev
Article

Abstract

The crystal structure of the salt [Pt(NH3)5Cl]Cl3·H2O has been re-determined by single crystal X-ray diffraction and the salt has been studied by the thermal analysis. It is shown that one molecule of crystallization water enters into the salt composition. Intermediate products of thermal decomposition of the salt have been isolated and explored by IR spectroscopy and powder X-ray diffraction.

Keywords

Chugaev’s salt thermal analysis X-ray diffraction study 

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Copyright information

© Springer Science+Business Media, Inc. 2006

Authors and Affiliations

  • K. V. Yusenko
    • 1
  • A. V. Zadesenets
    • 1
  • I. A. Baidina
    • 1
  • Yu. V. Shubin
    • 1
  • D. B. Vasil’chenko
    • 2
  • S. V. Korenev
    • 1
  1. 1.A. V. Nikolaev Institute of Inorganic Chemistry, Siberian DivisionRussian Academy of SciencesNovosibirsk
  2. 2.Novosibirsk State UniversityNovosibirsk

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