Re-determination of the crystal structure and investigation of thermal decomposition of the Chugaev’s salt, [Pt(NH3)5Cl]Cl3·H2O
- 36 Downloads
The crystal structure of the salt [Pt(NH3)5Cl]Cl3·H2O has been re-determined by single crystal X-ray diffraction and the salt has been studied by the thermal analysis. It is shown that one molecule of crystallization water enters into the salt composition. Intermediate products of thermal decomposition of the salt have been isolated and explored by IR spectroscopy and powder X-ray diffraction.
KeywordsChugaev’s salt thermal analysis X-ray diffraction study
Unable to display preview. Download preview PDF.
- 1.I. I. Chernyaev (ed.), in: Preparation of Coordination Compounds of Platinum Group Metals [in Russian], Nauka, Moscow (1964).Google Scholar
- 2.G. B. Bokii and L. A. Popova, Izv. Sektora Platiny, Vyp. 25, 156–175 (1946).Google Scholar
- 3.Kh. I. Gindengershel, ibid, Vyp. 31, 47–52.Google Scholar
- 4.A. V. Nikolaev and A. M. Rubinstein, Izv. In-ta Platiny, Vyp. 21, 128–143 (1948).Google Scholar
- 6.G. M. Sheldrick, SHELX-97, Release 97-1, Univ. Göttingen, Germany (1997).Google Scholar
- 7.N. V. Podberezskaya, T. S. Yudanova, S. A. Magarill, et al., Zh. Strukt. Khim., 32, No. 6, 137–150 (1991).Google Scholar
- 8.L. K. Shubochkin, in: Chemistry of Platinum and Heavy Atoms, series “The problems of coordination chemistry” [in Russian], R. N. Schelokov (ed.), Nauka, Moscow (1975).Google Scholar
- 10.Powder Diffraction File. Alphabetical Index. Inorganic Phases, JCPDS, International Center for Diffraction Data, Pennsylvania (1983).Google Scholar