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Journal of Structural Chemistry

, Volume 47, Issue 1, pp 91–96 | Cite as

Synthesis and structure of trans-diaquabis(dimethylsulfoxide)bis(3,5-dinitrobenzoato)copper(II)

  • É. B. Miminoshvili
  • K. É. Miminoshvili
  • G. P. Adeishvili
Article

Abstract

Single crystal of [Cu(DMSO)2(3,5-DNB)2(OH2)2], where DMSO-dimethylsulfoxide, 3,5-DNB-3,5-dinitrobenzoate, has been synthesized and its crystal structure is determined. Crystals belong to monoclinic symmetry, space group is P21/n, Z = 2, a = 10.911(4) Å, b = 5.362(2) Å, c = 22.673(7) Å, β = 92.06(2)°, V = 1325.8(1) Å3, T = 293 K. Final value of R = 0.040 was obtained for 1804 independent reflections with I > 3σ(I). The structure is built from complex molecules.

Keywords

complex compounds synthesis structural analysis transition metals dimethylsulfoxide dinitrobenzoate 

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Copyright information

© Springer Science+Business Media, Inc. 2006

Authors and Affiliations

  • É. B. Miminoshvili
    • 1
  • K. É. Miminoshvili
    • 1
  • G. P. Adeishvili
    • 2
  1. 1.Georgian Technical UniversityTbilisi
  2. 2.Institute of Physical and Organic ChemistryGeorgian Academy of SciencesTbilisi

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