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A detailed investigation on rhenium loaded SBA-15 supported catalyst for hydrodenitrogenation reaction of cyclohexylamine

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Abstract

The present work is aiming to utilize Re based catalysts for hydrodenitrogenation (HDN) of cyclohexylamine over SBA-15 supported catalyst under optimized conditions. Siliceous SBA-15 was synthesized by hydrothermal method and used as a support for Re catalysts with different Re loadings (1, 3, 5 and 7 wt%). The supported catalysts were characterized by various physico-chemical techniques like XRD, N2-sorption studies, UV-DRS, FE-SEM, HR-TEM, NH3-TPD, Raman spectroscopy and XPS (sulfided catalyst). The oxide catalysts were presulfided before the hydrodenitrogenation reaction using ditertiary butyl polysulfide (DBPS) as sulfiding agent and hydrogen. The catalytic activity of the sulfided catalysts was tested for HDN of cyclohexylamine. A high HDN activity was observed on 5 wt% Re loaded SBA-15 catalyst. The catalytic activity was correlated with characterization results.

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References

  1. C.S. Raghuveer, J.W. Thybaut, R. De Bruycker, K. Metaxas, T. Bera, G.B. Marin, Fuel 125, 206 (2014)

    CAS  Google Scholar 

  2. S. Eijsbouts, V.H.J. De Beer, R. Prins, J. Catal. 127, 619 (1991)

    CAS  Google Scholar 

  3. O.V. Klimov, K.A. Nadeina, Y.V. Vatutina, E.A. Stolyarova, I.G. Danilova, E.Y. Gerasimov, I.P. Prosvirin, A.S. Noskov, Catal. Today 307, 73 (2018)

    CAS  Google Scholar 

  4. M.S. Rana, B.N. Srinivas, S.K. Maity, G. Murali Dhar, T.S.R. Prasad Rao, J. Catal. 195, 31 (2000)

    CAS  Google Scholar 

  5. D. Gulkova, Z. Vit, Appl. Catal. A. 125, 61 (1995)

    CAS  Google Scholar 

  6. P. Arnoldy, E.M. van Oers, V.H.J. de Beer, J.A. Moulijn, R. Prins, Appl. Catal. 48, 241 (1989)

    CAS  Google Scholar 

  7. J. Quartararo, S. Mignard, S. Kasztelan, J. Catal. 192, 307 (2007)

    Google Scholar 

  8. N. Escalona, M. Vrinat, D. Laurenti and F.J. Gil Llambias, Appl. Catal. A. 322,113 (2007)

  9. N. Escalona, J. Ojeda, R. Cid, G. Alvez, A. López Agudo, J.L.G. Fierro, F.J. Gil Llambıas, Appl. Catal. A 234, 45 (2002)

    CAS  Google Scholar 

  10. J. Ojeda, N. Escalona, J.L.G. Fierro, A. López Agudo, F.J. Gil-Llambías, Appl. Catal. A. 281, 25 (2005)

    CAS  Google Scholar 

  11. N. Escalona, M. Yates, P. Ávila, A. López Agudo, J.L. García Fierro, J. Ojeda, F.J. Gil Llambías, Appl. Catal. A. 240, 151 (2003)

    CAS  Google Scholar 

  12. C. Sepulveda, R. Garcia, P. Reyes, I.T. Ghampson, J.L.G. Fierro, D. Laurenti, M. Vrinat, N. Escalona, Appl. Catal. A. 475, 427 (2014)

    CAS  Google Scholar 

  13. D. Laurenti, K.T. Ninh Thi, N. Escalona, L. Massin, M. Vrinat, F.J. Gil Llambías, Catal Today 130, 55 (2008)

    Google Scholar 

  14. F.J. Gil Llambias, A. Lopez Agudo, V. Rives-Arnau, J Mater Sci. 17, 936 (1982)

    CAS  Google Scholar 

  15. H. Li, M. Li, H. Nie, Microporous Mesoporous Mater. 188, 30 (2014)

    CAS  Google Scholar 

  16. M. Breysse, P. Afanasiev, C. Geante, M. Vrina, Catal Today 86, 5 (2003)

    CAS  Google Scholar 

  17. F. Rota, R. Prins, J. Mol. Catal. A 162, 367 (2000)

    Google Scholar 

  18. A. Bunch, L. Zhang, G. Karakas, U.S. Ozkan, Appl. Catal A. 190, 51 (2000)

    CAS  Google Scholar 

  19. G. Deepa, T.M. Sankaranarayanan, K. Shanthi, B. Viswanathan, Catal. Today 198, 252 (2012)

    CAS  Google Scholar 

  20. V. Sundaramurthy, I. Eswaramoorthi, A.K. Dalai, J. Adjaye Microporous Mesoporous Mater. 11, 560 (2008)

    Google Scholar 

  21. U.T. Turaga, C. Song, Catal Today 86, 129 (2003)

    CAS  Google Scholar 

  22. J.M. Herrera, J. Reyes, P. Roquero, T. Klimova, Microporous Mesoporous Mater. 83, 283 (2005)

    CAS  Google Scholar 

  23. B.C. Ledesma, M.L. Martínez, A.R. Beltramone, Catal. Today. (2018). https://doi.org/10.1016/j.cattod.2018.04.061

    Article  Google Scholar 

  24. J. Ma, L.S. Qiang, J.F. Wang, X.B. Tang, D.Y. Tang, J. Porous Mater. 18, 607 (2011)

    CAS  Google Scholar 

  25. K. Amit, Y. Santosh, P.G. Smirniotis, N.G. Pinto, J. Chromatogr. A 1122, 13 (2006)

    Google Scholar 

  26. P.J. Kooyman, P. Waller, A.D. van Langeveld, C. Song, K.M. Reddy, J.A.R. van Veen, Catal. Lett. 90, 131 (2003)

  27. L. Ma, L. Jia, X. Guo, L. Xiang, Chin. J. Catal. 35, 108 (2014)

    CAS  Google Scholar 

  28. G.M. Dhar, G.M. Kumaran, M. Kumar, K.S. Rawat, L.D. Sharma, B.D. Raju, K.S. Rama Rao, Catal. Today 99, 309 (2005)

    CAS  Google Scholar 

  29. L. Lizama, M. Pérez, T. Klimova, Stud. Surf. Sci. Catal. 174, 1251 (2008)

    Google Scholar 

  30. D. Zhao, J. Feng, Q. Huo, N. Melosh, G.H. Fredrickson, B.F. Chmelka, G.D. Stucky, Science 279, 548 (1998)

    CAS  PubMed  Google Scholar 

  31. S.J. Sardhar Basha, N.R. Sasirekha, R. Maheswari, K. Shanthi, Appl. Catal. A 308, 91 (2006)

    CAS  Google Scholar 

  32. K. Sureshkumar, K. Shanthi, N.R. Sasirekha, J. Jegan, S.J. Sardhar Basha, Mater. Res. Exp. 5, 065516 (2018)

    Google Scholar 

  33. M.G. Cutrufello, E. Rombi, C. Cannas, M. Casu, A. Virga, S. Fiorilli, B. Onida, I. Ferino, J Mater Sci 44, 6644 (2009)

    CAS  Google Scholar 

  34. J.G. Pacheco-Sosa, A.I. Castillo-Escobedo, J.C. Chavarria-Hernandez, M.C. Díaz-Félix, H. Pérez-Vidal, L.C. Ordóñez, J. García-Dávila, J.C. Morales-Ortuño, B. Escobar, J. Porous Mater. 1–17 (2019)

  35. H.M. Salem, R.S. Mohamed, A.A. Alkahlawy, H.M. Gobara, A.E. Hassan, S.A. Hassan, J. Porous Mater. 26, 735 (2019)

    CAS  Google Scholar 

  36. X. Di, Z. Shao, C. Li, W. Li, C. Liang, Catal. Sci. Technol. 5, 2441 (2015)

    CAS  Google Scholar 

  37. R. Saad, J. Hawari, J. Porous Mater. 20, 227 (2013)

    CAS  Google Scholar 

  38. T. Tsoncheva, G. Issa, I. Genova, l. Dimitrov, J. Porous Mater. 20, 1361 (2013)

  39. V. Meynen, P. Cool, E.F. Vansant, Microporous Mesoporous Mater. 125, 170 (2009)

    CAS  Google Scholar 

  40. K. Leiva, R. Garcia, C. Sepulveda, D. Laurenti, C. Geantet, M. Vrinat, J.L. Garcia-Fierro, N. Escalona, Catal. Today 296, 228 (2017)

    CAS  Google Scholar 

  41. S.P. Lee, A. Ramli, Chem. Central J. 7, 149 (2013)

    Google Scholar 

  42. E.L. Lee, I.E. Wachs, J. Phys. Chem. C. 111, 14410 (2008)

    Google Scholar 

  43. C. Lin, K. Tao, H. Yu, D. Hua, S. Zhou, Catal. Sci. Technol. 4, 4010 (2014)

    CAS  Google Scholar 

  44. E.L. Lee, I.E. Wachs, J. Phys. Chem. C 122, 20418 (2008)

    Google Scholar 

  45. P.E. Ruiz, K. Leiva, R. Garcia, P. Reyes, J.L.G. Fierro, N. Escalona, Appl. Catal. A. 384, 7 (2010)

    Google Scholar 

  46. M. Riad, S. Mikhail, J. Energy Chem. 24, 520 (2015)

    Google Scholar 

Download references

Acknowledgement

The authors gratefully acknowledge the Department of Science and Technology, New Delhi, India for the financial support under Fast Track Scheme (SR/FT/CS-05/2011) for young scientists.

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Authors and Affiliations

  1. Department of Nanotechnology, Anna University Regional Campus, Coimbatore, Tamil Nadu, 641 046, India

    K. Sureshkumar & S. J. Sardhar Basha

  2. Department of Chemistry, Anna University, Chennai, Tamil Nadu, 600 025, India

    K. Shanthi

  3. Centre of Advanced Study in Crystallography and Biophysics, University of Madras, Chennai, Tamil Nadu, 600 025, India

    N. R. Sasirekha

  4. Department of Civil Engineering, Anna University, University College of Engineering, Ramanathapuram, Tamil Nadu, 623 513, India

    J. Jegan

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  1. K. Sureshkumar
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  2. K. Shanthi
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  5. S. J. Sardhar Basha
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Sureshkumar, K., Shanthi, K., Sasirekha, N.R. et al. A detailed investigation on rhenium loaded SBA-15 supported catalyst for hydrodenitrogenation reaction of cyclohexylamine. J Porous Mater 27, 83–93 (2020). https://doi.org/10.1007/s10934-019-00793-z

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