In this study, vinyl-functionalized porous silica (V-P-SiO2) and ureido-functionalized porous silica (UD-P-SiO2) have been synthesized separately by using hexadecyl trimethyl ammonium bromide (CTAB) and sodium dodecyl sulfonate (SDS) as mixed templates. The samples were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), Fourier transform infrared spectrum (FTIR) and N2 adsorption–desorption measurement. The results showed that UD-P-SiO2 with a diversity of morphologies were obtained by judiciously chosen mole ratio of SDS to CTAB (R = nSDS:nCTAB). On the contrast, the mole ratio of surfactants had less effect on the morphologies of V-P-SiO2 until the mole ratio of SDS to CTAB was reached 1.6, however, FTIR proved that it had effect on the vinyl groups in the V-P-SiO2 network framework.
This is a preview of subscription content, log in to check access.
Buy single article
Instant access to the full article PDF.
Price includes VAT for USA
Subscribe to journal
Immediate online access to all issues from 2019. Subscription will auto renew annually.
This is the net price. Taxes to be calculated in checkout.
J.S. Beck, J.C. Vartuli, W.G. Roth, M.E. Leonowicz, C.T. Kresge, K.D.D.K. Schmitt, C.T-W. Chu , D.H. Olson, E.W. Sheppard, S.B. McCullen, J.B. Higgins, J. L. Schlenker, J. Am. Chem. Soc., 114, 10834–10843, (1992)
C.T. Kresge, M.E. Leonowicz, W.G. Roth, J.C. Vartuli, J.S. Beck, Nature 359, 710–712 (1992)
X.F. Song, L. Gao, J. Phys. Chem. C 111, 8180–8187 (2007)
F.P. Dong, W.P. Guo, S.K. Park, C.S. Ha, Chem. Commun. 48, 1108–1110 (2012)
S. Duan, X. Zhang, S. Xu, C.L. Zhou, Electrochim. Acta 88, 885–891 (2013)
C.O. Areana, M.J. Vesgaa, J.B. Parrab, M.R. Delgado, Ceram. Int. 39, 7407–7414 (2013)
F. Hoffmann, M. Cornelius, J. Morell, M. FrÖba, Angew. Chem. Int. Ed. 45, 3216–3251 (2006)
F. Zhu, Y.J. Liang, L.Y. Xia, M.Z. Rong, C.Y. Su, R. Lai, R.Y. Li, G.F. Ouyang, J. Chromatogr. A 1247, 42–48 (2012)
E.M. Usai, M.F. Sini, D. Meloni, V. Solinas, A. Salis, Microporous Mesoporous Mater. 179, 54–62 (2013)
B.J. Dou, Q. Hu, J.J. Li, S.Z. Qiao, Z.P. Hao, J. Hazard. Mater. 186, 1615–1624 (2011)
R. Hashimoto, M. Ogawa, J. Porous Mater. 25, 425–431 (2018)
J.L. Li, B. Hu, J.J. Tan, J.Z. Zhuang, Transiti. Met. Chem. 38, 495–501 (2013)
D.S. Karaman, T. Gulin-Sarfraz, J.X. Zhang, J.M. Rosenholm, Mater. Lett. 143, 140–143 (2015)
L. Zhang, S.B. Wu, C. Li, Q.H. Yang, Chem. Commun. 48, 4190–4192 (2012)
Y. Yang, J. Liu, X.B. Li, X. Liu, Q.H. Yang, Chem. Mater. 23, 3676–3684 (2011)
Y.D. Xia, R.M. Oakaya, J. Phys. Chem. B, 110, 3889–3894, (2006)
K.J. Shea, D.A.O. St Websterl, J. Am. Chem. Soc., 110, 6700–6710, (1992)
X.Y. Wang, Q. Kang, D.Z. Shen, Z. Zhang, J.H. Li, L.X. Chen, Talanta, 124, 7–13, (2014)
T.S. Deng, F. Marlow, Chem. Mater. 24, 536–542 (2012)
J. Li, L.X. Chen, X. Li, C.C. Chao, F.L. Zeng, Appl. Surf. Sci., 340, 126–131, (2015)
R.L. Wang, Y.M. Zhu, X.M. Zhang, H.W. Ji, L. Li, H.Y. Ge, J. Colloid Interface Sci. 407, 128–132 (2013)
W.Q. Jiao, M.B. Yue, Y.M. Wang, M.Y. He, J. Porous Mater. 19, 61–70 (2012)
J.J. Wang, J.M. Lu, J.H. Yang, W. Xiao, J.Q. Wang, Mater Lett 78, 199–201 (2012)
Y.H. Ma, L. Xing, H.Q. Zheng, S.A. Che, Langmuir 27, 517–520 (2011)
M.T. Yatcilla, K.L. Herrington, L.L. Brasher, J. Phys. Chem. 100, 5874–5879 (1996)
E.W. Kaler, A.K. Murthy, B.E. Rodriguez, J.A. Zasadzinski, Science 22, 1371–1374 (1989)
I.I. Yaacob, A. Bose, J. Colloid Interface Sci. 178, 638–647 (1996)
J.C. Hao, H. Hoffmann, Curr. Opin. Colloid Interface Sci. 9, 279–293 (2004)
M.J. Rosen, X.Y. Hua, J. Am. Oil Chem. Soc. 59, 582–585 (1982)
H.T. Pu, X. Zhang, J.J. Yuan, Z.L. Yang 331, 389–393 (2009)
Q. Wei, H.Q. Chen, Z.R. Nie, Y.L. Wang, Q.Y. Li, J.X. Zou, Mater. Lett. 61, 1469–1473 (2007)
L.M. Wei, D.W. Shi, Z.H. Zhou, P.Y. Ye, J. Wang, J. Zhao, L.Y. Liu, C.X. Chen, Y.F. Zhang, Nanoscale Res. Lett. 7, 334–342 (2012)
J. Li, L.X. Chen, X. Li, C.C. Zhang, Y. Jiang, New J. Chem., 39, 287–294, (2015)
The authors gratefully acknowledge the support of this research by Natural Science Foundation of Hubei Province (CN) (Grant No. 2017CFB296) and Research Fund for Doctoral Program of Wu Chang Institute of Technology (CN) (Grant No. 2017BSJ04).
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
About this article
Cite this article
Li, J., zhang, J., Chen, L. et al. Binary cationic-anionic surfactant templated synthesis of organic functionalized porous silica nanomaterials. J Porous Mater 27, 29–35 (2020). https://doi.org/10.1007/s10934-019-00787-x
- Organic silica
- Porous nanomaterials
- Cationic-anionic surfactant