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Journal of Porous Materials

, Volume 26, Issue 6, pp 1573–1579 | Cite as

Stable fluorinated 3D isoreticular nanotubular triazole MOFs: synthesis, characterization and CO2 separation

  • Sha Chen
  • Da-Wei Wang
  • Su-Juan WangEmail author
  • Ji-Jun JiangEmail author
  • Cheng-Yong Su
Article
  • 111 Downloads

Abstract

Much of the efficient efforts have been largely devoted to enhancing the CO2 binding affinity in MOFs. In this paper, three isoreticular triazolate frameworks with the formula LIFM-1(TAZ).solvents, LIFM-1(MTAZ).solvents and LIFM-1(AmTAZ).solvents (TAZ = 1,2,4-triazole; MTAZ = 3-methyl-1H-1,2,4-triazole; AmTAZ = 3-amino-1H-1,2,4-triazole) have been prepared by using divalent zinc ions with the ligands of TAZ and its amino and methyl substituted derivatives for comparison of their sorption properties. High thermal stability and phase purity of the three MOFs were verified by thermogravimetric analysis and powder X-ray diffraction, respectively. Single component adsorption isotherms of N2, CO2 and H2 were also measured experimentally. Virial method shows that the porous frameworks of LIFM-1(AmTAZ) display high selectivity of CO2 over N2.

Keywords

Functionalized porous MOFs 3D isoreticular triazole MOFs CO2 separation 

Notes

Acknowledgements

This work was supported by NSFC (21821003, 21890380, 21890382, 21801252, 21720102007, 21771197), Local Innovative and Research Teams Project of Guangdong Pearl River Talents Program (2017BT01C161) and STP Project of Guangzhou (201607010378).

Compliance with ethical standards

Conflict of interest

The authors declare that they have no conflict of interest.

Supplementary material

10934_2019_755_MOESM1_ESM.docx (1.9 mb)
Supplementary material 1 (DOCX 1988 kb)

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Authors and Affiliations

  1. 1.MOE Laboratory of Bioinorganic and Synthetic Chemistry, Lehn Institute of Functional Materials, School of ChemistrySun Yat-Sen UniversityGuangzhouChina
  2. 2.Hunan Province Key Laboratory of Materials Surface and Interface Science and Technology, School of Materials Science and EngineeringCentral South University of Forestry and TechnologyChangshaChina

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