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Novel hierarchical HZSM-5 zeolites prepared by combining desilication and steaming modification for converting methanol to propylene process

  • Fatemeh Gorzin
  • Jafar Towfighi DarianEmail author
  • Fereydoon Yaripour
  • Seyyed Mohammad Mousavi
Article
  • 23 Downloads

Abstract

The effect of mesoporosity formation and acidity modification have been investigated by desilication and combined desilication–dealumination treatments over highly siliceous zeolite HZSM-5 (Si/Al = 200) and its catalytic performance has been studied in the conversion of methanol to propylene (MTP) reaction. Desilication of a conventional microporous HZSM-5 catalyst was performed using NaOH, mixtures of NaOH and tetrapropylammonium hydroxide (TPAOH), and mixtures of NaOH and tetrabutylammonium hydroxide (TBAOH) with different ratios. Subsequent mild steaming treatment has been used to modify acidity of the selected samples. The physicochemical properties of all samples were characterized by XRD, FE-SEM, BET and NH3-TPD methods. Textural and acidity properties confirmed that TBAOH is more effective than TPAOH in the mesoporosity formation, micropore volume preservation, and acidity modification. Steaming treatment after desilication over the sample with TPAOH/(NaOH + TPAOH) ratio of 0.4, led to increase in selectivities to propylene from 38.4 to 41.3%, and total light olefins from 69.4 to 76.6%, while it led to decrease in C5+ components selectivity from 14.8 to 10.1%. The combined alkaline-steam treatment over the sample with TBAOH/(NaOH + TBAOH) ratio of 0.2 compared to the parent one led to considerable higher selectivities to propylene (44.8 vs. 30.7%), total light olefins (84.1 vs. 57.9%), as well as lower selectivities to C5+ components (7.4% vs. 27.1%). Moreover, this sample showed double lifetime (830 h) in MTP reaction compared to the conventional micropore ZSM-5 catalyst (425 h). The results showed that desilication led to a remarkable mesoporosity development, while steaming treatment generally influenced on the HZSM-5 acidity. Therefore, the combined alkaline-steam treatment leads to HZSM-5 zeolite formation with tailored pore architecture and surface acidic properties.

Keywords

High silica ZSM-5 Hierarchical zeolites Desilication Steaming modification TPAOH TBAOH Methanol to propylene (MTP) 

Notes

Supplementary material

10934_2019_740_MOESM1_ESM.docx (863 kb)
Supplementary material 1 (DOCX 863 KB)

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Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2019

Authors and Affiliations

  • Fatemeh Gorzin
    • 1
  • Jafar Towfighi Darian
    • 1
    Email author
  • Fereydoon Yaripour
    • 2
  • Seyyed Mohammad Mousavi
    • 1
  1. 1.Department of Chemical EngineeringTarbiat Modares UniversityTehranIran
  2. 2.Catalysis Research GroupPetrochemical Research & Technology Company, National Iranian Petrochemical CompanyTehranIran

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