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Immobilized Ni-Schiff-base metal complex on MCM-41 as a heterogeneous catalyst for the green synthesis of benzimidazole derivatives using glycerol as a solvent

  • M. Bharathi
  • S. Indira
  • G. Vinoth
  • K. Shanmuga BharathiEmail author
Article
  • 28 Downloads

Abstract

A Nickel(II) Schiff-base complex was anchored on hexagonal mesoporous MCM-41 to prepare a new catalyst. The prepared catalyst has been characterized by FT-IR, UV–DRS, small angle-XRD, SEM–EDX, HR-TEM, N2 adsorption and desorption, ICP-AES, 1H and 13C-NMR. The newly synthesized Ni–MCM-41 is used as an efficient catalyst in the synthesis of benzimidazole derivatives through the oxidative condensation of an aromatic aldehyde with o-phenylenediamine under mild conditions with glycerol as high potential and alternative green solvent. It is found out that the yields of the products were good. Notably, both catalyst and solvent were recovered and reused upto four cycles without any significant loss in the yield. The catalytic efficiency of the catalyst was compared to that of some other reported catalysts and discussed.

Keywords

MCM-41 Ni(II) Schiff base complex Immobilized Mesoporous material Benzimidazole derivative 

Notes

Acknowledgements

The authors are grateful for the financial support from the University Grants Commission (UGC-BSR) F.30-319/2016 (BSR) Government of India, New Delhi, India. The first author acknowledges to University Grants Commission-Rajiv Gandhi National Fellowship (UGC-RGNF) (Grant No. RGNF-2015-17-SC-TAM-21024) research grant for their financial support.

Supplementary material

10934_2019_736_MOESM1_ESM.doc (74 kb)
Supplementary material 1 (DOC 74 KB)

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Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2019

Authors and Affiliations

  • M. Bharathi
    • 1
  • S. Indira
    • 1
  • G. Vinoth
    • 1
  • K. Shanmuga Bharathi
    • 1
    Email author
  1. 1.Department of ChemistryPeriyar UniversitySalemIndia

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