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Copper oxide modified SBA-15 for the selective vapour phase dehydrogenation of cyclohexanol to cyclohexanone

  • Chandralayam Soumini
  • Sankaran Sugunan
  • Suja Haridas
Article
  • 17 Downloads

Abstract

Catalysts with efficient dispersion, high activity, and minimum leaching of active component are evergreen areas of interest in the field of catalysis. Incorporation of active component on high surface area materials helps to attain uniform dispersion, increased activity and stability for the catalyst system. Mesoporous materials like SBA-15 are widely used as catalyst support because of its high surface area, thermal and hydrothermal stability, uniform hexagonal mesopores, etc. Here we have synthesized copper oxide modified SBA-15 catalysts with various weight percentages of copper metal and its activity towards the dehydrogenation of cyclohexanol was studied. The reaction was monitored on a continuous flow fixed bed gas phase reactor. Various parameters for the reaction were optimized. SBA-15 with less than 10% Cu content was observed to be the most effective catalyst. The catalysts were found to be competent for the reaction with efficient dispersion of the active component and minimum deactivation.

Keywords

SBA-15 Cyclohexanol Dehydrogenation Cyclohexanone 

Notes

Acknowledgements

The authors acknowledge their sincere gratitude to University Grants Commission (UGC), Govt. of India for the award of Junior Research Fellowship and teacher fellowship under FDP scheme to SC. SC sincerely acknowledges Prof. B. Viswanathan, NCCR, IIT Chennai and Dr. N. N. Binitha, S.N.G.S College, Pattambi for their help and support. The authors also acknowledge SAIF CUSAT, India, St. Thomas College, Pala, Kerala, India, CSMCRI, Bhavnagar, Gujarat, India and Amrita Institute of Nano Sciences, Kochi, Kerala, India for various analyses.

Supplementary material

10934_2018_658_MOESM1_ESM.docx (98 kb)
Supplementary material 1 (DOCX 97 KB)

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Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2018

Authors and Affiliations

  • Chandralayam Soumini
    • 1
    • 2
  • Sankaran Sugunan
    • 1
  • Suja Haridas
    • 1
  1. 1.Department of Applied ChemistryCochin University of Science and TechnologyCochinIndia
  2. 2.Department of ChemistryM.E.S Ponnani College, PonnaniMalappuramIndia

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